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The unique properties and applications of transition metal
compounds have long fascinated both physicists and chemists. This
volume presents theoretical and experimental studies for a deeper
understanding of the electronic and vibronic properties of these
compounds. In particular, an introduction into properties of spin
sublevels of dd*, dA*, and AA* states is given, and a modern ligand
field theory based on the Angular Overlap Model is presented. In
experimental case studies it is shown how to characterize different
types of electronic transitions using modern methods of laser
spectroscopy. Consequences of spin-orbit coupling, zero-field
splittings, spin-lattice relaxations, chromophore-matrix
interactions, Herzberg-Teller/Franck-Condon activities, and
localization/delocalization properties are treated.
The unique properties and applications of transition metal
compounds have long fascinated both physicists and chemists. This
volume presents theoretical and experimental studies for a deeper
understanding of the electronic and vibronic properties of these
compounds. In particular, an introduction into properties of spin
sublevels of dd*, dA*, and AA* states is given, and a modern ligand
field theory based on the Angular Overlap Model is presented. In
experimental case studies it is shown how to characterize different
types of electronic transitions using modern methods of laser
spectroscopy. Consequences of spin-orbit coupling, zero-field
splittings, spin-lattice relaxations, chromophore-matrix
interactions, Herzberg-Teller/Franck-Condon activities, and
localization/delocalization properties are treated.
Databases have revolutionized nearly every aspect of our lives.
Information of all sorts is being collected on a massive scale,
from Google to Facebook and well beyond. But as the amount of
information in databases explodes, we are forced to reassess our
ideas about what knowledge is, how it is produced, to whom it
belongs, and who can be credited for producing it. Every scientist
working today draws on databases to produce scientific knowledge.
Databases have become more common than microscopes, voltmeters, and
test tubes, and the increasing amount of data has led to major
changes in research practices and profound reflections on the
proper professional roles of data producers, collectors, curators,
and analysts. Collecting Experiments traces the development and use
of data collections, especially in the experimental life sciences,
from the early twentieth century to the present. It shows that the
current revolution is best understood as the coming together of two
older ways of knowing--collecting and experimenting, the museum and
the laboratory. Ultimately, Bruno J. Strasser argues that by
serving as knowledge repositories, as well as indispensable tools
for producing new knowledge, these databases function as digital
museums for the twenty-first century.
In diesem Buch wird ein "synergetisches Management" entwickelt,
welches durch die Zusammenfuhrung von Erkenntnissen der
Systemtheorie und der Ethik die Einbindung der Okologie in die
strategische Unternehmensfuhrung garantieren soll."
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