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The objective of this book is to provide an up-to-date
comprehensive descr- tion of the Kamimura-Suwa model, which is the
?rst of the present rep- sentative two-component theories in high
temperature superconductivity. In 1986 George Bednorz and Karl Alex
Muller .. made the remarkable discovery
ofsuperconductivitywithanunbelievinglyhighvalueofT = 35K,bysubs- c
2+ 3+ tuting Ba ions for La ions in the antiferromagnetic insulator
La CuO . 2 4 Soon after this discoveryT rose to 90K by synthesizing
YBa Cu O with c 2 3 7?? ade?citinoxygen.
Furtherexplorationfornewcopperoxidesuperconducting materials with
higherT led to the discovery of Bi-Sr-Ca-Cu-O, Tl-Ba-Ca- c Cu-O and
Hg-Ba-Ca-Cu-O compounds in subsequent years. The new class of
copper oxide compounds mentioned above is called "cuprates". At
present T = 135K under ambient pressure andT = 164K under 31 GPa
observed c c in HgBa Ca Cu O are the highest value so far obtained.
The Kamimura- 2 2 3 8 Suwa model, which was originally developed in
1993, is a theory of these real copper oxide superconducting
materials. Since undoped La CuO is a 2 4 Mott-Hubbard
antiferromagnetic insulator, its electronic structure can not
beexplained bytheordinaryone-electron energybandtheory.
Inthiscontext the important role of electron-correlation was
pointed out. 2+ On theother hand, ad-hole state in each Cu ion in
theligand ?eld with octahedral symmetry is orbitally
doubly-degenerate so that it is subject to strong Jahn-Teller
interaction in La CuO. Asaresult,aCuO octahedron 2 4 6 in La CuO is
elongated along thec-axis due to the Jahn-Teller distortion.
The behaviour of electrons in systems without periodicity is one of
the most fascinating areas in solid-state physics, and the last 25
years have seen an enormous increase in research in this field.
This has given rise to many new ideas for understanding electronic
states in disordered systems, especially the study of the
degenerate electron gas in which electron-electron interactions are
important. This book provides a much needed survey of these
advances. In the first part of the book, the authors discuss
impurity bands in three dimensions. Attention is focused on the
regime in which the electrons are spatially localized rather than
free, so that an interesting interplay of localization and
interaction arises. In the second part of the book, they look at
the outstanding features of the two-dimensional systems, explaining
how these make the localization problem special and interesting.
The authors have provided a clear outline of the theoretical
picture for the chosen materials and description heuristic. Each
chapter is self-contained, allowing readers to pursue their special
interests.
Since the discovery by Bednorz and Muller of Cu-O alloys displaying
high temperature superconductivity, great energy has been put into
research in this field. One of the most important and interesting
issues, and the subject of this volume, is the clarification of the
microscopic origin and mechanism of high temperature
superconductivity. This book discusses the latest experimental
results on magnetic, optical, electrical, thermal and mechanical
properties of the Cu-O and Bi-O superconductors, as well as
proposed theoretical models of the mechanisms. The participants in
the symposium agreed that for the high Tc Cu-O superconductors
electron correlation effects are of central importance. For the
Bi-O superconductors the main topic was whether the mechanism of
superconductivity is the same as that of high Tc Cu-O
superconductors. What was and what was not resolved at the
symposium is summarized at the end of the volume.
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