This thesis presents the fundamental research and latest findings on novel flexible/wearable photovoltaic technology, and comprehensively summarizes the rapid developments in flexible photovoltaics, from traditional planar solar cells to fiber solar cells. It discusses the rational design of fiber solar cell materials, electrodes and devices, as well as critical factors including cost, efficiency, flexibility and stability . Furthermore, it addresses fundamental theoretical principles and novel fabrication technologies and their potential applications. The book provides practical information for university researchers and graduate students interested in flexible fiber photovoltaics, and inspires them to design other novel flexible/wearable electronics and textiles.

This brief is concerned with the fundamentals of corrosion of metallic materials and electrochemistry for better understanding of corrosion phenomena. Corrosion is related to both the environment and material properties, induced by electrochemical reactions at the interface between metallic materials and the environment as in aqueous and gaseous phases. In order to understand corrosion phenomena, knowledge of electrochemistry is thus required, and to investigate the cause of corrosion damage, appropriate electrochemical experiments must be performed. Corrosion scientists should therefore possess knowledge of both electrochemistry and its related experimental techniques. In this book, corrosion phenomena are introduced from the electrochemical aspect. Electrochemical techniques for the study of corrosion are then described with other techniques that can be combined with electrochemistry. Because this brief is characterized as starting with the fundamentals of corrosion and electrochemistry, it is accessible to undergraduate students as well as to graduate students who are beginning corrosion research.

A text- and exercise book for physical chemistry students! This book deals with the fundamental aspects of physical chemistry taught at the undergraduate level in chemistry and the engineering sciences in a compact and practice-oriented form. Numerous problems and detailed solutions offer the possibility of an in-depth reflection of topics like chemical thermodynamics and kinetics, atomic structure and spectroscopy. Every chapter starts with a recapitulation of important background information, before leading over to representative exercises and problems. Detailed descriptions systematically present and explain the solutions to the problems, so that readers can carefully check their own solutions and get clear-cut introductions on how to approach similar problems systematically. The book addresses students at the (upper) undergraduate level, as well as tutors and teachers. It is a rich source of exercises for exam preparation and can be used alongside classical textbooks. Furthermore it can serve teachers and tutors for the conception of their lessons. Its well-thought-through presentation, structure and design make the book appeal to everybody who wants to succeed with the physical chemistry lessons and exercises.

This book discusses the physics of the dynamics of ions in various ionically conducting materials, and applications including electrical energy generation and storage. The experimental techniques for measurements and characterization, molecular dynamics simulations, the theories of ion dynamics, and applications are all addressed by the authors, who are experts in their fields. The experimental techniques of measurement and characterization of dynamics of ions in glassy, crystalline, and liquid ionic conductors are introduced with the dual purpose of introducing the reader to the experimental activities of the field, and preparing the reader to understand the physical quantities derived from experiments. These experimental techniques include calorimetry, conductivity relaxation, nuclear magnetic resonance, light scattering, neutron scattering, and others. Methods of molecular dynamics simulations are introduced to teach the reader to utilize the technique for practical applications to specific problems. The results elucidate the dynamics of ions on some issues that are not accessible by experiments. The properties of ion dynamics in glassy, crystalline and liquid ionic conductors brought forth by experiments and simulations are shown to be universal, i.e. independent of physical and chemical structure of the ionic conductor as long as ion-ion interaction is the dominant factor. Moreover these universal properties of ion dynamics are shown to be isomorphic to other complex interacting systems including the large class of glass-forming materials with or without ionic conductivity.By covering the basic concepts, theories/models, experimental techniques and data, molecular dynamics simulations, and relating them together, Dynamics of Glassy, Crystalline and Liquid Ionic Conductors will be of great interest to many in basic and applied research areas from the broad and diverse communities of condensed matter physicists, chemists, materials scientists and engineers. The book also provides the fundamentals for an introduction to the field and it is written in such a way that can be used for teaching courses either at the undergraduate or graduate level in academic institutions.

This book presents the fundamental scientific principles of long afterglow phosphorescent materials and a comprehensive review of both commercialized afterglow materials and the latest advances in the development of novel long afterglow materials. It is designed to supply much needed information about inorganic and organic afterglow materials, including detailed treatment of structure, classification, preparation techniques, characterization, surface modification chemistry, and optical measurements. Special attention is given to technological applications such as photovoltaics, photocatalytic reactions, and lighting and molecular sensing. Although traditional long afterglow phosphors have been widely investigated and used in industry, and significant efforts have recently been made toward the use of these materials for bioimaging, there is to date no scientific monograph dedicated to afterglow materials. This book not only provides a beginners' guide to the fundamentals of afterglow luminescence and materials, but also gives skilled researchers essential updates on emerging trends and efforts. The work provides a special focus on organic afterglow materials, which offer several advantages such as light-weight, flexible, and wide varieties; mild preparation conditions; and good processability. This book is aimed at postgraduate students, researchers, and technologists who are engaged in the synthesis, development, and commercialization of afterglow materials. It represents essential reading on interdisciplinary frontiers in the materials science, chemistry, photophysics, and biological aspects of afterglow materials.

This book presents a comprehensive survey about conducting polymers and their hybrids with different materials. It highlights the topics pertinent to research and development in academia and in the industry. The book thus discusses the preparation and characterization of these materials, as well as materials properties and their processing. The current challenges in the field are addressed, and an outline on new and even futuristic approaches is given. "Conducting Polymer Hybrids" is concerned with a fascinating class of materials with the promise for wide-ranging applications, including energy generation and storage, supercapacitors, electronics, display technologies, sensing, environmental and biomedical applications. The book covers a large variety of systems: one-, two-, and three-dimenstional composites and hybrids, mixed at micro- and nanolevel.

In this book well-known experts highlight cutting-edge research priorities and discuss the state of the art in the field of solid oxide fuel cells giving an update on specific subjects such as protonic conductors, interconnects, electrocatalytic and catalytic processes and modelling approaches.Fundamentals and advances in this field are illustrated to help young researchers address issues in the characterization of materials and in the analysis of processes, not often tackled in scholarly books.

This thoroughy updated open-learning book provides an introduction to electroanalytical chemistry, one of today's fastest growing and most exciting branches of analytical science. This text discusses electroanalysis in a non-mathematical and informal tutorial style. In addition to over 250 discussion and self-assessment questions, 50 worked examples are also included throughout the book, thus providing a wide range of excellent material for testing the reader's understanding of the subject matter.
The topics covered include the following:

• Simple emf measurements with cells
• Equilibrium and dynamic measurements
• Polarography
• Cyclic voltammetry
• Rotated disc, ring-disc and wall-jet electrodes
• In situ spectroelectrochemistry measurements
• Impedance analysis
• Preparation of electrodes
• Data processing

The book also contains a comprehensive bibliography and details of web-based resources.
Electroanalytical Chemistry assumes no prior knowledge of this powerful branch of analytical science and will be an invaluable aid for anyone wanting to perform analytical measurements using electrochemical techniques. The book's approach is ideal for students studying at Foundation, BTEC (HNC and HND), and for those pursuing BSc and MChem courses in analytical and physical chemistry, as well as subsidiary courses in life, environmental and materials science.
Analytical Techniques in the Sciences
This series of books provides coverage of all the major analytical techniques and their application in the most important areas of physical, life and materials sciences. Each text is presented in an open-learning/distance-learning style, in which the learning objectives are clearly identified. The reader's understanding of the materials is constantly evaluated by the use of self-assessment and discussion questions.

This book outlines methods to improve functioning of these polymer based devices - in particular, the multi-faceted cognition of these materials. In situ electrochemical techniques are studied to elucidate redox switching between non-conducting and conducting states. The book examines the advantages of combinations of in situ electrochemical techniques in a hyphenated mode for analyzing conducting polymers.

The study of electrochemical nanotechnology has emerged as researchers apply electrochemistry to nanoscience and nanotechnology. These two related volumes in the Modern Aspects of Electrochemistry Series review recent developments and breakthroughs in the specific application of electrochemistry and nanotechnology to biology and medicine. Internationally renowned experts contribute chapters that address both fundamental and practical aspects of several key emerging technologies in biomedicine, such as the processing of new biomaterials, biofunctionalization of surfaces, characterization of biomaterials, discovery of novel phenomena and biological processes occurring at the molecular level.

Amperometric sensors, biosensors included, particularly rely on suitable electrode materials. Progress in material science has led to a wide variety of options that are available today. For the first time, these novel functional electrode coating materials are reviewed in this monograph, written by and for electroanalytical chemists. This includes intrinsically conducting, redox and ion-exchange polymers, metal and carbon nanostructures, silica based materials. Monolayers and relatively thick films are considered. The authors critically discuss preparation methods, in addition to chemical and physical characteristics of these new materials. They present various examples of emerging applications in electroanalysis. Due to its comprehensive coverage, the book will become an indispensable source for researchers working on the development and even proper use of new amperometric sensor systems.

This book updates the latest advancements in new chemistries, novel materials and system integration of rechargeable batteries, including lithium-ion batteries and batteries beyond lithium-ion and addresses where the research is advancing in the near future in a brief and concise manner. The book is intended for a wide range of readers from undergraduates, postgraduates to senior scientists and engineers. In order to update the latest status of rechargeable batteries and predict near research trend, we plan to invite the world leading researchers who are presently working in the field to write each chapter of the book. The book covers not only lithium-ion batteries but also other batteries beyond lithium-ion, such as lithium-air, lithium-sulfur, sodium-ion, sodium-sulfur, magnesium-ion and liquid flow batteries.

This thesis describes novel strategies for the rational design of several cutting-edge high-efficiency photocatalysts, for applications such as water photooxidation, reduction, and overall splitting using a Z-Scheme system. As such, it focuses on efficient strategies for reducing energy loss by controlling charge transfer and separation, including novel faceted forms of silver phosphate for water photooxidation at record high rates, surface-basic highly polymerised graphitic carbon nitride for extremely efficient hydrogen production, and the first example of overall water splitting using a graphitic carbon nitride-based Z-Scheme system. Photocatalytic water splitting using solar irradiation can potentially offer a zero-carbon renewable energy source, yielding hydrogen and oxygen as clean products. These two ‘solar’ products can be used directly in fuel cells or combustion to provide clean electricity or other energy. Alternatively they can be utilised as separate entities for feedstock-based reactions, and are considered to be the two cornerstones of hydrogenation and oxidation reactions, including the production of methanol as a safe/portable fuel, or conventional catalytic reactions such as Fischer-Tropsch synthesis and ethylene oxide production. The main driving force behind the investigation is the fact that no photocatalyst system has yet reported combined high efficiency, high stability, and cost effectiveness; though cheap and stable, most suffer from low efficiency.

This work takes advantage of high-resolution silicon stencil masks to build air-stable complementary OTFTs using a low-temperature fabrication process. Plastic electronics based on organic thin-film transistors (OTFTs) pave the way for cheap, flexible and large-area products. Over the past few years, OTFTs have undergone remarkable advances in terms of reliability, performance and scale of integration. Many factors contribute to the allure of this technology; the masks exhibit excellent stiffness and stability, thus allowing OTFTs with submicrometer channel lengths and superb device uniformity to be patterned. Furthermore, the OTFTs employ an ultra-thin gate dielectric that provides a sufficiently high capacitance to enable the transistors to operate at voltages as low as 3 V. The critical challenges in this development are the subtle mechanisms that govern the properties of aggressively scaled OTFTs. These mechanisms, dictated by device physics, are well described and implemented into circuit-design tools to ensure adequate simulation accuracy.

This second edition of a successful and highly-accessed monograph has been extended by more than 100 pages. It includes an enlarged coverage of applications for materials characterization and analysis. Also a more detailed description of strategies for determining free energies of ion transfer between miscible liquids is provided. This is now possible with a "third-phase strategy" which the authors explain from theoretical and practical points of view. The book is still the only one detailing strategies for solid state electroanalysis. It also features the specific potential of the techniques to use immobilized particles (for studies of solid materials) and of immobilized droplets of immiscible liquids for the purpose of studying the three-phase electrochemistry of these liquids. This also includes studies of ion transfer between aqueous and immiscible non-aqueous liquids. The bibliography of all published papers in this field of research has been expanded from 318 to now 444 references in this second edition. Not only are pertinent references provided at the end of each chapter, but the complete list of the cited literature is also offered as a separate chapter for easy reference.

This edited volume presents research results of the PPP European Green Vehicle Initiative (EGVI), focusing on electric vehicle batteries. Electrification is one road towards sustainable road transportation, and battery technology is one of the key enabling technologies. However, at the same time, battery technology is one of the main obstacles for a broad commercial launch of electric vehicles. This book includes research contributions which try to bridge the gap between research and innovation in the field of battery technology for electric vehicles. The target audience primarily comprises researchers and experts in the field.

Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.

Graphene has grasped the attention of academia and industry world-wide due its unique structure and reported advantageous properties. This was reflected via the 2010 Nobel Prize in Physics being awarded for groundbreaking experiments regarding the two-dimensional material graphene. One particular area in which graphene has been extensively explored is electrochemistry where it is potentially the world’s thinnest electrode material. Graphene has been widely reported to perform beneficially over existing electrode materials when used within energy production or storage devices and when utilised to fabricate electrochemical sensors. This book charts the history of graphene, depicting how it has made an impact in the field of electrochemistry and how scientists are trying to unravel its unique properties, which has, surprisingly led to its fall from grace in some areas. A fundamental introduction into Graphene Electrochemistry is given, through which readers can acquire the tools required to effectively explain and interpret the vast array of graphene literature. The readers is provided with the appropriate insights required to be able to design and implement diligent electrochemical experiments when utilising graphene as an electrode material.

Through this monograph, the pharmaceutical chemist gets familiar with the possibilities electroanalytical methods offer for validated analyses of drug compounds and pharmaceuticals. The presentation focuses on the techniques most frequently used in practical applications, particularly voltammetry and polarography. The authors present the information in such a way that the reader can judge whether the application of such techniques offers advantages for solving a particular analytical problem. Basics of individual electroanalytical techniques are outlined using as simple language as possible, with a minimum of mathematical apparatus. For each electroanalytical technique, the physical and chemical processes as well as the instrumentation are described. The authors also cover procedures for the identification of electroactive groups and the chemical and electrochemical processes involved. Understanding the principles of such processes is essential for finding optimum analytical conditions in the most reliable way. Added to this is the validation of such analytical procedures. A particularly valuable feature of this book are extensive tables listing numerous validated examples of practical applications. Various Indices according to the drug type, the electroactive group and the type of method as well as a subject and author index are also provided for easy reference.

This comprehensive presentation of the integral equation method as applied to electro-analytical experiments is suitable for electrochemists, mathematicians and industrial chemists. The discussion focuses on how integral equations can be derived for various kinds of electroanalytical models. The book begins with models independent of spatial coordinates, goes on to address models in one dimensional space geometry and ends with models dependent on two spatial coordinates. Bieniasz considers both semi-infinite and finite spatial domains as well as ways to deal with diffusion, convection, homogeneous reactions, adsorbed reactants and ohmic drops. Bieniasz also discusses mathematical characteristics of the integral equations in the wider context of integral equations known in mathematics. Part of the book is devoted to the solution methodology for the integral equations. As analytical solutions are rarely possible, attention is paid mostly to numerical methods and relevant software. This book includes examples taken from the literature and a thorough literature overview with emphasis on crucial aspects of the integral equation methodology.

Polyelectrolyte Complexes for Tailoring of Wood Fibre Surfaces. Polyelectrolyte Complexes in Flocculation Applications. Spontaneous Assembly and Induced Aggregation of Food Proteins. Polyelectrolyte Complexes of DNA and Polycations as Gene Delivery Vectors. Sizing, Shaping and Pharmaceutical Applications of Polyelectrolyte Complex Nanoparticles.

This book represents the first rigorous treatment of thermoelectrochemistry, providing an overview that will stimulate electrochemists to develop and apply modern thermoelectrochemical methods. While classical static approaches are also covered, the emphasis lies on methods that make it possible to independently vary temperature such as in-situ heating of electrodes by means of electric current, microwaves or lasers. For the first time, "hot-wire electrochemistry" is examined in detail. The theoretical background presented addresses all aspects of temperature impacts in the context of electrochemistry.

This book covers broad aspects of the chemistry of -stacked polymers and low-molecular-weight molecules, from synthesis through theory. It is intended for graduate students and researchers in academia and industry and consists of chapters written by renowned scientists who have made significant contributions to this field in the past decade. -Stacked polymers and low-molecular-weight molecules are expected to replace main-chain conjugated polymers such as polyacetylenes and polythiophenes as organic conducting and energy-transferring substances that are important as materials for photo-electronic applications. -Stacked polymers and molecules have significant advantages over main-chain conjugated polymers, i.e., high solubility in solvents, large freedom in molecular design, and colorless nature.

In DNA Electrophoresis: Methods and Protocols, expert researchers in the field detail many of the methods which are now commonly used to study DNA using electrophoresis as the major approach. A powerful tool that allows separating DNA molecules according to their size and shape, this volume includes methods and techniques such as 2-dimentional gel electrophoresis as the major approach. These include methods and techniques such as 2-dimentional gel electrophoresis, DNA electrophoresis under conditions in which DNA molecules are completely or partially denatured during the runs, Pulse Field Gel Electrophoresis, electrophoresis coupled to fluorescence in situ hybridization, as well as protein-DNA interactions studied using electrophoreses. Written in the highly successful Methods in Molecular Biology series format, chapters include introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible laboratory protocols, and key tips on troubleshooting and avoiding known pitfalls. Authoritative and practical, DNA Electrophoresis: Methods and Protocols aids scientists in continuing to study DNA dynamics both in live cells and in test tubes.

This volume of Modern Aspects of Electrochemistry has contributions from significant individuals in electrochemistry. This 7 chapter book discusses electrodeposition and the characterization of alloys and composite materials, the mechanistic aspects of lead electrodeposition, electrophoretic deposition of ceramic materials onto metal surfaces and the fundamentals of metal oxides for energy conversion and storage technologies. This volume also has a chapter devoted to the anodization of aluminum, electrochemical aspects of chemical and mechanical polishing, and surface treatments prior to metallization of semiconductors, ceramics, and polymers. This volume of Modern Aspects of Electrochemistry is ideal for scientists, researchers, engineers, and students interested in the latest findings in the field of electrodeposition and surface finishing.