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Inorganic and Metal-Containing Polymeric Materials (Paperback, Softcover reprint of the original 1st ed. 1990)
Loot Price: R1,619
Discovery Miles 16 190
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Inorganic and Metal-Containing Polymeric Materials (Paperback, Softcover reprint of the original 1st ed. 1990)
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Total price: R1,639
Discovery Miles: 16 390
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Research on metal-containing polymers began in the early 1960's
when several workers found that vinyl ferrocene and other vinylic
transition metal TI -complexes would undergo polymerization under
the same conditions as conventional organic monomers to form high
polymers which incorporated a potentially reactive metal as an
integral part of the polymer structures. Some of these materials
could act as semi conductors and possessed one or two dimensional
conductivity. Thus applications in electronics could be visualized
immediately. Other workers found that reactions used to make simple
metal chelates could be used to prepare polymers if the ligands
were designed properly. As interest in homogeneous catalysts
developed in the late 60's and early 70's, several investigators
began binding homogeneous catalysts onto polymers, where the
advantage of homogeneous catalysis - known reaction mechanisms and
the advantage of heterogeneous catalysis - simplicity and ease of
recovery of catalysts could both be obtained. Indeed the polymer
matrix itself often enhanced the selectivity of the catalyst. The
first symposium on Organometallic Polymers, held at the National
Meeting of the American Chemical Society in September 1977,
attracted a large number of scientists interested in this field,
both established investigators and newcomers. Subsequent symposia
in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds
of papers and patents have been published."
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