This book explores the conversion for solar energy into renewable liquid fuels through electrochemical reactions. The first section of the book is devoted to the theoretical fundamentals of solar fuels production, focusing on the surface properties of semiconductor materials in contact with aqueous solutions and the reaction mechanisms. The second section describes a collection of current, relevant characterization techniques, which provide essential information of the band structure of the semiconductors and carrier dynamics at the interface semiconductor. The third, and last section comprises the most recent developments in materials and engineered structures to optimize the performance of solar-to-fuel conversion devices.

Research on advanced energy conversion devices such as solar cells has intensified in the last two decades. A broad landscape of candidate materials and devices were discovered and systematically studied for effective solar energy conversion and utilization. New concepts have emerged forming a rather powerful picture embracing the mechanisms and limitation to efficiencies of different types of devices. The Physics of Solar Energy Conversion introduces the main physico-chemical principles that govern the operation of energy devices for energy conversion and storage, with a detailed view of the principles of solar energy conversion using advanced materials. Key Features include: Highlights recent rapid advances with the discovery of perovskite solar cells and their development. Analyzes the properties of organic solar cells, lithium ion batteries, light emitting diodes and the semiconductor materials for hydrogen production by water splitting. Embraces concepts from nanostructured and highly disordered materials to lead halide perovskite solar cells Takes a broad perspective and comprehensively addresses the fundamentals so that the reader can apply these and assess future developments and technologies in the field. Introduces basic techniques and methods for understanding the materials and interfaces that compose operative energy devices such as solar cells and solar fuel converters.

Research on advanced energy conversion devices such as solar cells has intensified in the last two decades. A broad landscape of candidate materials and devices were discovered and systematically studied for effective solar energy conversion and utilization. New concepts have emerged forming a rather powerful picture embracing the mechanisms and limitation to efficiencies of different types of devices. The Physics of Solar Energy Conversion introduces the main physico-chemical principles that govern the operation of energy devices for energy conversion and storage, with a detailed view of the principles of solar energy conversion using advanced materials. Key Features include: Highlights recent rapid advances with the discovery of perovskite solar cells and their development. Analyzes the properties of organic solar cells, lithium ion batteries, light emitting diodes and the semiconductor materials for hydrogen production by water splitting. Embraces concepts from nanostructured and highly disordered materials to lead halide perovskite solar cells Takes a broad perspective and comprehensively addresses the fundamentals so that the reader can apply these and assess future developments and technologies in the field. Introduces basic techniques and methods for understanding the materials and interfaces that compose operative energy devices such as solar cells and solar fuel converters.

The book provides an explanation of the operation of photovoltaic devices from a broad perspective that embraces a variety of materials concepts, from nanostructured and highly disordered organic materials, to highly efficient devices such as the lead halide perovskite solar cells. The book establishes from the beginning a simple but very rich model of a solar cell, in order to develop and understand step by step the photovoltaic operation according to fundamental physical properties and constraints. It emphasizes the aspects pertaining to the functioning of a solar cell and the determination of limiting efficiencies of energy conversion. The final chapters of the book establish a more refined and realistic treatment of the many factors that determine the actual performance of experimental devices: transport gradients, interfacial recombination, optical losses and so forth. The book finishes with a short review of additional important aspects of solar energy conversion, such as the photonic aspects of spectral modification, and the direct conversion of solar photons to chemical fuel via electrochemical reactions.

This book explores the conversion for solar energy into renewable liquid fuels through electrochemical reactions. The first section of the book is devoted to the theoretical fundamentals of solar fuels production, focusing on the surface properties of semiconductor materials in contact with aqueous solutions and the reaction mechanisms. The second section describes a collection of current, relevant characterization techniques, which provide essential information of the band structure of the semiconductors and carrier dynamics at the interface semiconductor. The third, and last section comprises the most recent developments in materials and engineered structures to optimize the performance of solar-to-fuel conversion devices.