This thesis systematically introduces readers to a new metal-organic framework approach to fabricating nanostructured materials for electrochemical applications. Based on the metal-organic framework (MOF) approach, it also demonstrates the latest ideas on how to create optimal MOF and MOF-derived nanomaterials for electrochemical reactions under controlled conditions. The thesis offers a valuable resource for researchers who want to understand electrochemical reactions at nanoscale and optimize materials from rational design to achieve enhanced electrochemical performance. It also serves as a useful reference guide to fundamental research on advanced electrochemical energy storage materials and the synthesis of nanostructured materials.

This book highlights the development of novel metal-supported solid oxide fuel cells (MS-SOFCs). It describes the metal-supported solid oxide fuel cells (MS-SOFCs) that consist of a microporous stainless steel support, nanoporous electrode composites and a thin ceramic electrolyte using the "tape casting-sintering-infiltrating" method. Further, it investigates the reaction kinetics of the fuel cells' electrodes, structure-performance relationship and degradation mechanism. By optimizing the electrode materials, preparation process for the fuel cells, and nano-micro structure of the electrode, the resulting MS-SOFCs demonstrated (1) great output power densities at low temperatures, e.g., 1.02 W cm-2 at 600 DegreesC, when operating in humidified hydrogen fuels and air oxidants; (2) excellent long-term stability, e.g., a degradation rate of 1.3% kh-1 when measured at 650 DegreesC and 0.9 A cm-2 for 1500 h. The design presented offers a promising pathway for the development of low-cost, high power-density and long-term-stable SOFCs for energy conversion.

This volume discusses the theoretical fundamentals and potential applications of the original electro-Fenton (EF) process and its most innovative and promising versions, all of which are classified as electrochemical advanced oxidation processes. It consists of 15 chapters that review the latest advances and trends, material selection, reaction and reactor modeling and EF scale-up. It particularly focuses on the applications of EF process in the treatment of toxic and persistent organic pollutants in water and soil, showing highly efficient removal for both lab-scale and pre-pilot setups. Indeed, the EF technology is now mature enough to be brought to market, and this collection of contributions from leading experts in the field constitutes a timely milestone for scientists and engineers.

This textbook discusses the latest advances in the corrosion of metals and related protection methods, and explores all corrosion-related aspects used in natural and industrial environments, including monitoring and testing. Throughout the textbook, the science and engineering of corrosion are merged to help readers perform correct corrosion assessments in both the design phase and plant management phase, and to define the optimal protection technique. In addition, the book addresses basic aspects of corrosion science, including the electrochemical mechanism, thermodynamic and kinetic aspects, the use of Pourbaix and Evans diagrams, and various forms of corrosion (from uniform to localised to stress corrosion phenomena); as well as the protection systems adopted to combat corrosion, including inhibitors, coatings and cathodic protection. Such basic knowledge is fundamental to understanding the "corrosion engineering" approach applied to the durability of metals immersed in water, buried in soil, exposed to the atmosphere, used in reinforced concrete, in the human body and in petrochemical plants, or at risk of high-temperature corrosion. A final chapter is dedicated to the use of statistics in corrosion. All chapters include exercises and practical examples to help students understand, predict, evaluate and mitigate corrosion problems. As such, the book offers the ideal learning resource for all students of corrosion courses in chemical, mechanical, energy and materials engineering at the graduate and advanced undergraduate level, as well as a valuable reference guide for engineers whose work involves real-world applications.

This book provides a review of the latest advances in anion exchange membrane fuel cells. Starting with an introduction to the field, it then examines the chemistry and catalysis involved in this energy technology. It also includes an introduction to the mathematical modelling of these fuel cells before discussing the system design and performance of real-world systems. Anion exchange membrane fuel cells are an emerging energy technology that has the potential to overcome many of the obstacles of proton exchange membrane fuel cells in terms of the cost, stability, and durability of materials. The book is an essential reference resource for professionals, researchers, and policymakers around the globe working in academia, industry, and government.

Global experts provide an authoritative source of information on the use of electrochemical fuel cells, and in particular discuss the use of nanomaterials to enhance the performance of existing energy systems. The book covers the state of the art in the design, preparation, and engineering of nanoscale functional materials as effective catalysts for fuel cell chemistry, highlights recent progress in electrocatalysis at both fuel cell anode and cathode, and details perspectives and challenges in future research.

This book is for anyone interested in renewable energy for a sustainable future of mankind. Batteries, fuel cells, capacitors, electrolyzers and solar cells are explained at the molecular level and at the power plant level, in their historical development, in their economical and political impact, and social change. Cases from geophysics and astronomy show that electrochemistry is not confined to the small scale. Examples are shown and exercised.

This book addresses electrocatalysis based on chalcogenides, particularly in the nanoscale domain. Special attention is paid to the hydrogen evolution reaction (HER) and the oxygen reduction reaction (ORR). The book provides an introduction to materials synthesis; the basic principles of electrocatalysis; related precious metal versus non-precious metal catalytic center chalcogenides as well as supports; and the role of such supports in stabilizing the catalytic centers. In short: pursuing a bottom-up approach, it covers the properties of this class of electrocatalysts and examines their applications in low-temperature fuel systems such as microfluidic fuel cells for portable devices. Accordingly, it is ideally suited for all professionals and researchers interested in electrochemistry, renewable energy and electrocatalysis, and non-precious metal centers for chemical energy conversion.

This book covers the various advanced manufacturing processes employed by manufacturing industries to improve their productivity in terms of socio-economic development. The authors present automated conventional and non-conventional machining techniques as well as virtual machining principles and techniques. Material removal by mechanical, chemical, thermal and electrochemical processes are described in detail. A glossary of key concepts is attached at end of the book.

This volume explores the latest developments in the area of polymer electrolyte membranes (PEMs) used for high-temperature fuel cells. Featuring contributions from an international array of researchers, it presents a unified viewpoint on the operating principles of fuel cells, various methodologies used for the fabrication of PEMs, and issues related to the chemical and mechanical stabilities of the membranes. Special attention is given to the fabrication of electrospun nanocomposite membranes. The editors have consciously placed an emphasis on developments in the area of fast-growing and promising PEM materials obtained via hygroscopic inorganic fillers, solid proton conductors, heterocyclic solvents, ionic liquids, anhydrous H3PO4 blends, and heteropolyacids. This book is intended for fuel cell researchers and students who are interested in a deeper understanding of the organic-inorganic membranes used in fuel cells, membrane fabrication methodologies, properties and clean energy applications.

This book addresses the control of electronic properties of carbon nanotubes. It presents thermodynamic calculations of the formation of impurities and defects in the interaction of nanotubes with hydrogen, oxygen, nitrogen and boron, based on theoretical models of the formation of defects in carbon nanotubes. It is shown that doping and adsorption lead to changes in the electronic structure of the tubes as well as to the appearance of impurity states in the HOMO-LUMO gap. The book presents examples of specific calculations for doping of carbon nanotubes with oxygen, hydrogen, nitrogen and boron, together with numerous experimental results and a comparison with the author's thermodynamic calculations. Possible directions of the technological processes of optimization are pointed out, as well as the perspectives of p-n-transition creation with the help of carbon nanotube arrays. The results presented were derived from the physics of the processes and a theoretical model of the technological processes. Though a wealth of empirical information on doping nanotubes has been accumulated in the scientific literature, what is lacking is a theoretical model for their analysis. As such, the book develops a thermodynamic model of the self-organization of structural elements in multicomponent systems - including carbon nanotubes, clusters and precipitates in condensed matter - and subsequently adapts it to the doping of carbon nanotubes. This approach allows readers to gain a far deeper understanding of the processes of doping carbon nanotubes.

This thesis focuses on the theoretical description of electro-osmosis of polymer solutions. In particular, it emphasizes the importance of considering non-uniform profiles of the solution viscosity and polymer concentration near a solid surface. The thesis begins with an introduction to fundamental theories and experimental observations for beginners in this field, concerning electrolyte solutions, electric double layers, and electrokinetics. In Chapter 2, the author discusses the linear response of electro-osmotic flow with respect to applied electric fields in aqueous polyelectrolyte solutions, and predicts a possibility of flow reversal caused by oppositely charged polyelectrolytes adsorbed on a charged surface. In Chapter 3, the author extends the discussion to non-linear electro-osmotic flow driven by applied electric fields in neutral polymer solutions. The dynamics of polymers are modeled and simulated using Brownian dynamics and kinetic theory. Finally, the thesis is summarized in Chapter 4. The introduction provides a comprehensive review of electrokinetics for graduate students and researchers interested in soft matter physics. An additional attraction is that readers can effectively learn various theoretical approaches to electro-osmosis.

This book outlines issues related to massive integration of electric and plug-in hybrid electric vehicles into power grids. Electricity is becoming the preferred energy vector for the next new generation of road vehicles. It is widely acknowledged that road vehicles based on full electric or hybrid drives can mitigate problems related to fossil fuel dependence. This book explains the emerging and understanding of storage systems for electric and plug-in hybrid vehicles. The recharging stations for these types of vehicles might represent a great advantage for the electric grid by facilitating integration of renewable and distributed energy production. This book presents a broad review from analyzing current literature to on-going research projects about the new power technologies related to the various charging architectures for electric and plug-in hybrid vehicles. Specifically focusing on DC fast charging operations, as well as, grid-connected power converters and the full range of energy storage systems. These key components are analyzed for distributed generation and charging system integration into micro-grids. The authors demonstrate that these storage systems represent effective interfaces for the control and management of renewable and sustainable distributed energy resources. New standards and applications are emerging from micro-grid pilot projects around the world and case studies demonstrate the convenience and feasibility of distributed energy management. The material in this unique volume discusses potential avenues for further research toward achieving more reliable, more secure and cleaner energy.

This book highlights the various topics in which luminescence and electrochemistry are intimately coupled. The topic of this book is clearly at the frontier between several scientific domains involving physics, chemistry and biology. Applications in these various fields naturally also need to be mentioned, especially concerning displays and advanced investigation techniques in analytical chemistry or for biomedical issues.

The book introduces the outcomes of latest research in the field of Chemical Engineering. The book also illustrates the application of Chemical Engineering principles to provide innovative and state of the art solutions to problems associated with chemical industries. It covers a wide spectrum of topics in the area of Chemical Engineering such as Transfer operations, novel separation processes, adsorption, photooxidation, process control, modelling, and simulation. The book provides timely contribution towards implementation of recent approaches and methods in Chemical Engineering Research. It presents chapters focussed on several Chemical Engineering principles and methodologies of wide multidisciplinary applicability. The intended audience of this book will mainly consist of researchers, research students, and practitioners in Chemical Engineering and allied fields. The book can also serve researchers and students involved in multidisciplinary research.

This book discusses recent progress in endohedral fullerenes - their production and separation techniques, as well as their characterization and properties. Furthermore, the book delves into the all-important issue of stability by investigating electron transfer between the encapsulated metal species and the carbon cage. It also reviews spin-based phenomena caused by the shielding of endohedral spin by the fullerene, and analyzes formation of the spin states by charge transfer as studied by electron spin resonance. Tuning of charge states of endohedral species and of spin states of both the cage and the cluster are explained. Finally, the book considers the recent discovery of magnetism in some endohedral fullerenes, and the potential for quantum computing.

This book review series presents current trends in modern biotechnology. The aim is to cover all aspects of this interdisciplinary technology where knowledge, methods and expertise are required from chemistry, biochemistry, microbiology, genetics, chemical engineering and computer science. Volumes are organized topically and provide a comprehensive discussion of developments in the respective field over the past 3-5 years. The series also discusses new discoveries and applications. Special volumes are dedicated to selected topics which focus on new biotechnological products and new processes for their synthesis and purification. In general, special volumes are edited by well-known guest editors. The series editor and publisher will however always be pleased to receive suggestions and supplementary information. Manuscripts are accepted in English.

A text- and exercise book for physical chemistry students! This book deals with the fundamental aspects of physical chemistry taught at the undergraduate level in chemistry and the engineering sciences in a compact and practice-oriented form. Numerous problems and detailed solutions offer the possibility of an in-depth reflection of topics like chemical thermodynamics and kinetics, atomic structure and spectroscopy. Every chapter starts with a recapitulation of important background information, before leading over to representative exercises and problems. Detailed descriptions systematically present and explain the solutions to the problems, so that readers can carefully check their own solutions and get clear-cut introductions on how to approach similar problems systematically. The book addresses students at the (upper) undergraduate level, as well as tutors and teachers. It is a rich source of exercises for exam preparation and can be used alongside classical textbooks. Furthermore it can serve teachers and tutors for the conception of their lessons. Its well-thought-through presentation, structure and design make the book appeal to everybody who wants to succeed with the physical chemistry lessons and exercises.

The second edition of this textbook includes refined text in each chapter, new sections on corrosion of steel-reinforced concrete and on cathodic protection of steel reinforced bars embedded in concrete, and some new solved examples. The book introduces mathematical and engineering approximation schemes for describing the thermodynamics and kinetics of electrochemical systems, which are the essence of corrosion science, in addition to electrochemical corrosion, forms of corrosion and mechanisms of corrosion. This approach should capture the reader's attention on the complexity of corrosion. Thus, the principles of electrochemistry and electrochemical cells are subsequently characterized in simple electrolytes from a thermodynamics point of view.

This book presents a comprehensive survey about conducting polymers and their hybrids with different materials. It highlights the topics pertinent to research and development in academia and in the industry. The book thus discusses the preparation and characterization of these materials, as well as materials properties and their processing. The current challenges in the field are addressed, and an outline on new and even futuristic approaches is given. "Conducting Polymer Hybrids" is concerned with a fascinating class of materials with the promise for wide-ranging applications, including energy generation and storage, supercapacitors, electronics, display technologies, sensing, environmental and biomedical applications. The book covers a large variety of systems: one-, two-, and three-dimenstional composites and hybrids, mixed at micro- and nanolevel.

This volume offers a careful selection of trend-setting topics in the field. In-depth review articles illustrate current trends in the field. Experienced experts present a comprehensive overview concerning the electrochemical biosensing of glucose for diabetes care from an industrial research and development perspective a survey of bioassay applications for individually addressable electrochemical arrays, focusing on liquid-phase bioanalytical assays a review of recent advances in the development of electronic tongues based on the use of biosensor arrays coupled with advanced chemometric data analysis novel strategies of DNA biosensor development and corresponding applications for studies of DNA damage a survey of recent trends in the electrochemistry of redox proteins, including the increasing diversity of redox proteins used in electrochemical studies, novel immobilization strategies, and biosensor / biofuel cell applications an overview of electrochemical sensing of blood gases with advanced sensor concepts a survey of recent bioelectroanalytical studies with high spatial resolution using scanning electrochemical microscopy with a wide range of applications covering imaging of living cells, studies of metabolic activity, imaging of local enzyme activity, and studies of transport through biolayers This timely collection will be of interest not only for experts in the field, but also to students and their teachers in disciplines that include analytical chemistry, biology, electrochemistry, and various interdisciplinary research areas.

This book discusses the physics of the dynamics of ions in various ionically conducting materials, and applications including electrical energy generation and storage. The experimental techniques for measurements and characterization, molecular dynamics simulations, the theories of ion dynamics, and applications are all addressed by the authors, who are experts in their fields. The experimental techniques of measurement and characterization of dynamics of ions in glassy, crystalline, and liquid ionic conductors are introduced with the dual purpose of introducing the reader to the experimental activities of the field, and preparing the reader to understand the physical quantities derived from experiments. These experimental techniques include calorimetry, conductivity relaxation, nuclear magnetic resonance, light scattering, neutron scattering, and others. Methods of molecular dynamics simulations are introduced to teach the reader to utilize the technique for practical applications to specific problems. The results elucidate the dynamics of ions on some issues that are not accessible by experiments. The properties of ion dynamics in glassy, crystalline and liquid ionic conductors brought forth by experiments and simulations are shown to be universal, i.e. independent of physical and chemical structure of the ionic conductor as long as ion-ion interaction is the dominant factor. Moreover these universal properties of ion dynamics are shown to be isomorphic to other complex interacting systems including the large class of glass-forming materials with or without ionic conductivity.By covering the basic concepts, theories/models, experimental techniques and data, molecular dynamics simulations, and relating them together, Dynamics of Glassy, Crystalline and Liquid Ionic Conductors will be of great interest to many in basic and applied research areas from the broad and diverse communities of condensed matter physicists, chemists, materials scientists and engineers. The book also provides the fundamentals for an introduction to the field and it is written in such a way that can be used for teaching courses either at the undergraduate or graduate level in academic institutions.

This book honors Professor. John O'M. Bockris, presenting authoritative reviews on some of the subjects to which he made significant contributions - i.e., electrocatalysis, fuel cells, electrochemical theory, electrochemistry of single crystals, in situ techniques, rechargeable batteries, passivity, and solar-fuels - and revealing the roles of electrochemical science and technology in achieving a sustainable society. Electrochemistry has long been an object of study and is now growing in importance, not only because of its fundamental scientific interest but also because of the central role it is expected to play in a future sustainable society. Professor John O'M. Bockris contributed greatly to various aspects of fundamental and applied electrochemistry - such as the structure of the double layer, kinetics and mechanism of the electrochemistry of hydrogen and oxygen, electrocatalysis, adsorption and electrochemical oxidation of small organic molecules, fuel cells, electrocrystallization, theoretical electrochemistry, new methods, photoelectrochemistry, bioelectrochemistry, corrosion and passivity, hydrogen in metals, ionic solutions and ionic liquids, and molten silicates and glasses, as well as socio-economic issues such as the hydrogen economy - for over half a century from 1945 until his retirement in 1997.

This thesis focuses on the electrochemical synthesis of multi-segmented nanowires. In contrast to previous work, which was largely limited to one-dimensional modifications, Tuncay Ozel presents a technique, termed coaxial Lithography (COAL), which allows for the synthesis of coaxial nanowires in a parallel fashion with sub-10 nanometer resolution in both the axial and radial dimensions. This work has significantly expanded current synthetic capabilities with respect to materials generality and the ability to tailor two-dimensional growth in the formation of core-shell structures. These developments have enabled fundamental and applied studies which were not previously possible. The COAL technique will increase the capabilities of many researchers who are interested in studying light-matter interactions, nanoparticle assembly, solution-dispersible nanoparticles and labels, semiconductor device physics and nanowire biomimetic probe preparation. The methodology and results presented in this thesis appeal to researchers in nanomaterial synthesis, plasmonics, biology, photovoltaics, and photocatalysis.

This book presents a design-driven investigation into smart materials developed by chemists, physicists, materials and chemical engineers, and applied by designers to consumer products, buildings, interfaces, or textiles. Introducing a class of smart materials (referred to as stimuli-responsive, morphing or kinetic materials) that move and change their shape in response to stimuli, the book presents their characteristics, advantages, potentials, as well as the difficulties involved in their application. The book also presents a large number of case studies on products, projects, concepts, and experiments employing smart materials, thus mapping out new design territories for these innovative materials. The case studies involve different fields of design, including product, interior, fashion, and communication design. Reflecting the growing demand for sustainable and human-centered design agendas, the book explores and reveals the role and influence of these new materials and technologies on design and human experience, and discusses how they can be used to redefine our objects and spaces so as to promote more resilient environments. The book offers an intriguing and valuable resource for design professionals, engineers, scientists and students alike.