In this new textbook on physical chemistry, fundamentals are introduced simply yet in more depth than is common. Topics are arranged in a progressive pattern, with simpler theory early and more complicated theory later. General principles are induced from key experimental results. Some mathematical background is supplied where it would be helpful. Each chapter includes worked-out examples and numerous references. Extensive problems, review, and discussion questions are included for each chapter. More detail than is common is devoted to the nature of work and heat and how they differ. Introductory Caratheodory theory and the standard integrating factor for dGrev are carefully developed. The fundamental role played by uncertainty and symmetry in quantum mechanics is emphasized. In chemical kinetics, various methods for determined rate laws are presented. The key mechanisms are detailed. Considerable statistical mechanics and reaction rate theory are then surveyed. Professor Duffey has given us a most readable, easily followed text in physical chemistry.

In this new textbook on physical chemistry, fundamentals are introduced simply yet in more depth than is common. Topics are arranged in a progressive pattern, with simpler theory early and more complicated theory later. General principles are induced from key experimental results. Some mathematical background is supplied where it would be helpful. Each chapter includes worked-out examples and numerous references. Extensive problems, review, and discussion questions are included for each chapter. More detail than is common is devoted to the nature of work and heat and how they differ. Introductory Caratheodory theory and the standard integrating factor for dGrev are carefully developed. The fundamental role played by uncertainty and symmetry in quantum mechanics is emphasized. In chemical kinetics, various methods for determined rate laws are presented. The key mechanisms are detailed. Considerable statistical mechanics and reaction rate theory are then surveyed. Professor Duffey has given us a most readable, easily followed text in physical chemistry.

The theory of quantum mechanics continues to appear arbitrary and abstruse to new students; and to many veterans, it has become acceptable and useable only because it is familiar. Yet, this theory is at the basis of all modern physics, chem istry, and engineering, describing, as it does, the behavior of the submicroscopic particles making up all matter. So it needs to be presented more effectively to a diverse audience. The primary question is, I believe, 'What can be considered self-evident?' Indeed, what do certain key experiments reveal about the workings of nature? How can we consider that some probabilities are not a result of our ignorance, but instead, fundamental properties? We must pay particular attention to the subject of what we can do, what we cannot do, and what we can and cannot observe. We can prepare a homogeneous beam of almost independent particles by boiling electrons out of a metal and accelerating them by a given potential drop. We cannot follow an electron in dividually in the beam without introducing conditions that destroy the beam's homogeneity, but we can detennine when electrons arrive at a given position."