This book focuses on the design, fabrication and applications of carbon-based materials for lithium-sulfur (Li-S) batteries. It provides insights into the localized electrochemical transition of the "solid-solid" reaction instead of the "sulfur-polysulfides-lithium sulfides" reaction through the desolvation effect in subnanometer pores; demonstrates that the dissolution/diffusion of polysulfide anions in electrolyte can be greatly reduced by the strong binding of sulfur to the oxygen-containing groups on reduced graphene oxide; manifests that graphene foam can be used as a 3D current collector for high sulfur loading and high sulfur content cathodes; and presents the design of a unique sandwich structure with pure sulfur between two graphene membranes as a very simple but effective approach to the fabrication of Li-S batteries with ultrafast charge/discharge rates and long service lives. The book offers an invaluable resource for researchers, scientists, and engineers in the field of energy storage, providing essential insights, useful methods, and practical ideas that can be considered for the industrial production and future application of Li-S batteries.

In its second volume, this book aims to link the academic research with development in the real world and provide a historical and institutional background that can enrich more formal research. The first section will include an assessment of the evolution and the state of the nascent second-generation biofuel as well as a perspective on the evolution of corn ethanol and sugarcane ethanol in Brazil. It will also include a historical and institutional background on the biofuel industry in Brazil that has global lessons, and later, provide a technical overview of major analytical tools used to assess the economic, land use and greenhouse gas implications of biofuel policies at a regional and global level. Additionally, the book analyzes the various drivers for land use change both at a micro-economic level and at a macro-economic level. It presents studies that apply regional and global economic models to examine the effects of biofuel policies in the US, EU and Brazil on regional and global land use, on food and fuel prices and greenhouse gas emissions. These papers illustrate the use of partial and general equilibrium modeling approaches to simulate the effects of various biofuel policies, and includes studies showing the effects of risk aversion, time preferences and liquidity constraints on farmers decision to grow energy crops for biofuel production. By presenting the tools of lifecycle analysis for assessing the direct greenhouse gas intensity of biofuels, this handbook investigates the types of indirect or market mediated effects that can offset or strengthen these direct effects. It will include tools to assess the direct and indirect effects of biofuel production on greenhouse gas emissions in the US and Brazil, and ultimately provide a comprehensive background to understand the state of biofuel in the present and how to analyze their implication.

This book presents a collection of chapters on modern bioelectrochemistry focusing on new materials for biodevice, bioelectrosynthesis and bioenergy. The chapters cover protein engineering, semiconductors, biorecognition, graphene-based bioelectronics, bioelectrosynthesis, biofuel cells, bioinspired batteries and biophotovoltaics.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience.Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

This book systematically describes the design and synthesis of MOF-related materials and the electrochemical energy storage-related research in the field of batteries. It starts with an introduction to the synthesis of MOF-based materials and various MOF derivatives, such as MOF-derived porous carbon and MOF-derived metal nanoparticles. This is followed by highlighting the interesting examples for electrochemical applications, illustrating recent advances in battery, supercapacitor, and water splitting. This book is interesting and useful to a wide readership in the various fields of chemical science, materials science, and engineering.

This book documents the proceedings of the symposium "Fundamentals and Applications of Anion Separations" held during American Chemical Society National Meeting in Chicago, Illinois, August 25-30, 200I. Nearly 40 papers devoted to discussions on anion separation related to fundamental research and applications were presented. The symposium, sponsored by Osram Sylvania, BetzDearbom, and the Separation Science & Technology Subdivision of the Industrial & Engineering Chemistry Division of the American Chemical Society was organized by Bruce A. Moyer, Chemical Sciences Division, Oak Ridge National Laboratory, P.O. Box 2008, Building. 4500S, Oak Ridge, TN 37831-6119, and Raj P. Singh, Chemicals and Powders R&D, Osram Sylvania, Chemical and Metallurgical Products Division, Towanda, PA 18848. It drew presenters from Australia, the Czech Republic, France, Germany, Japan, South Africa, Thailand, the United Kingdom, and the United States. Separations constitute an integral part of chemical industry. Chemical products typically originate in resources that must be concentrated and purified, chemically transformed, and subjected to fmal purification. Effluent streams from the processes must be treated to recycle reusable components and to remove environmentally harmful species. Some industrial processes are devoted to environmental cleanup after pollution has occurred. In addition, many analytical methods require a separation for preconcentration, or a separation may be an inherent part of the analysis itself. Micro separations occurring at membranes or interfaces are also related phenomena employed for ion sensing. Many species targeted for separation are naturally anionic. Although the standard separations techniques ofextraction, ion exchange, adsorption, precipitation, etc.

This book is intended to be a working guide to the operation of capillary electrophoresis (CE) instrumentation. Since CE is still a rap idly maturing technique, detailed validated protocols are not widely established. Therefore, extensive experimental procedures are not pro vided for individual analyses. The intention is to provide general guide lines on the principles and practice of CE and to give an overview of the specific technologies and important application areas. Part I provides operating instructions for standard commercially available instruments. Guidelines are included for activities such as changing capillaries, method development, quantitative procedures, optimization of precision and sensitivity, and the validation of meth ods, fraction collection, and troubleshooting, as well as a quick guide to running a separation. The application range of CE is possibly the most diverse of all analytical techniques and ranges from large, complex macromolecules, such as proteins and nucleic acids, to small solutes, such as organic drugs and inorganic anions and cations."

This book discusses systematically the theoretical research and the applications of electrochemical oxygen reduction. Oxygen reduction reaction is a common issue in electrochemistry, but is also an important process involved in the field of energy, cryogenic fuel cells, metal-air cells, oxygen sensors and hydrogen peroxide preparation. This book is divided into 6 chapters; it starts with a description of dynamic mechanisms, followed by a detailed introduction on the related experimental methods and related catalyst preparation technology. By providing the basic methods and testing techniques, and by demonstrating their applications, it helps readers gain a better understanding of oxygen reduction reactions, making it a valuable resource for the industrialization of scientific research achievements. Accordingly, the book appeals to a broad readership, particularly graduate students, those working at universities and research organizations, and industrial researchers.

Electrochemistry for Bioanalysis provides a comprehensive understanding of the benefits and challenges of the application of electrochemical and electroanalytical techniques for measurement in biological samples. The book presents detailed information on measurement in a host of various biological samples from single cells, tissues and in vivo. Sections cover real insights surrounding key experimental design and measurement within multiple complex biological environments. Finally, users will find discussions on emerging topics such as electrogenerated chemiluminescence and the use of additive manufacturing for biosensor fabrication. Continuous learning reinforcement throughout the book, including problems for self-assessment, make this an ideal resource.

This book encompasses select proceedings of NSEST-2020 and ECSIRM-2020. The volume covers advances in major areas of electrochemical science and technology and surface engineering. It covers all aspects of electrochemistry with more emphasis on corrosion. The corrosion topics include self-healing sol-gel based corrosion resistant coatings, nitric acid corrosion of stainless steel, stress corrosion cracking, etc. Few chapters are focused on electrodeposition and new materials for oxygen evolution catalysts, fuel cells and batteries. The chapters on molecularly imprinted polymer sensor for dual analytes, electrochemical sensors for lead ions and dopamine, etc., are of interest. Some papers are related to the green synthesis of nanosized oxides and superhydrophobic coatings. This book will be handy and beneficial to researchers, students, and professionals working in areas related to electrochemistry and surface engineering.

This book deals with the electro-chemo-mechanical properties characteristic of and unique to solid electrode surfaces, covering interfacial electrochemistry and surface science. Electrochemical reactions such as electro-sorption, electro-deposition or film growth on a solid electrode induce changes in surface stress or film stress that lead to transformation of the surface phase or alteration of the surface film. The properties of solid electrode surfaces associated with the correlation between electrochemical and mechanical phenomena are named "electro-chemo-mechanical properties". The book first derives the surface thermodynamics of solid electrodes as fundamentals for understanding the electro-chemo-mechanical properties. It also explains the powerful techniques for investigating the electro-chemo-mechanical properties, and reviews the arguments for derivation of surface thermodynamics of solid electrodes. Further, based on current experimental findings and theories, it discusses the importance of the contribution of surface stress to the transformation of surface phases, such as surface reconstruction and underpotential deposition in addition to the stress evolution during film growth and film reduction. Moreover, the book describes the nano-mechanical properties of solid surfaces measured by nano-indentation in relation to the electro-chemo-mechanical properties. This book makes a significant contribution to the further development of numerous fields, including electrocatalysis, materials science and corrosion science.

This volume discusses both the latest experimental research in bioelectrosynthesis and current applications. Beginning with an introduction into the "electrification of biotechnology" as well as the underlying fundamentals, the volume then discusses a wide range of topics based on the interfacing of biotechnological and electrochemical reaction steps. It includes contributions on the different aspects of bioelectrochemical applications for synthesis purposes, i.e. the production of fine and platform chemicals based on enzymatically or microbially catalyzed reactions driven by electric energy. The volume finishes with a summary and outlook chapter which gives an overview of the current status of the field and future perspectives. Edited by experts in the field, and authored by a wide range of international researchers, this volume assesses how research from today's lab bench can be developed into industrial applications, and is of interest to researchers in academia and industry.

Transition metal oxides form a series of compounds with a uniquely wide range of electronic properties. They have important applications as dielectrics, semiconductors and metals, and as materials for magnetic and optical uses. The discovery of high temperature superconductors has brought the attention of a wide scientific community to this area and has highlighted the problems involved in trying to understand transition metal oxides. The present book is not primarily about Tc superconductors, although their main properties are discussed in the final sections. The main aim is to describe the varied electronic behaviour shown by transition metal oxides, and to discuss the different types of theoretical models that have been proposed to interpret this behaviour.

In this book, the development of next-generation batteries is introduced. Included are reports of investigations to realize high energy density batteries: Li-air, Li-sulfur, and all solid-state and metal anode (Mg, Al, Zn) batteries. Sulfide and oxide solid electrolytes are also reviewed.A number of relevant aspects of all solid-state batteries with a carbon anode or Li-metal anode are discussed and described: The formation of the cathode; the interface between the cathode (anode) and electrolyte; the discharge and charge mechanisms of the Li-air battery; the electrolyte system for the Li-air battery; and cell construction. The Li-sulfur battery involves a critical problem, namely, the dissolution of intermediates of sulfur during the discharge process. Here, new electrolyte systems for the suppression of intermediate dissolution are discussed. Li-metal batteries with liquid electrolytes also present a significant problem: the dendrite formation of lithium. New separators and electrolytes are introduced to improve the safety and rechargeability of the Li-metal anode. Mg, Al, and Zn metal anodes have been also applied to rechargeable batteries, and in this book, new metal anode batteries are introduced as the generation-after-next batteries.This volume is a summary of ALCA-SPRING projects, which constitute the most extensive research for next-generation batteries in Japan. The work presented in this book is highly informative and useful not only for battery researchers but also for researchers in the fields of electric vehicles and energy storage.

The IUTAM Symposium on "Combustion in Supersonic Flows" was held in Poitiers at Ecole Nationale Superieure de Mecanique et d'Aerotechnique (ENSMA) from 2 to 6 october 1995. The Symposium was hosted by the Laboratoire de Combustion et de Detonique (UPR - CNRS 9028) and was attended by 60 delegates from 10 countries. The formal presentations and invited lectures were focused on four main topics, related to combustion in supersonic streams and practical issues relative to the development of new propulsion system: fundamental studies on premixed and unpremixed combustion, fluid dynamic aspects of supersonic combustion, practical system including Scramjet, Ramaccelerators and Pulsed Detonation Engines, application of detonation to propulsion. Invited lectures presenting the state of the art on these topics as well as available data base were delivered by professors Paul A. Libby from University of California at San Diego, Vladimir Sabel'nikov from TsAGI (Russia), Paul Clavin from IRPHE (Marseille, France) and Drs Shmuel Eidelman from SAlC (USA), Gunter Smeets from the French-German Institut of Saint-Louis and Bruno Deshaies from LCD (poi tiers, France).

This book provides a brief research source for optical fiber sensors for energy production and storage systems, discussing fundamental aspects as well as cutting-edge trends in sensing. This volume provides industry professionals, researchers and students with the most updated review on technologies and current trends, thus helping them identify technology gaps, develop new materials and novel designs that lead to commercially viable energy storage systems.

This book highlights the state of the art in solid electrolytes, with particular emphasis on lithium garnets, electrolyte-electrode interfaces and all-solid-state batteries based on lithium garnets. Written by an international group of renowned experts, the book addresses how garnet-type solid electrolytes are contributing to the development of safe high energy density Li batteries. Unlike the flammable organic liquid electrolyte used in existing rechargeable Li batteries, garnet-type solid electrolytes are intrinsically chemically stable in contact with metallic lithium and potential positive electrodes, while offering reasonable Li conductivity. The book's respective chapters cover a broad spectrum of topics related to solid electrolytes, including interfacial engineering to resolve the electrolyte-electrode interfaces, the latest developments in the processing of thin and ultrathin lithium garnet membranes, and fabrication strategies for the high-performance solid-state batteries.This highly informative and intriguing book will appeal to postgraduate students and researchers at academic and industrial laboratories with an interest in the advancement of high energy-density lithium metal batteries

This book provides a comprehensive review of functional nanomaterials for electrochemical applications, presenting interesting examples of nanomaterials with different dimensions and their applications in electrochemical energy storage. It also discusses the synthesis of functional nanomaterials, including quantum dots; one-dimensional, two-dimensional and three-dimensional nanostructures; and advanced nanocomposites. Highlighting recent advances in current electrochemical energy storage hotpots: lithium batteries, lithium-ion batteries, sodium-ion batteries, other metal-ion batteries, halogen ion batteries, and metal-gas batteries, this book will appeal to readers in the various fields of chemistry, material science and engineering.

This book introduces readers to the fundamental physics and chemistry of the proton exchange membrane fuel cell (PEMFC), followed by discussions on recent advances in low platinum electrocatalysis and related catalyst development for PEMFC (the book's primary focus), methods of membrane electrode assembly (MEA) fabrication for low platinum catalysts, and durability issues in connection with MEA. While energy and environmental issues are becoming the two main subjects in global sustainable development, the proton exchange membrane fuel cell (PEMFC), a clean and efficient new energy technology, has attracted more and more attention in recent years The major hurdle for more extensive applications of the PEMFC, especially for the automotive sector, is the high platinum loading requirement. Readers will gain a comprehensive understanding of the fundamentals and methods of low platinum PEMFC. This book is intended for researchers, engineers and graduate students in the fields of new energy technology, the fuel cell vehicle industry and fuel cell design.

Modelling of heterogeneous processes, such as electrochemical reactions, extraction or ion-exchange, usually requires solving the transport problem associated to the process. Since the processes at the phase boundary are described by scalar quantities and transport quantities are vectors or tensors, coupling of them can take place only via conservation of mass, charge or momentum. In this book, transport of ionic species is addressed in a versatile manner, emphasizing the mutual coupling of fluxes in particular. Treatment is based on the formalism of irreversible thermodynamics, i.e. on linear (ionic) phenomenological equations, from which the most frequently used Nernst-Planck equation is derived. Limitations and assumptions made are thoroughly discussed.
The Nernst-Planck equation is applied to selected problems at the electrodes and in membranes. Mathematical derivations are presented in detail so that the reader can learn the methodology of solving transport problems. Each chapter contains a large number of exercises, some of them more demanding than others.

Written by the inventors and leading experts of this new field, the book results from the International Symposium on "Atomic Switch: Invention, Practical use and Future Prospects" which took place in Tsukuba, Japan on March 27th - 28th, 2017. The book chapters cover the different trends from the science and technology of atomic switches to their applications like brain-type information processing, artificial intelligence (AI) and completely novel functional electronic nanodevices. The current practical uses of the atomic switch are also described. As compared with the conventional semiconductor transistor switch, the atomic switch is more compact (~1/10) with much lower power consumption (~1/10) and scarcely influenced by strong electromagnetic noise and radiation including cosmic rays in space (~1/100). As such, this book is of interest to researchers, scholars and students willing to explore new materials, to refine the nanofabrication methods and to explore new and efficient device architectures.

Volume 41 of the prominent series Modern Aspects of Electrochemistry covers a range of topics in Electrochemistry and Electrochemical Engineering. The topics include the second chapter on the survey of experimental techniques and devices of solid state electrochemistry begun by Professor Joachim Maier in Volume 39. Chapter two contains a review of synthesis and characterization of nanoporous carbons and their electrochemical applications. The next chapter reviews and discusses the use of graphs in the study of chemical reaction network. The book also reviews and discusses mathematical models of three dimensional electrode structures.