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Assembled Lanthanide Complexes with Advanced Photophysical Properties (Paperback, Softcover reprint of the original 1st ed. 2018)
Loot Price: R3,263
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Assembled Lanthanide Complexes with Advanced Photophysical Properties (Paperback, Softcover reprint of the original 1st ed. 2018)
Series: Springer Theses
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This thesis provides essential information on the systematic design
of assembled lanthanide complexes for functional luminescent
materials. It discusses the relationships between assembled
structures and photo, thermal, and mechanical properties on the
basis of crystallography, spectroscopy, and thermodynamics. The
described guidelines for assembled structures will be extremely
valuable, both for industrial applications and for readers'
fundamental understanding of solid-state photophysics and materials
chemistry. Luminescent lanthanide complexes are promising
candidates for lighting devices, lasers, and bio-probes owing to
their line-like and long-lived emission arising from characteristic
4f-4f transitions. Low-vibrational and asymmetrical coordination
structures around lanthanide ions have been introduced to achieve
strong luminescence, using specific organic ligands. Recently,
assembled lanthanide complexes including coordination polymers and
metal organic frameworks have increasingly attracted attention as a
new class of luminescent materials offering thermal stability and
color tunability. However, improving the luminescence efficiencies
of these compounds remains a challenge, and specific molecular
designs to control assembled structures and yield additional
physical properties have not been established. The author provides
a group of bent-angled bridging ligands to boost photoluminescence
efficiency, and successfully introduces for the first time glass
formability and strong triboluminescence properties.
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