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Algal Blooms and Membrane Based Desalination Technology (Paperback)
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Algal Blooms and Membrane Based Desalination Technology (Paperback)
Series: IHE Delft PhD Thesis Series
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Seawater desalination is rapidly growing in terms of installed
capacity (~80 million m3/day in 2013), plant size and global
application. An emerging threat to this technology is the seasonal
proliferation of microscopic algae in seawater known as algal
blooms. Such blooms have caused operational problems in seawater
reverse osmosis (SWRO) plants due to clogging and poor effluent
quality of the pre-treatment system which eventually forced the
shutdown of the plant to avoid irreversible fouling of downstream
SWRO membranes. As more extra large SWRO plants (>500,000
m3/day) are expected to be constructed in the coming years,
frequent chemical cleaning (>1/year) of SWRO installations will
not be feasible, and more reliable pre-treatment system will be
required. To maintain stable operation in SWRO plants during algal
bloom periods, pre-treatment using ultrafiltration (UF) membranes
has been proposed. This thesis addresses the effect of algal blooms
on the operation of UF pre-treatment and SWRO. Experimental
investigations demonstrated that marine algal blooms can impact the
backwashability of UF and can accelerate biological fouling in RO.
However, it is unlikely that algae themselves are the main causes
of fouling but rather the transparent exopolymer particles (TEPs)
that they produce. To better monitor TEPs, a new method capable of
measuring TEP as small as 10 kDa was developed and showed that TEPs
can be effectively removed by UF pre-treatment prior to SWRO. This
work also demonstrated that although TEPs and other algal-derived
material (AOM) are very sticky and can adhere to UF and RO
membranes, adhesion can be much stronger on membranes already
fouled with AOM. Moreover, a model was developed to predict the
accumulation of algal cells in capillary UF membranes which further
demonstrated that the role of algal cells in UF fouling is not as
significant as that of AOM and TEPs. Overall, this study
demonstrates that better analytical methods and tools are essential
in elucidating the adverse impacts of algal blooms in seawater on
the operation of membrane-based desalination plants (UF-RO). It
also highlighted the importance of developing effective
pre-treatment processes to remove AOM from the raw water and reduce
the membrane fouling potential of the feed water for downstream
SWRO membranes.
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