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Polyoxometalate-Based Hybrids and their Applications focuses on
recent progress in polyoxometalate-based hybrids materials.
Chapters present the structure, composition, classification, and
properties of POMs such as isopolyaions, heteropolyanions, giant,
and lacunary polyoxometalates and then cover polyoxometalate-based
open-frameworks (POM-OFs), include a historical introduction to
these compounds, and present their synthetic strategies. The
structural diversity and relative applications of POM-OFs is also
covered. Other sections delve into synthetic strategies, structural
diversity and relative applications of porous polyoxometalate-based
metal-organic frameworks. Polyoxometalate-based coordination
polymers (POMCPs) and polyoxometalate-based host-guest framework
materials are highlighted in final sections. This book is an
essential reference for inorganic chemists, biochemists, and
material scientists working in academia and industry.
Heteropolyacids as Highly Efficient and Green Catalysts Applied in
Organic Transformations introduces heteropolyacids (HPAs) as
promising candidates for use as green catalysts. This book
initially presents an overview of chemistry of HPAs, including the
history of their discovery and applications, systematic
classifications, solubility, coordination and binding chemistry,
isomerization, stability, redox activity, acidic properties,
basicity, skeleton structure, structure types, self-assemblage,
surface area, electrochemical behavior, methods of investigation,
and characterization. Other sections present and compare the
applications of HPAs as homogeneous and heterogeneous catalysts.
The book provides readers with a basic-to-advanced range of
knowledge on how useful and green HPAs can be used for use as
catalysts in organic transformations and even the synthesis of
complex organic molecules.
Recent Applications of Selected Name Reactions in the Total
Synthesis of Alkaloids includes comprehensive coverage of name
reactions in the synthesis of alkaloids. This book highlights the
synthesis of various alkaloids using special name reactions
including the Diels-Alder, Friedel-Crafts, Heck, Mannich,
Pauson-Khand, Pictet-Spengler, Sonogashira and Suzuki reactions. In
this book, some selected name reactions in the total synthesis of
alkaloids are covered, as they can be used as the key step/steps in
the synthesis of different alkaloids exhibiting various biological
activities. All chapters include an introduction, history and
mechanism of the name reaction, and present the origin of the
natural product and its known biological activities. The pathway to
total synthesis is visually illustrated, and the focus is on the
step in which a name reaction is applied. Chemists working in the
area of synthetic organic chemistry will find this reference
useful, as well as those working to develop novel methodologies for
the synthesis of natural products in both academia and industry.
This book is also beneficial to biologists, pharmacists and
botanists.
Recent Advances in Applications of Name Reactions in Multicomponent
Reactions is an ideal reference for researchers and postgraduate
students studying organic chemistry, as well as synthetic organic
chemists working on the development of novel methodologies for the
synthesis of various heterocyclic systems, especially drug design
and discovery, in both academia and industry. The book reviews
recent applications of name reactions in multicomponents for the
synthesis of heterocycles and examines recent advances in
applications of significant name reactions, such as Ugi and
Passirini, Click, Knoevenagel, Michael, Diels-Alder, Aldol,
Mannich, Heck, Huisgen, and Suzuki in MCRs. These reactions can be
used in the synthesis of a wide variety of novel heterocycles with
different sizes and heteroatoms, as well as in the total synthesis
of natural products in order to decrease the number of synthetic
steps. Since chiral inductions are necessary for most of these
sequential name reactions, their asymmetric catalyzed reactions are
also described.
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