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A series of critical reviews and perspectives focussing on specific
aspects of organometallic chemistry interfacing with other fields
of study are provided. For this volume, the critical reviews cover
topics such as the activation of "inert" carbon-hydrogen bonds,
ligand design and organometallic radical species. For example,
Charlie O'Hara discusses how mixed-metal compounds may perform the
highly selective activation of C-H bonds and, in particular, how
synergic relationships between various metals are crucial to this
approach. The chemistry of a remarkable series of air-stable chiral
primary phosphine ligands is discussed in some depth by Rachel
Hiney, Arne Ficks, Helge M(3)ller-Bunz, Declan Gilheany and Lee
Higham. This article focuses on the preparation of these ligands
and also how they may be applied in various catalytic applications.
Bas De Bruin reports on how ligand radical reactivity can be
employed in synthetic organometallic chemistry and catalysis to
achieve selectivity in radical-type transformations. As well as
highlighting ligand-centered radical transformations in open-shell
transition metals, an overview of the catalytic mechanism of
Co(II)-catalysed olefin cyclopropanation is given, showing that
enzyme-like cooperative metal-ligand-radical reactivity is no
longer limited to real enzymes. Valuable and informative
comprehensive reviews in the field of organometallic chemistry are
also covered in this volume. For example, organolithium and
organocuprate chemistry are reviewed by Joanna Haywood and Andrew
Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds
by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by
Mark Humphrey and Marie Cifuentes; and recent developments in the
chemistry of the elements of Group 14 - focusing on
low-coordination number compounds by Richard Layfield. This volume
therefore covers many synthetic and applied aspects of modern
organometallic chemistry which ought to be of interest to
inorganic, organic and applied catalysis fields.
With the increase in volume, velocity and variety of information,
researchers can find it difficult to keep up to date with the
literature in their field. This interdisciplinary field has the
potential to provide answers to problems and challenges faced in
catalysis, synthetic organic chemistry and the development of
therapeutic agents and new materials. Providing an invaluable
volume, Organometallic Chemistry Volume 41 contains analysed,
evaluated and distilled information on the latest in organometallic
chemistry research including developments and applications of Lewis
acidic boron reagents, masked low-coordinate main group species in
synthesis and the diiron centre.
A series of critical reviews and perspectives focussing on specific
aspects of organometallic chemistry interfacing with other fields
of study are provided. For this volume, the critical reviews cover
topics such as the activation of "inert" carbon-hydrogen bonds,
ligand design and organometallic radical species. For example,
Charlie O'Hara discusses how mixed-metal compounds may perform the
highly selective activation of C-H bonds and, in particular, how
synergic relationships between various metals are crucial to this
approach. The chemistry of a remarkable series of air-stable chiral
primary phosphine ligands is discussed in some depth by Rachel
Hiney, Arne Ficks, Helge M(3)ller-Bunz, Declan Gilheany and Lee
Higham. This article focuses on the preparation of these ligands
and also how they may be applied in various catalytic applications.
Bas De Bruin reports on how ligand radical reactivity can be
employed in synthetic organometallic chemistry and catalysis to
achieve selectivity in radical-type transformations. As well as
highlighting ligand-centered radical transformations in open-shell
transition metals, an overview of the catalytic mechanism of
Co(II)-catalysed olefin cyclopropanation is given, showing that
enzyme-like cooperative metal-ligand-radical reactivity is no
longer limited to real enzymes. Valuable and informative
comprehensive reviews in the field of organometallic chemistry are
also covered in this volume. For example, organolithium and
organocuprate chemistry are reviewed by Joanna Haywood and Andrew
Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds
by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by
Mark Humphrey and Marie Cifuentes; and recent developments in the
chemistry of the elements of Group 14 - focusing on
low-coordination number compounds by Richard Layfield. This volume
therefore covers many synthetic and applied aspects of modern
organometallic chemistry which ought to be of interest to
inorganic, organic and applied catalysis fields.
A series of critical reviews and perspectives focussing on specific
aspects of organometallic chemistry interfacing with other fields
of study are provided. For this volume, the critical reviews cover
topics such as the activation of "inert" carbon-hydrogen bonds,
ligand design and organometallic radical species. For example,
Charlie O'Hara discusses how mixed-metal compounds may perform the
highly selective activation of C-H bonds and, in particular, how
synergic relationships between various metals are crucial to this
approach. The chemistry of a remarkable series of air-stable chiral
primary phosphine ligands is discussed in some depth by Rachel
Hiney, Arne Ficks, Helge M(3)ller-Bunz, Declan Gilheany and Lee
Higham. This article focuses on the preparation of these ligands
and also how they may be applied in various catalytic applications.
Bas De Bruin reports on how ligand radical reactivity can be
employed in synthetic organometallic chemistry and catalysis to
achieve selectivity in radical-type transformations. As well as
highlighting ligand-centered radical transformations in open-shell
transition metals, an overview of the catalytic mechanism of
Co(II)-catalysed olefin cyclopropanation is given, showing that
enzyme-like cooperative metal-ligand-radical reactivity is no
longer limited to real enzymes. Valuable and informative
comprehensive reviews in the field of organometallic chemistry are
also covered in this volume. For example, organolithium and
organocuprate chemistry are reviewed by Joanna Haywood and Andrew
Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds
by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by
Mark Humphrey and Marie Cifuentes; and recent developments in the
chemistry of the elements of Group 14 - focusing on
low-coordination number compounds by Richard Layfield. This volume
therefore covers many synthetic and applied aspects of modern
organometallic chemistry which ought to be of interest to
inorganic, organic and applied catalysis fields.
Organometallic chemistry is an interdisciplinary science which
continues to grow at a rapid pace. Although there is continued
interest in synthetic and structural studies, the last decade has
seen a growing interest in the potential of organometallic
chemistry to provide answers to problems in catalysis, synthetic
organic chemistry and also in the development of new materials.
Each volume in the series is published either annually or
biennially and is a superb reference point for researchers.
Organometallic chemistry is an interdisciplinary science which
continues to grow at a rapid pace. Although there is continued
interest in synthetic and structural studies the last decade has
seen a growing interest in the potential of organometallic
chemistry to provide answers to problems in catalysis synthetic
organic chemistry and also in the development of new materials.
This Specialist Periodical Report aims to reflect these current
interests reviewing progress in theoretical organometallic
chemistry, main group chemistry, the lanthanides and all aspects of
transition metal chemistry.
Organometallic chemistry is an interdisciplinary science which
continues to grow at a rapid pace. Although there is continued
interest in synthetic and structural studies the last decade has
seen a growing interest in the potential of organometallic
chemistry to provide answers to problems in catalysis, synthetic
organic chemistry and also in the development of new materials.
This Specialist Periodical Report aims to reflect these current
interests, reviewing progress in theoretical organometallic
chemistry, main group chemistry, the lanthanides and all aspects of
transition metal chemistry. Volume 31 covers literature published
during 2002. Specialist Periodical Reports provide systematic and
detailed review coverage in major areas of chemical research.
Compiled by teams of leading authorities in the relevant subject
areas, the series creates a unique service for the active research
chemist, with regular, in-depth accounts of progress in particular
fields of chemistry. Subject coverage within different volumes of a
given title is similar and publication is on an annual or biennial
basis.
Organometallic chemistry is an interdisciplinary science which
continues to grow at a rapid pace. Although there is continued
interest in synthetic and structural studies the last decade has
seen a growing interest in the potential of organometallic
chemistry to provide answers to problems in catalysis, synthetic
organic chemistry and also in the development of new materials.
This Specialist Periodical Report aims to reflect these current
interests, reviewing progress in theoretical organometallic
chemistry, main group chemistry, the lanthanides and all aspects of
transition metal chemistry. Volume 31 covers literature published
during 2001. Specialist Periodical Reports provide systematic and
detailed review coverage in major areas of chemical research.
Compiled by teams of leading authorities in the relevant subject
areas, the series creates a unique service for the active research
chemist, with regular, in-depth accounts of progress in particular
fields of chemistry. Subject coverage within different volumes of a
given title is similar and publication is on an annual or biennial
basis.
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