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Os Organoosmium Compounds (Paperback, 8th ed. 1995. Softcover reprint of the original 8th ed. 1995)
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Os Organoosmium Compounds (Paperback, 8th ed. 1995. Softcover reprint of the original 8th ed. 1995)
Series: Os. Osmium (System-Nr. 66), O-s / a- / B / 4 / a
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The GmeLin series "Organometallic Compounds" comprises compounds
containing at least one carbon-to-metal bond (except cyano
compounds, which are considered inorganic). It includes all
information in scientific journals, but patents, conference
reports, and disserta- tions generally were not reviewed. The
volumes published so far are listed on p. V/' Organometallic
compounds are classified according to their nuclearity and the
bonding mode of the organic ligands nL. Nuclearity means the number
of atoms of the title metal in the formula unit disregarding any
additional metals that may be present. The term nL designates a
ligand bonded by n carbon atoms to one or different atoms of the
title metal. As usual, a-bonded 1 L ligands are designated by R.
Inorganic ligands (Le., ligands bonded exclusively by elements
other than carbon) are generally designated by 0 or X. 0 means
donor ligands such as pyridine or phosphanes; m-electron donors are
specified by mO. X is reserved for negatively charged ligands or
other one-electron donors such as halogens or SnR; bridging X
ligands may donate one 3 2 2 2 (~-H), three (~-Cl, ~-OR), or five
(~3-1) electrons. Terms such as lL_ 0, 20-X, or 20_ 0_ 0 may be
used for multidentate ligands. Heterometals are often designated by
M, and bridging elements, bridging groups, or nonmetallic cluster
constituents by E. The symbols 1] and ~ follow the IUPAC
nomenclature.
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