This important work is based on the editors' symposium at the 2005 ACS meeting in Washington, DC. The contents include an emphasis on main-group polymers, including boron. The chapters are not simply journal articles, but have real added value as the editors have reviewed the general area by placing the work into a larger perspective. This book will be required reading for scientists in a number of disciplines including chemical engineers and physics researchers.

''A must for anyone interested in metal-containing polymers and all its aspects.'' ---American Scientist ''Nicely organized...well-written....An excellent shapshot of the current state of this field.'' ---MRS Bulletin, July 1998

Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published."

This important work is based on the editors symposium at the 2005 ACS meeting in Washington, DC. The contents include an emphasis on main-group polymers, including boron. The chapters are not simply journal articles, but have real added value as the editors have reviewed the general area by placing the work into a larger perspective. This book will be required reading for scientists in a number of disciplines including chemical engineers and physics researchers.