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Thermoelectric Materials - Advances and Applications (Hardcover)
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Thermoelectric Materials - Advances and Applications (Hardcover)
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Environmental and economic concerns have significantly spurred the
search for novel, high-performance thermoelectric materials for
energy conversion in small-scale power generation and refrigeration
devices. This quest has been mainly fueled by the introduction of
new designs and the synthesis of new materials. In fact, good
thermoelectric materials must simultaneously exhibit extreme
properties: they must have very low thermal conductivity values and
both electrical conductivity and Seebeck coefficient high values as
well. Since these transport coefficients are interrelated, the
required task of optimization is a formidable one. Thus,
thermoelectric materials provide a full-fledged example of
interdisciplinary research connecting fields such as solid-state
physics, materials science engineering, and structural chemistry
and raise the need of gaining proper knowledge of the role played
by the electronic structure in the thermal and electrical transport
properties of solid matter. This book presents a detailed, updated
introduction to the field of thermoelectric materials in a tutorial
way, focusing on both basic notions and fundamental questions and
illustrating the abstract concepts with suitable application
examples. It discusses thermoelectric effects, the transport
coefficients and their mutual relations, the efficiency of
thermoelectric devices, and some notions on the characterization
and related industry standards. It also reviews the two basic
strategies for optimizing the thermoelectric performance of
materials: the control of thermal conductivity and the power factor
enhancement. It discusses structural complexity approach, focusing
on complex enough lattice structures with heavy atoms in the
unit-cell or nanostructured systems characterized by
low-dimensional effects, and introducing different kinds of bulk
materials of growing chemical and structural complexity. It also
discusses the electronic structure engineering approach that
focuses on obtaining a guiding principle, in terms of an electronic
band structure tailoring process, and describes the role played by
the electronic structure in the thermoelectric performance of
different materials.
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