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In this work aggression and conflict in man and other primates are
interpreted in the light of evolutionary biology and game theory
models.Unitlnow interdisciplinary collaboration between the
humanities and the natural sciences has been rare and hampered by
different methodologies and terminology. Nevertheless, such
cooperation is essential for elucidating the causes and
consequences of aggression in humans and in explaining what shape
aggression takes in particular situations. The aim of this volume
is to present empirical and theoretical studies from biologists and
social scientists to create an interdisciplinary framework for
understanding aggression.
The papers collected in this volume have been presented during a
workshop on "Electron-Atom and Molecule Collisions" held at the
Centre for Interdisciplinary Studies of the University of Bielefeld
in May 1980. This workshop, part of a larger program concerned with
the "Properties and Reactions of Isolated Molecules and Atoms,"
focused on the theory and computational techniques for the quanti
tative description of electron scattering phenomena. With the
advances which have been made in the accurate quantum mechanical
characterisation of bound states of atoms and molecules, the more
complicated description of the unbound systems and resonances
important in electron collision processes has matured too. As expli
cated in detail in the articles of this volume, the theory for the
quantitative explanation of elastic and inelastic electron molecule
collisions, of photo- and multiple photon ionization and even for
electron impact ionization is well developed in a form which lends
itself to a complete quantitative ab initio interpretation and pre
diction of the observable effects. Many of the experiences gained
and the techniques which have evolved over the years in the com
putational characterization of bound states have become an
essential basis for this development. To be sure, much needs to be
done before we have a complete and detailed theoretical
understanding of the known collisional processes and of the
phenomena and effects, which may still be un covered with the
continuing refinement of the experimental tech niques."
The papers collected in this volume have been presented during a
workshop on "Electron-Atom and Molecule Collisions" held at the
Centre for Interdisciplinary Studies of the University of Bielefeld
in May 1980. This workshop, part of a larger program concerned with
the "Properties and Reactions of Isolated Molecules and Atoms,"
focused on the theory and computational techniques for the quanti
tative description of electron scattering phenomena. With the
advances which have been made in the accurate quantum mechanical
characterisation of bound states of atoms and molecules, the more
complicated description of the unbound systems and resonances
important in electron collision processes has matured too. As expli
cated in detail in the articles of this volume, the theory for the
quantitative explanation of elastic and inelastic electron molecule
collisions, of photo- and multiple photon ionization and even for
electron impact ionization is well developed in a form which lends
itself to a complete quantitative ab initio interpretation and pre
diction of the observable effects. Many of the experiences gained
and the techniques which have evolved over the years in the com
putational characterization of bound states have become an
essential basis for this development. To be sure, much needs to be
done before we have a complete and detailed theoretical
understanding of the known collisional processes and of the
phenomena and effects, which may still be un covered with the
continuing refinement of the experimental tech niques.
We characterize an isolated molecule by its compos t on, i.e. the
number and types of atoms forming the molecule, its structure, i.e.
the geometrical arrangement of the composite atoms with respect to
each other, and its possible, i.e. quantum mechanically allowed,
stationary energy states. Conceptually we separate the latter,
being aware that this is an approximation, into electronic,
vibrational and rotational states, including fine and hyperfine
structure splittings. To be sure, there is an intimate relation
between molecular structure and molecular energy states, in fact it
is this relation we use, when we obtain structural information
through spectroscopy, where we determine transitions between
various stationary states of the molecule. The concepts above have
proven extremely useful in chemistry and spectroscopy, however, the
awareness of the limitations of these concepts has grown in recent
years with the increasing recognition of (i) fluctional molecules,
(ii) multiphoton absorption processes and (iii) influences due to
the surroundings on "isolated" molecules.
During the last thirty years, with the development of high speed
electronic computers, methods have evolved, which permit an
accurate and quantitative, ab initio determina tion of the
electronic wavefunctions of atoms and molecules. Thus a detailed
elucida tion of the electronic energy and structure of molecules
has become possible using quantum mechanics directly. Ho\ ever, it
is necessary, if such calculations are to yield accurate and
reliable results, to include electron correlation explicitely,
which requires in general . configuration mixing procedures with an
extremely large 5 number of configurations, of the order of 10
configurations. With eigenvalue problems of this size, the limits
of even the largest and fastest computers are reached rapidly, and
their solution has become possible only, because direct methods
have been deve loped which permit the determination of eigenvalues
and eigenvectors for such large matrices iteratively without
constructing the energy matrix explicitely. These direct methods
had been limited to the description of closed shell systems, i. e.
systems with a single dominant closed shell reference determinant.
This limitation arose, because with an open shell reference or with
several reference determinants, no procedures were known, which
allowed a rapid calculation of the energy matrix elements between
configurations with general and widely different spin couplings,
which would be necessary. Recently such methods have been
developed, based on early work of Gelfand, Biedenharn and Moshinski
using a unitary group representation of different spin coupled
states; Paldus achieved an extremely compact description."
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