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The present volume, "Organoosmium Compounds" 8 6, systematically
covers the litera ture through 1992, including many later
references. This volume is the first published of Series 8. This
series is devoted to compounds containing two or more osmium atoms.
The volume forms a unit with" Organoosmium Compounds" 8 5 (in
preparation). 80th volumes deal with trinuclear compounds with
ligands other than CO which are bonded to Os by one carbon atom
("1L ligands "), regardless of whether the ligand is additionally
coordinated to Os by heteroatoms. Generally CO groups are
additional ligands. As is usual in the organometallic Gmelin
series, the term "trinuclear" means three osmium atoms in the
molecule without regard to any additional metals that may be
present. The content and the subdivision of both volumes are
described on p. 1. Volume 85 will deal with homometallic compounds
in which the bonding C atom of the leading 1L ligand is bonded to
Os by one non-bridging Os-C bond. The first part of the present
volume, 86, is devoted to homometallic compounds in which the
bonding C atom of the 1L ligand bridges two or three Os atoms. A
second part deals with all heterometallic compounds with 1L ligands
other than CO. An Empirical Formula Index and a Ligand Formula
Index for both volumes 8 5 and 86 will be included in volume 8 5.
For abbreviations and dimensions used throughout this volume, see
p. X."
The GmeLin series "Organometallic Compounds" comprises compounds
containing at least one carbon-to-metal bond (except cyano
compounds, which are considered inorganic). It includes all
information in scientific journals, but patents, conference
reports, and disserta- tions generally were not reviewed. The
volumes published so far are listed on p. V/' Organometallic
compounds are classified according to their nuclearity and the
bonding mode of the organic ligands nL. Nuclearity means the number
of atoms of the title metal in the formula unit disregarding any
additional metals that may be present. The term nL designates a
ligand bonded by n carbon atoms to one or different atoms of the
title metal. As usual, a-bonded 1 L ligands are designated by R.
Inorganic ligands (Le., ligands bonded exclusively by elements
other than carbon) are generally designated by 0 or X. 0 means
donor ligands such as pyridine or phosphanes; m-electron donors are
specified by mO. X is reserved for negatively charged ligands or
other one-electron donors such as halogens or SnR; bridging X
ligands may donate one 3 2 2 2 (~-H), three (~-Cl, ~-OR), or five
(~3-1) electrons. Terms such as lL_ 0, 20-X, or 20_ 0_ 0 may be
used for multidentate ligands. Heterometals are often designated by
M, and bridging elements, bridging groups, or nonmetallic cluster
constituents by E. The symbols 1] and ~ follow the IUPAC
nomenclature.
This well-presented and richly illustrated study of Etruscan
history and culture is based around a catalogue of Etruscan
artworks and artefacts from an exhibition held in Hamburg in 2004.
The exhibits, which include wall paintings, tombs, ceramics,
metalwork, armour and weapons, mirrors and everyday items, are all
presented in colour photographs with a full description. Background
essays place the objects in their setting, discussing Etruscan
culture, grave goods, wall paintings and tombs and Etruscan
archaeology.
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