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Electronic and Vibronic Spectra of Transition Metal Complexes II (Hardcover, 1997 ed.)
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Electronic and Vibronic Spectra of Transition Metal Complexes II (Hardcover, 1997 ed.)
Series: Topics in Current Chemistry, 191
Expected to ship within 12 - 17 working days
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The unique properties and applications of transition metal
compounds have long fascinated both physicists and chemists. This
volume presents theoretical and experimental studies for a deeper
understanding of the electronic and vibronic properties of these
compounds. In particular, an introduction into properties of spin
sublevels of dd*, dA*, and AA* states is given, and a modern ligand
field theory based on the Angular Overlap Model is presented. In
experimental case studies it is shown how to characterize different
types of electronic transitions using modern methods of laser
spectroscopy. Consequences of spin-orbit coupling, zero-field
splittings, spin-lattice relaxations, chromophore-matrix
interactions, Herzberg-Teller/Franck-Condon activities, and
localization/delocalization properties are treated.
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