The objective of this book is to summarize and critically assess the current status, development trends and needs of three basic defensive elements that safeguard the quality and environmental safety of soil and water/sediments: early warning monitoring, protection and remediation measures, with particular regard to the viability of methods and technologies, i.e. easiness-to-use, reliability, cost-effectiveness, high efficiency and non-destructive character of remediation that is of particular importance considering the scale of application. The primary aim of the book is to contribute to the improving maintenance of ecosystems, and specifically to summarize and add to information on how best to protect our soils and aquifers, prevent migration and mobilization of pollutants and how to enhance their degradation and/or immobilization. Mechanism of action is considered the first priority, but optimization of technical construction/application details are of no lesser importance. In the permeable reactive barriers, and other preventive/remediation measures, a number of novel integrated physicochemical and biochemical methods are presented. The remediation solutions for soil pollution are focused on non-destructive methods such as phyto- and ecoremediation that would preserve soil properties during and after decontamination. The contributors to the book are internationally recognized experts, which present both state-of-the art and novel approaches in the above fields that makes the book unique with respect to the scope.

Halogenated organic compounds constitute one of the largest groups of environmental chemicals. The industrial production of new halogenated organic compounds has increased throughout the last century and these compounds are integral to a variety of industrial applications. Although organohalide compounds are typically considered to be anthropogenic industrial compounds, these have their counterpart in several thousands of natural biogenic and geogenic organohalides, representing most classes of organic chemicals. Natural sources account for a significant portion of the global organohalogen budget.

This volume, authored by leading experts in the field, provides a current perspective on how both natural and synthetic organohalides are formed and degraded, and how these processes are incorporated into a global halogen cycle. The list of organohalides that can be utilized by microbes continues to increase dramatically, as do the number of dehalogenating microorganisms that have been identified and characterized. A critical step in the degradation of organohalides is cleavage of the carbon-halogen bond, and microorganisms have evolved a variety of metabolic strategies for dehalogenation. The chapters provide a global perspective on the diversity of dehalogenating microorganisms, explore their ecology, biochemistry and genetics, and review the range of biologically-mediated dehalogenation mechanisms. Many of the problematic organohalides, such as pesticides, chlorofluorocarbons, chlorinated solvents, polychlorinated dibenzo-p-dioxins and polychlorinated biphenyls, are covered in detail. The book provides a comprehensive overview of fate of these compounds in the environment, practicalapplications in the laboratory and the field, and strategies for the development of bioremediation technologies for organohalide-contaminated sites.

Detailed information on biodegradation and biotransformation mechanisms for a variety of organohalides and on the microorganisms mediating these processes has greatly increased our understanding of the cycling and fate of these unique and widespread compounds in our environment. The book will serve as a comprehensive resource on the processes and applications of microbial degradation of halogenated organic compounds.

Halogenated organic compounds constitute one of the largest groups of environmental chemicals. The industrial production of new halogenated organic compounds has increased throughout the last century peaking in the 1960s, and continuing in widespread use today. Organohalides are integral to a variety of industrial applications, including use as solvents, degreasing agents, biocides, pharmaceuticals, plasticizers, hydraulic and heat transfer fluids, and intermediates for chemical synthesis, to name a few. It is important to recognize the beneficial aspects of halogenated organic compounds, as well as their potentially deleterious impact on the environment and health. Recognition ofthe adverse environmental effects ofmanytypes oforganohalide compounds has led to efforts to reduce or eliminate the most problematic ones. Although organohalide compounds are typically considered to be anthropogenic industrial compounds, they have their counterpart in several thousands of natural biogenic and geogenic organohalides, representing most classes of organic chemicals. Natural sources account for a significant portion of the global organohalogen budget. This volume authored by recognized experts in the field provides a current perspective on how both natural and synthetic organohalides are formed and degraded, and how these processes are incorporated into a global halogen cycle. The focus is on microbial processes, since these play a major role both in the production and degradation, i. e. , cycling of halogenated organic compounds inthe environment. This book is organized into five parts. Part I, Introduction, provides a global perspective on the issues of organohalides and their fate in the environment.

The objective of this book is to summarize and critically assess the current status, development trends and needs of three basic defensive elements that safeguard the quality and environmental safety of soil and water/sediments: early warning monitoring, protection and remediation measures, with particular regard to the viability of methods and technologies, i.e. easiness-to-use, reliability, cost-effectiveness, high efficiency and non-destructive character of remediation that is of particular importance considering the scale of application. The priority aim of the book is to contribute to the improving maintenance of ecosystems, and specifically to summarize and add to information on how best to protect our soils and aquifers, prevent migration and mobilization of pollutants and how to enhance their degradation and/or immobilization. Mechanism of action is considered of the first priority, but optimization of technical construction/application details are of no lesser importance. In the permeable reactive barriers, and other preventive/remediation measures, a number of novel integrated physicochemical and biochemical methods are presented. The remediation solutions for soil pollution are focused on non-destructive methods such as phyto- and ecoremediation that would preserve soil properties during and after decontamination. The contributors to the book are internationally recognized experts, which present both state-of-the art and novel approaches in the above fields that makes the book unique with respect to the scope.