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The majority of this book was written in 1983-84 while the senior author was a Visiting Scientist at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee. We believe that the approach to the problem of acid deposition effects on soils and waters developed during this collaboration contains ele ments that are significantly different from most prior work in this area. Some of the material and the software used in the development of these concepts stem from earlier individual efforts of the authors. However, what we believe to be the more significant concepts concerning the processes by which alkalinity may be developed in acid soil solutions, and by which acid deposition may contrib ute to the loss of this alkalinity, were the result of this collaboration. The ultimate usefulness of these concepts in understanding and dealing with various aspects of the problems associated with acid deposition cannot be adequately gauged at the present time. They must first withstand tests of con sistency with available observation, and of direct experimentation. It is our hope that dissemination through this book will facilitate this process within the scientific community. The authors wish to thank the administration of the Environmental Science Division at ORNL, and the College of Agricultural Sciences at Colorado State University for their support in arranging this collaboration. We also wish to express our appreciation for the financial support provided by EPA. Personal thanks are due to Dr."
This book documents CCPS's Aerosol Research Program to develop a model to predict liquid rainout from release of a pressurized, liquefied gas--and, hence the residual amount of material in a vapor cloud, which may be greater than the amount calculated from an enthalpy chart. RELEASE predicts the rate of fluid discharge, the depressurization, flashing and formation of liquid drops, the entrainment of drops into the vapor cloud, the subsequent spreading of the jet, and rate of liquid rainout to a pool on the ground. Designed in a modular fashion to permit adjustment and corrections as new data become available, its multi-layered approach contains sub-models that include the complexities of many variables, including the effect of liquid superheat, rate of bubble growth, criterion for bubble formation, and heat transfer from the liquid to the growing vapor bubble. To validate RELEASE, CCPS conducted small- and large-scale experiments using superheated water, heated liquefied chlorine, methylamine, and cyclohexane that produced valuable data in an area where data are scarce. This book gives complete access, in text and on CD-ROM, to the model and the test data, giving users an informed ability to apply the model to their own work.
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