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Fire Retardancy Behavior of Polymer/Clay Nanocomposites (Hardcover, 1st ed. 2018)
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Fire Retardancy Behavior of Polymer/Clay Nanocomposites (Hardcover, 1st ed. 2018)
Series: Springer Theses
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This thesis investigates the early ignition behavior of
polymer/clay nanocomposites, which are perceived as potential
eco-friendly flame retardant systems. It examines the correlation
between clay structural chemistry and high-temperature
transformations with clay-assisted decomposition of organic
macromolecules. In particular, it investigates the unique effects
of metal ions like Mg2+, Al3+ and Fe3+ that are inherent in clays
(smectite) on the combustion and thermo-oxidative decomposition of
polyamide 6. The results indicate that metal ions present on/in
montmorillonite platelets have preferential reactivity towards
peroxy/alkoxy groups during polyamide 6 thermal decomposition.
Lastly, a simple solution in the form of a physical coating on clay
surface is proposed, based on the role of polymer-clay interfacial
interaction.
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