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Templates in Chemistry III (Paperback, 2009 ed.)
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Templates in Chemistry III (Paperback, 2009 ed.)
Series: Topics in Current Chemistry, 287
Expected to ship within 10 - 15 working days
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The?rsttwovolumesinthis"TemplatesinChemistry"serieshavefocused on
templates that controlsolution-phase reactions. Among the templates
d- cussed in these two volumes were convex and concave templates
that mediate the formation of (macro)cyclic molecules and
mechanically bound molecules withtheir intriguingintertwined
topology.Also,three-dimensional templates that are used to imprint
polymers and that organize compounds in the solid state for
predestined reactions have been included in the earlier volumes. In
the present volume, we extend thetemplate topologytosurfaces that
act
asmatricesforthecontrolledgrowthoftwo-dimensionalarrays.Naturally,the
typical methods for the characterization of surfaces such as
scanning probe microscopyare prominently represented in this
volume.
Differentlateralinteractionssuchascoordinativebondsorhydrogenbo-
ing play a major role in assembling the 2D networks on surfaces in
addition to the interaction of the samples with the underlying
substrates. Many p- nomena that are also encountered in solution
can be directly visualized on surfaces: Reversible self-assembly
processes lead to the formation of large structures through
multiple recognition of small building blocks and cul- nate in the
engineering of crystals in two dimensions. Self-sorting processes
drive the formation of highly ordered arrays through the geometric
?t of the available components. Either the surface itself is the
template, for example, when clusters grow on metal oxide ?lms, or
colloidal templates control the formationof
macroporousnetworksonthe substrate. This volume highlightsa
selection of actual complementary aspects of s-
facetemplates.Webelievethatthescopeandthevarietyoftopicscoveredinthis
volume will attract readers fromdifferent communities such as
supramole-
larchemistry,materialsciences,surfacechemistry,surfacephysicsandsurface
technologyandwehopetheywillenjoythisnewvolumeonTemplatesinCh-
istry.
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