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The book gives an overview of the current state-of-the-art
concerning the activation and dissolution of cellulose in a broad
variety of solvents. Research on this topic can lead to new
pathways for the utilization of the most abundant terrestrial
biomolecule and may therefore be the basis for new green strategies
towards advanced materials. Leading scientists in the field show
different conceptions for the solubilization of cellulose. The long
history and groundbreaking developments in the field of polymer
chemistry, which are related to this subject, have lead to timely
alternatives to already established methods. In addition to
discussing attempts for the optimization of known dissolving
procedures, this book also details new solvent systems. New
solvents include inorganic and organic salt melts (ionic liquids),
new aqueous media, multi-component organic solvents and the
dissolution under partial derivatization of the polysaccharide. The
opportunities and the limitations of the solvents are demonstrated,
with a particular emphasis on the stability of the solutions and a
possible recycling of the solvent components.
This book illustrates that the new procedures for cellulose
dissolution can lead to a huge number of unconventional
superstructures of regenerated cellulose material, such as fibers
and polymer layers with a thickness in the nanometer range or
aerogels, i.e. regenerates with a highly porous character and a
large surface. Moreover, cellulose blends can be generated via
solutions. The book also contains chapters that show the amazing
potential of solvents for defined modification reactions on the
cellulose backbone. On one hand, it is possible to synthesize known
cellulose derivatives with new substitution patterns both on the
basis of the repeating unit and along the polymer chain. On the
other hand, completely new derivatives are presented which are
hardly accessible via heterogeneous reactions. Consequently, the
book is intended to give a comprehensive overview of procedures for
dissolution of cellulose. It is of interest for scientists new in
the field but is also a timely summary of trends for experts who
are looking for new approaches for problems related to cellulose
shaping or chemical modification.
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Satiren (Hardcover)
Richard Heinze, Kiessling Adolf
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R923
Discovery Miles 9 230
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Ships in 10 - 15 working days
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The attacks and blockade on Yemen by the Saudi-led multinational
coalition have killed thousands and triggered humanitarian
disaster. The longstanding conflict in the country between the
Huthi rebels and (until December 2017) Salih militias on the one
side and those loyal to the internationally recognized government
and many other groups fighting for their interests on the other are
said to have evolved into a proxy war between Saudi Arabia and
Iran. In 2011, however, thousands of Yemenis had taken to the
streets to protest for a better future for their country. When
President Ali Abdullah Salih signed over power in the aftermath of
these protests, there were hopes that this would signal the
beginning of a new period of transition. Yemen and the Search for
Stability focuses on the aspirations that inspired revolutionary
action, and analyzes what went wrong in the years that followed. It
examines the different groups involved in the protests - Salih
supporters, Muslim Brothers, Salafis, Huthis, secessionists, women,
youth, artists and intellectuals- in terms of their competing
visions for the country's future as well as their internal
struggles. This book traces the impact of the 2011 upheavals on
these groups' ideas for a `new Yemen' and on their strategies for
self-empowerment. In so doing, Yemen and the Search for Stability
examines the mistakes committed in the country's post-2011
transition process but also points towards prospects for stability
and positive change.
Optimization problems subject to constraints governed by partial
differential equations (PDEs) are among the most challenging
problems in the context of industrial, economical and medical
applications. Almost the entire range of problems in this field of
research was studied and further explored as part of the Deutsche
Forschungsgemeinschaft (DFG) priority program 1253 on "Optimization
with Partial Differential Equations" from 2006 to 2013. The
investigations were motivated by the fascinating potential
applications and challenging mathematical problems that arise in
the field of PDE constrained optimization. New analytic and
algorithmic paradigms have been developed, implemented and
validated in the context of real-world applications. In this
special volume, contributions from more than fifteen German
universities combine the results of this interdisciplinary program
with a focus on applied mathematics. The book is divided into five
sections on "Constrained Optimization, Identification and Control",
"Shape and Topology Optimization", "Adaptivity and Model
Reduction", "Discretization: Concepts and Analysis" and
"Applications". Peer-reviewed research articles present the most
recent results in the field of PDE constrained optimization and
control problems. Informative survey articles give an overview of
topics that set sustainable trends for future research. This makes
this special volume interesting not only for mathematicians, but
also for engineers and for natural and medical scientists working
on processes that can be modeled by PDEs.
Simulation based on mathematical models plays a major role in
computer aided design of integrated circuits (ICs). Decreasing
structure sizes, increasing packing densities and driving
frequencies require the use of refined mathematical models, and to
take into account secondary, parasitic effects. This leads to very
high dimensional problems which nowadays require simulation times
too large for the short time-to-market demands in industry. Modern
Model Order Reduction (MOR) techniques present a way out of this
dilemma in providing surrogate models which keep the main
characteristics of the device while requiring a significantly lower
simulation time than the full model. With Model Reduction for
Circuit Simulation we survey the state of the art in the
challenging research field of MOR for ICs, and also address its
future research directions. Special emphasis is taken on aspects
stemming from miniturisations to the nano scale. Contributions
cover complexity reduction using e.g., balanced truncation,
Krylov-techniques or POD approaches. For semiconductor applications
a focus is on generalising current techniques to
differential-algebraic equations, on including design parameters,
on preserving stability, and on including nonlinearity by means of
piecewise linearisations along solution trajectories (TPWL) and
interpolation techniques for nonlinear parts. Furthermore the
influence of interconnects and power grids on the physical
properties of the device is considered, and also top-down system
design approaches in which detailed block descriptions are combined
with behavioral models. Further topics consider MOR and the
combination of approaches from optimisation and statistics, and the
inclusion of PDE models with emphasis on MOR for the resulting
partial differential algebraic systems. The methods which currently
are being developed have also relevance in other application areas
such as mechanical multibody systems, and systems arising in
chemistry and to biology. The current number of books in the area
of MOR for ICs is very limited, so that this volume helps to fill a
gap in providing the state of the art material, and to stimulate
further research in this area of MOR. Model Reduction for Circuit
Simulation also reflects and documents the vivid interaction
between three active research projects in this area, namely the
EU-Marie Curie Action ToK project O-MOORE-NICE (members in Belgium,
The Netherlands and Germany), the EU-Marie Curie Action RTN-project
COMSON (members in The Netherlands, Italy, Germany, and Romania),
and the German federal project System reduction in nano-electronics
(SyreNe).
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