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This book takes an interface science approach to describe and
understand the behavior of the dispersions we call emulsions,
microemulsions and foams. The one thing all these dispersions have
in common is the presence of surface-active species (surfactants)
adsorbed at the interfaces between the two fluid phases that make
up the emulsions, microemulsions or foams. The interfacial layers
formed by the surfactants control most of the properties of the
dispersions. The book describes the properties of interfacial
layers, thin films and bulk fluids used in the elaboration of the
various dispersions and it explains how such properties relate to
the dispersion properties of these soft matter systems: structure,
rheology and stability. These dispersion properties are far from
being fully understood, in particular foam and emulsion stability.
In discussing the state of the art of the current knowledge, the
author draws interesting parallels between emulsions,
microemulsions and foams that enlighten the interpretation of
previous observations and point to a deeper understanding of the
behavior of these materials in the future.
This book takes an interface science approach to describe and
understand the behavior of the dispersions we call emulsions,
microemulsions and foams. The one thing all these dispersions have
in common is the presence of surface-active species (surfactants)
adsorbed at the interfaces between the two fluid phases that make
up the emulsions, microemulsions or foams. The interfacial layers
formed by the surfactants control most of the properties of the
dispersions. The book describes the properties of interfacial
layers, thin films and bulk fluids used in the elaboration of the
various dispersions and it explains how such properties relate to
the dispersion properties of these soft matter systems: structure,
rheology and stability. These dispersion properties are far from
being fully understood, in particular foam and emulsion stability.
In discussing the state of the art of the current knowledge, the
author draws interesting parallels between emulsions,
microemulsions and foams that enlighten the interpretation of
previous observations and point to a deeper understanding of the
behavior of these materials in the future.
"Amphiphilic layers" play essential roles in the behaviour of a
great variety of disperse systems such as micelles, microemulsions
and vesicles. They can also exist as isolated mono- or bilayers, or
constitute extended liquid crystalline structures. Although the
properties of these different systems may at first sight seem
unrelated, theoretical interpretations of them depend on several
common concepts. This was the reason for bringing together
scientists working in this area for the International Winter School
on the Physics of Amphiphilic Layers, which was held at Les
Houches, 10-18 February, 1987. The topics treated in the
proceedings volume are mono- and bilayers, interactive forces
between layers (with special emphasis on steric forces), ordered
structures (in particular swollen lamellar phases and defects),
vesicles, micelles (including polymer-like systems), microemulsions
(especially random bicontinuous structures) and porous media. The
importance of thermal fluctuations in the amphiphilic layers is
stressed. Recent results are presented and literature references
allow readers not familiar with the subject to find any background
information they require.
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