E.O. Fischer received the Nobel prize in 1973 for the
investigations of complexes with a formal metal atom-carbon double
bond. Among these, the Iron-Carbene species is readily available
and has proved to be a versatile reagent in organic syntheses. It
is rather simple to tune the electronicproperties of this Fischer
Carbene and to control reactivity and stereospecificity of the
reagent in, e.g., cyclopropanation reactions. This first volume of
the "Scripts in Inorganic and Organome- tallic Chemistry" addresses
graduate students in the fields ofcoordination compounds and
organic synthesis. It covers the chemistry and structural aspects
of iron-carbon com- pounds with a iron-carbon double bond. The
first part deals with the carbene moiety, the second with
vinylidene ligands.
General
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