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The?rsttwovolumesinthis"TemplatesinChemistry"serieshavefocused on
templates that controlsolution-phase reactions. Among the templates
d- cussed in these two volumes were convex and concave templates
that mediate the formation of (macro)cyclic molecules and
mechanically bound molecules withtheir intriguingintertwined
topology.Also,three-dimensional templates that are used to imprint
polymers and that organize compounds in the solid state for
predestined reactions have been included in the earlier volumes. In
the present volume, we extend thetemplate topologytosurfaces that
act
asmatricesforthecontrolledgrowthoftwo-dimensionalarrays.Naturally,the
typical methods for the characterization of surfaces such as
scanning probe microscopyare prominently represented in this
volume.
Differentlateralinteractionssuchascoordinativebondsorhydrogenbo-
ing play a major role in assembling the 2D networks on surfaces in
addition to the interaction of the samples with the underlying
substrates. Many p- nomena that are also encountered in solution
can be directly visualized on surfaces: Reversible self-assembly
processes lead to the formation of large structures through
multiple recognition of small building blocks and cul- nate in the
engineering of crystals in two dimensions. Self-sorting processes
drive the formation of highly ordered arrays through the geometric
?t of the available components. Either the surface itself is the
template, for example, when clusters grow on metal oxide ?lms, or
colloidal templates control the formationof
macroporousnetworksonthe substrate. This volume highlightsa
selection of actual complementary aspects of s-
facetemplates.Webelievethatthescopeandthevarietyoftopicscoveredinthis
volume will attract readers fromdifferent communities such as
supramole-
larchemistry,materialsciences,surfacechemistry,surfacephysicsandsurface
technologyandwehopetheywillenjoythisnewvolumeonTemplatesinCh-
istry.
Metal carbene complexes have made their way from organometallic
curiosities to valuable reagents and catalysts. They offer novel
synthetic opportunities in carbon carbon bond formation based on
either carbene-centered reactions or on metal-templated processes
which makes them indispensable in modern synthetic methodology. The
most prominent metal carbenes are now either commercially available
or easy to synthesize and handle by modern laboratory techniques.
This volume organized in eight chapters written by the leading
scientists in the field illustrates the theoretical background,
non-classical nucleophilic and cycloaddition patterns,
chromium-templated benzannulation and photo-induced reactions,
rhodium-catalyzed carbene transfer as well as the principles and
applications of olefin metathesis which coined the progress in
synthetic methodology over the past decade. Designed for
researchers in academia and industry as well as graduate students
it presents the state-of-the-art potential of carbene complexes in
modern organic synthesis.
The?rsttwovolumesinthis"TemplatesinChemistry"serieshavefocused on
templates that controlsolution-phase reactions. Among the templates
d- cussed in these two volumes were convex and concave templates
that mediate the formation of (macro)cyclic molecules and
mechanically bound molecules withtheir intriguingintertwined
topology.Also,three-dimensional templates that are used to imprint
polymers and that organize compounds in the solid state for
predestined reactions have been included in the earlier volumes. In
the present volume, we extend thetemplate topologytosurfaces that
act
asmatricesforthecontrolledgrowthoftwo-dimensionalarrays.Naturally,the
typical methods for the characterization of surfaces such as
scanning probe microscopyare prominently represented in this
volume.
Differentlateralinteractionssuchascoordinativebondsorhydrogenbo-
ing play a major role in assembling the 2D networks on surfaces in
addition to the interaction of the samples with the underlying
substrates. Many p- nomena that are also encountered in solution
can be directly visualized on surfaces: Reversible self-assembly
processes lead to the formation of large structures through
multiple recognition of small building blocks and cul- nate in the
engineering of crystals in two dimensions. Self-sorting processes
drive the formation of highly ordered arrays through the geometric
?t of the available components. Either the surface itself is the
template, for example, when clusters grow on metal oxide ?lms, or
colloidal templates control the formationof
macroporousnetworksonthe substrate. This volume highlightsa
selection of actual complementary aspects of s-
facetemplates.Webelievethatthescopeandthevarietyoftopicscoveredinthis
volume will attract readers fromdifferent communities such as
supramole-
larchemistry,materialsciences,surfacechemistry,surfacephysicsandsurface
technologyandwehopetheywillenjoythisnewvolumeonTemplatesinCh-
istry.
Metal carbene complexes have made their way from organometallic
curiosities to valuable reagents and catalysts. They offer novel
synthetic opportunities in carbon carbon bond formation based on
either carbene-centered reactions or on metal-templated processes
which makes them indispensable in modern synthetic methodology. The
most prominent metal carbenes are now either commercially available
or easy to synthesize and handle by modern laboratory techniques.
This volume organized in eight chapters written by the leading
scientists in the field illustrates the theoretical background,
non-classical nucleophilic and cycloaddition patterns,
chromium-templated benzannulation and photo-induced reactions,
rhodium-catalyzed carbene transfer as well as the principles and
applications of olefin metathesis which coined the progress in
synthetic methodology over the past decade. Designed for
researchers in academia and industry as well as graduate students
it presents the state-of-the-art potential of carbene complexes in
modern organic synthesis.
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