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Exposure and Fire Hazard Assessment of Nanoparticles in Fire Safe Consumer Products - Interagency Agreement Final Report (Paperback)
Loot Price: R308
Discovery Miles 3 080
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Exposure and Fire Hazard Assessment of Nanoparticles in Fire Safe Consumer Products - Interagency Agreement Final Report (Paperback)
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Loot Price R308
Discovery Miles 3 080
Expected to ship within 10 - 15 working days
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An innovative technology was evaluated to generate fire and health
safe soft furnishings. Nanoparticle-based thin coatings on a
polyurethane foam and nonwoven barrier fabric were applied using
Layerby- layer (Lbl) assembly. This is the first report of using
Lbl on a complex three dimensional substrate, to improve the fire
resistance of foam and barrier fabrics, and with sodium
montmorillonite clay (MMT), carbon nanofibers (CNF) and
multi-walled carbon nanotubes (MWCNT). The Lbl process was tailored
for each nanoparticle in order to fabricate durable coatings that
completely covered the entire substrate surface. The CNF and MWCNT
coatings on foam were thinner and contained fewer nanoparticles,
but resulted in the greatest reduction in peak heat release rate
(flammability). The reduction in foam flammability due to the
nanoparticle \Lbl coatings is as high as 1138% greater than 17
other commercial fire retardants commonly used in foam. This
technology has strong commercial viability for foam due to easy and
flexibility of the Lbl process and the significant reduction in
foam flammability caused by the coatings. However, Lbl does not
work for nonwoven barrier fabrics as the structure was unable to
remain intact during the fabrication process. In order to enable
other agencies to access the potential health risk of using this
nanoparticle-based technology for reducing the flammability of soft
consumer products, this project developed the methodology to
promote, collect, and quantify nanoparticles released from these
substrates. In general, the release of nanoparticles was an order
of magnitude higher from simulated chewing than simulated wear and
tear, highest from the barrier fabric, and lowest for MMT. The
release was between 0.50 mass fraction % to 0.0003 mass fraction %
of the total nanoparticle loading on the substrate.
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