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Syngas Generation from Hydrocarbons & Oxygenates with Structured Catalysts (Paperback, New)
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Syngas Generation from Hydrocarbons & Oxygenates with Structured Catalysts (Paperback, New)
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Syngas generation by oxidative or steam reforming of hydrocarbons
and oxygenates now attracts a lot of attention of researchers in
the fields of heterogeneous catalysis and chemical engineering due
to its tremendous importance for energy generation and synfuels
production. This book reviews results of the long-term research of
the international team of scientists aimed at development of
efficient processes of syngas generation in structured catalytic
reactors. Multiscale integrated optimisation approach is applied
throughout of this work including design of nanocomposite active
components stable to coking and sintering; developing
heat-conducting monolithic substrates comprised of refractory
alloys and cermets (honeycomb and microchannel structures, gauzes
etc) and procedures of their loading with active components; design
and manufacturing of several types of pilot-scale reactors (with
the radial or the axial flow direction) equipped with unique liquid
fuel evaporation and mixing units and internal heat exchangers.
Extended tests of these reactors fed by fuels from C1 to gasoline,
mineral and sunflower oil have been carried out with a broad
variation of experimental parameters including stability tests up
to 1000 h. Performance analysis has been made with a due regard for
equilibrium restrictions on the operational parameters. Transient
behaviour of the monolith reactor during start-up (ignition) of the
methane partial oxidation to synthesis gas was studied and analysed
via mathematical modelling based upon detailed elementary step
mechanism. This provides required bases for theoretical
optimisation of the catalyst bed configuration and process
parameters.
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