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Success comes in many forms and in synthesis it can be a failure
that results in their ultimate successful solutions. This
long-awaited sequel to "Dead Ends and Detours" retains the proven
concept while featuring over 20 new case studies of failed
strategies and their (successful) solutions in natural product
total synthesis. Additionally, computational models are used to
discuss the problem in much more detail and to provide readers with
additional information not found in the primary literature. The
topics range from classic synthetic reactions (e.g. Diels Alder
reaction), metal-mediated coupling reactions, metathesis, and
asymmetric catalysis to the importance of protecting and activating
groups.
A plethora of publications provide valuable information for the
organic chemist, yet the results are almost always based on
successful reactions. However, a chemist's life is unfortunately
not that easy. On the contrary, trial and error is still one of the
most commonly used methods. Thus it would be useful to have access
to those syntheses that do not work, since they also provide
important results of great importance for further synthesis.
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