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Organometallic Bonding and Reactivity - Fundamental Studies (Paperback, Softcover reprint of the original 1st ed. 1999): J.M.... Organometallic Bonding and Reactivity - Fundamental Studies (Paperback, Softcover reprint of the original 1st ed. 1999)
J.M. Brown; Contributions by P. B. Armentrout; Edited by P. Hofmann; Contributions by D. Braga, A. Dedieu, …
R5,733 Discovery Miles 57 330 Ships in 10 - 15 working days

General The making and breaking of carbon-metal bonds is fundamental to all the p- cesses of organometallic chemistry and moreover plays a significant role in - mogeneous as well as heterogeneous catalysis. This rather blunt statement - phasises the extent to which a proper understanding of the structure, energetics and reactivity of C-M bonds is at the core of the discipline. In order to accept it, a proper definition of the terms involved is required. Quite simply we define the metal-carbon bond in its broadest sense to embrace carbon linked to transiti- metals, lanthanides and actinides, and main group metals. We do not dist- guish between formally covalent single or multiple bonding on the one hand and q-bonding on the other. In the studies to be described in the following chapters, the emphasis will be on transition metal complexes and insofar as the fun- mentals come under scrutiny, simple metal alkyls or related species (metal al- nyl, alkynyl, aryl, or allyl) will play an emphatic part. The central role of metal alkyls and their congeners and especially the role of their metal carbon linkage in homogeneous catalysis may be appreciated by considering some key reaction steps leading to their formation or breakdown. There follows a few prominent examples of transition metal mediated stoichiometric or catalytic processes: - In homogeneous hydrogenation of double bonds, the stepwise reaction of an q2-coordinated alkene with dihydrogen gives first an alkyl metal hydride, and then the decoordinated alkane by elimination.

Organometallic Bonding and Reactivity - Fundamental Studies (Hardcover, 1999 ed.): J.M. Brown Organometallic Bonding and Reactivity - Fundamental Studies (Hardcover, 1999 ed.)
J.M. Brown; Contributions by P. B. Armentrout; Edited by P. Hofmann; Contributions by D. Braga, A. Dedieu, …
R5,766 Discovery Miles 57 660 Ships in 10 - 15 working days

General The making and breaking of carbon-metal bonds is fundamental to all the p- cesses of organometallic chemistry and moreover plays a significant role in - mogeneous as well as heterogeneous catalysis. This rather blunt statement - phasises the extent to which a proper understanding of the structure, energetics and reactivity of C-M bonds is at the core of the discipline. In order to accept it, a proper definition of the terms involved is required. Quite simply we define the metal-carbon bond in its broadest sense to embrace carbon linked to transiti- metals, lanthanides and actinides, and main group metals. We do not dist- guish between formally covalent single or multiple bonding on the one hand and q-bonding on the other. In the studies to be described in the following chapters, the emphasis will be on transition metal complexes and insofar as the fun- mentals come under scrutiny, simple metal alkyls or related species (metal al- nyl, alkynyl, aryl, or allyl) will play an emphatic part. The central role of metal alkyls and their congeners and especially the role of their metal carbon linkage in homogeneous catalysis may be appreciated by considering some key reaction steps leading to their formation or breakdown. There follows a few prominent examples of transition metal mediated stoichiometric or catalytic processes: - In homogeneous hydrogenation of double bonds, the stepwise reaction of an q2-coordinated alkene with dihydrogen gives first an alkyl metal hydride, and then the decoordinated alkane by elimination.

Signal Transduction in Photoreceptor Cells - Proceedings of an International Workshop Held at the Research Centre Julich,... Signal Transduction in Photoreceptor Cells - Proceedings of an International Workshop Held at the Research Centre Julich, Julich, Fed. Rep. of Germany, 8-11 August 1990 (Paperback)
Paul A. Hargrave, Klaus P. Hofmann, U. Benjamin Kaupp
R2,969 Discovery Miles 29 690 Ships in 10 - 15 working days

This volume contains manuscripts based upon talks presented at the International Symposium on Signal Transduction in Photoreceptor Cells which was held at the Forschungszentrum Jiilich August 8-11, 1990. * The meeting was dedicated to the memory of Hermann Kuhn who made major contributions to our understand ing of transduction pathways in visual cells. Presentations at the meeting were organized around the following topics: (1) Rhodopsin Structure and Function, (2) Transducin and Phosphodiesterase, (3) Arrestin and Kinase, (4) The cGMP-gated 2 channel, (5) Role of Ca + in Photoreceptors, and (6) Transduction in Inverte brates. In a Plenary Lecture, D. Oesterhelt (Martinsried, FRG) described the sen sory transduction system of the halobacteria. These primitive organisms employ several retinal-containing pigments for sensory and ion-translocation purposes. Their study is intrinsically interesting as well as serving as potential models for the understanding of more complex systems. Study of the structure and function of rhodopsin has been greatly aided by use of the methods of molecular biology. T. Sakmar (Cambridge, MA, USA) described his use of site specific mutagenesis to make systematic substitutions of charged residues in the transmembrane helices of rhodopsin, leading to iden tification of the particular glutamic acid residue that serves as a counterion for the protonated Schiff base. Vertebrate rhodopsin has also been cloned and ex pressed in the baculovirus system, (W. DeGrip, Nijmegen, The Netherlands) which should facilitate production of sufficient quantities of mutant rhodopsin to allow biophysical studies."

Organometallics in Organic Synthesis - Aspects of a Modern Interdisciplinary Field (Paperback, Softcover reprint of the... Organometallics in Organic Synthesis - Aspects of a Modern Interdisciplinary Field (Paperback, Softcover reprint of the original 1st ed. 1988)
Armin De Meijere; Assisted by R. Aumann; Edited by Heindirk Tom Dieck; Assisted by L. Dahlenburg, K.H. Doetz, …
R2,992 Discovery Miles 29 920 Ships in 10 - 15 working days

More and more possible applications of organometallic compounds in organic synthesis have been uncovered and a growing number of scientists are attracted to this area of research. This book presents an state-of-the-art account of the successful application of main- and transition metal mediated syntheses. It will stimulate new ideas and initiate further research in all areas of this fascinating chemistry.

Klinische Psychotherapie (German, Paperback): P. Hofmann, M. Lux, Ch Probst, M Steinbauer, J Taucher, H.G. Zapotoczky Klinische Psychotherapie (German, Paperback)
P. Hofmann, M. Lux, Ch Probst, M Steinbauer, J Taucher, …
R2,362 Discovery Miles 23 620 Ships in 10 - 15 working days

Das Buch enthAlt eine Auswahl der besten BeitrAge des Internationalen Kongresses fA1/4r "Klinische Psychotherapie a " Psychotherapie in der Psychiatrie" im Oktober 1995 in Graz. Die BeitrAge setzen sich mit grundlegend konzeptionellen Fragestellungen klinischer Psychotherapie, mit konkreten Beschreibungen einzelner Anwendungsgebiete verschiedener therapeutischer Schulen sowie mit der Darstellung der Ergebnisse klinischer Studien auseinander. Das Buch bietet den interessierten A"rzten und Psychotherapeuten einen aktuellen Aoeberblick A1/4ber das sich rasch entwickelnde Gebiet der Psychotherapie in der Psychiatrie.

Tabellen Zur Bundesgebuhrenordnung Fur Rechtsanwalte, Zur Kostenordnung in Freiwilliger Gerichtsbarkeit, Zum... Tabellen Zur Bundesgebuhrenordnung Fur Rechtsanwalte, Zur Kostenordnung in Freiwilliger Gerichtsbarkeit, Zum Gerichtskostengesetz, Zum Umsatzsteuergesetz, Zum Gesetz UEber Kosten Der Gerichtsvollzieher, Zu Den Gebuhren Der Rechtsbeistande Und Zu Den... - Nebst Erganzenden Bestimmungen Und Erlauterungen (German, Hardcover, 18th 18., Vollig Neu Bearb. Aufl. Z ed.)
Gottfried Quandt; Edited by P. Hofmann
R4,261 Discovery Miles 42 610 Ships in 10 - 15 working days
Tabellen Zur Gebuhrenordnung Fur Rechtsanwalte, Zur Reichskostenordnung in Freiwilliger Gerichtsbarkeit, Zum... Tabellen Zur Gebuhrenordnung Fur Rechtsanwalte, Zur Reichskostenordnung in Freiwilliger Gerichtsbarkeit, Zum Gerichtskostengesetz, Zum Umsatzsteuergesetz, Zu Den Gebuhren Fur Gerichtsvollzieher Und Zu Den Gebuhren Nach Der Justizbeitreibungsordnung - Nebst Erganzenden Bestimmungen Und Erlauterungen (German, Hardcover, 17th 17., Erg. U. Erw. Aufl ed.)
Gottfried Quandt, P. Hofmann
R4,261 Discovery Miles 42 610 Ships in 10 - 15 working days
Tabellen Zur Gebuhrenordnung Fur Rechtsanwalte, Zur Reichskostenordnung in Freiwilliger Gerichtsbarkeit, Zum... Tabellen Zur Gebuhrenordnung Fur Rechtsanwalte, Zur Reichskostenordnung in Freiwilliger Gerichtsbarkeit, Zum Gerichtskostengesetz Zum Umsatzsteuergesetz, Zu Den Gebuhren Fur Gerichts Vollzieher Und Zu Den Gebuhren Nach Der Justizbeitreibungsordnung - Nebst Erganzenden Bestimmungen Und Erlauterungen (German, Hardcover, 16th 16., Vollig Neu Bearb. Aufl., ed.)
Gottfried Quandt; Edited by P. Hofmann
R4,261 Discovery Miles 42 610 Ships in 10 - 15 working days
Psychology of Decision Making in Economics, Business & Finance (Hardcover, Illustrated Ed): Klaus P. Hofmann Psychology of Decision Making in Economics, Business & Finance (Hardcover, Illustrated Ed)
Klaus P. Hofmann
R6,330 R3,960 Discovery Miles 39 600 Save R2,370 (37%) Ships in 12 - 17 working days

In a fast-moving world, the necessity of making decisions, and preferably good ones, has become even more difficult. One reason is the variety and number of choices perhaps available which often are not presented or understood. Alternatives are often unclear and complex paths to them confusing and misleading. Thus the process of decision making itself requires analysis on an ongoing basis. Decision making is often made based on cultural factors whereas the best alternative might be quite different. The subject touches ethics aspects as well as psychological considerations. This book presents important research on the psychology of decision making related to economics, business and finance.

Mensch – Körper – Tod - Der Umgang mit menschlichen Überresten im Neolithikum Mitteleuropas: Nadia Balkowski, Isabel A.... Mensch – Körper – Tod - Der Umgang mit menschlichen Überresten im Neolithikum Mitteleuropas
Nadia Balkowski, Isabel A. Hohle, Kerstin P. Hofmann, Almut Schülke
R1,549 Discovery Miles 15 490 Ships in 12 - 17 working days

Das europäische Neolithikum zeichnet sich durch eine Vielzahl von Umgangsweisen mit menschlichen Körpern von Toten aus. Der archäologische Diskurs zu Mensch, Körper und Tod stützte sich für das Neolithikum traditionell jedoch auf Körperbestattungen. Dies ist unter anderem auf die in der westlichen Welt vorherrschende Idealvorstellung von Totenruhe und der Deponierung eines Körpers an einem, oft separat dafür vorgesehenen Ort zurückzuführen. In der letzten Zeit gerieten jedoch Deponierungen fragmentierter und mitunter auch manipulierter menschlicher Überreste in den Fokus des Interesses, nicht zuletzt durch die Zunahme neuer archäologischer Funde, die sich mit traditionellen Begriffen und Konzepten nicht ohne weiteres erklären lassen. Eine wachsende Zahl solcher Funde fordert die Archäologie heraus, sich mit diesen Themen aus neuen Perspektiven zu beschäftigen. Der vorliegende Band integriert theoretische Reflexionen zur Bedeutung des menschlichen Körpers und zur Wahrnehmung des Übergangs vom Leben zum Tod, wie sie anhand von Bestattungen und Deponierungen menschlicher Überreste und archäologischer Funde untersucht werden können. Ein besonderer Schwerpunkt liegt dabei auf dem neolithischen Mitteleuropa. Mit Hilfe verschiedener interdisziplinärer und theoretischer Ansätze wird anhand von Fallstudien deutlich, dass etablierte Praktiken und performative Akte des Umgangs mit dem menschlichen Körper hochkomplex sind und daher auch gemeinsam aus unterschiedlichen Blickwinkeln betrachtet werden sollten. Der aus einer Tagungssektion in Würzburg 2019 hervorgegangene Sammelband vereint dabei Beiträge zu verschiedenen Gebieten und neolithischen Subperioden, wie der Linearbandkeramik, der Trichterbecherkultur und dem subalpinen Spätneolithikum, darunter prominente Fundkomplexe. Eingerahmt werden diese von Aufsätzen, die sich kritisch mit der archäologischen Erforschung des Umgangs von Tod und mit Toten auseinandersetzen und einem zusammenfassenden Überblick zu den Beiträgen des Sammelbandes geben. English Abstract The European Neolithic is characterized by a variety of practices for dealing with human remains. In Central European Neolithic studies, the archaeological discourse on humans, bodies and death has traditionally dealt with finds of inhumations. This is not least due to dominant Western conceptions of death involving the deposition of the intact body at one, often delimited, place. Recently, focus has been drawn to the depositions of fragmented and even manipulated human remains, not least through an increasing amount of new archaeological evidence, which challenges traditional archaeological terms, concepts and research practices. The present volume integrates theoretical perspectives on the meaning of the human body and the perception of the transformation from life to death in as much as they can be studied from archaeological finds such as burials and depositions of human remains, with a special focus on Neolithic Central Europe. The collection of papers, the result of a session at a conference in Würzburg 2019, brings together articles with theoretical approaches, as well as contributions which deal with different areas and Neolithic sub-periods, such as the Linear Pottery culture, the Funnel Beaker Culture and the sub-alpine Late Neolithic, and includes prominent find complexes. These are framed by essays that critically examine archaeological research on the handling of death and the dead, and a summary overview of the contributions to the volume.

Mensch – Körper – Tod - Der Umgang mit menschlichen Überresten im Neolithikum Mitteleuropas: Nadia Balkowski, Isabel A.... Mensch – Körper – Tod - Der Umgang mit menschlichen Überresten im Neolithikum Mitteleuropas
Nadia Balkowski, Isabel A. Hohle, Kerstin P. Hofmann, Almut Schülke
R3,151 Discovery Miles 31 510 Ships in 12 - 17 working days

Das europäische Neolithikum zeichnet sich durch eine Vielzahl von Umgangsweisen mit menschlichen Körpern von Toten aus. Der archäologische Diskurs zu Mensch, Körper und Tod stützte sich für das Neolithikum traditionell jedoch auf Körperbestattungen. Dies ist unter anderem auf die in der westlichen Welt vorherrschende Idealvorstellung von Totenruhe und der Deponierung eines Körpers an einem, oft separat dafür vorgesehenen Ort zurückzuführen. In der letzten Zeit gerieten jedoch Deponierungen fragmentierter und mitunter auch manipulierter menschlicher Überreste in den Fokus des Interesses, nicht zuletzt durch die Zunahme neuer archäologischer Funde, die sich mit traditionellen Begriffen und Konzepten nicht ohne weiteres erklären lassen. Eine wachsende Zahl solcher Funde fordert die Archäologie heraus, sich mit diesen Themen aus neuen Perspektiven zu beschäftigen. Der vorliegende Band integriert theoretische Reflexionen zur Bedeutung des menschlichen Körpers und zur Wahrnehmung des Übergangs vom Leben zum Tod, wie sie anhand von Bestattungen und Deponierungen menschlicher Überreste und archäologischer Funde untersucht werden können. Ein besonderer Schwerpunkt liegt dabei auf dem neolithischen Mitteleuropa. Mit Hilfe verschiedener interdisziplinärer und theoretischer Ansätze wird anhand von Fallstudien deutlich, dass etablierte Praktiken und performative Akte des Umgangs mit dem menschlichen Körper hochkomplex sind und daher auch gemeinsam aus unterschiedlichen Blickwinkeln betrachtet werden sollten. Der aus einer Tagungssektion in Würzburg 2019 hervorgegangene Sammelband vereint dabei Beiträge zu verschiedenen Gebieten und neolithischen Subperioden, wie der Linearbandkeramik, der Trichterbecherkultur und dem subalpinen Spätneolithikum, darunter prominente Fundkomplexe. Eingerahmt werden diese von Aufsätzen, die sich kritisch mit der archäologischen Erforschung des Umgangs von Tod und mit Toten auseinandersetzen und einem zusammenfassenden Überblick zu den Beiträgen des Sammelbandes geben. English Abstract The European Neolithic is characterized by a variety of practices for dealing with human remains. In Central European Neolithic studies, the archaeological discourse on humans, bodies and death has traditionally dealt with finds of inhumations. This is not least due to dominant Western conceptions of death involving the deposition of the intact body at one, often delimited, place. Recently, focus has been drawn to the depositions of fragmented and even manipulated human remains, not least through an increasing amount of new archaeological evidence, which challenges traditional archaeological terms, concepts and research practices. The present volume integrates theoretical perspectives on the meaning of the human body and the perception of the transformation from life to death in as much as they can be studied from archaeological finds such as burials and depositions of human remains, with a special focus on Neolithic Central Europe. The collection of papers, the result of a session at a conference in Würzburg 2019, brings together articles with theoretical approaches, as well as contributions which deal with different areas and Neolithic sub-periods, such as the Linear Pottery culture, the Funnel Beaker Culture and the sub-alpine Late Neolithic, and includes prominent find complexes. These are framed by essays that critically examine archaeological research on the handling of death and the dead, and a summary overview of the contributions to the volume

Massendinghaltung in der Archaologie - Der material turn und die Ur- und Fruhgeschichte (German, Paperback): Kerstin P.... Massendinghaltung in der Archaologie - Der material turn und die Ur- und Fruhgeschichte (German, Paperback)
Kerstin P. Hofmann, Thomas Meier, Doreen Moelders, Stefan Schreiber
R2,055 Discovery Miles 20 550 Ships in 12 - 17 working days

The primary way of generating knowledge in archaeology is through its collections and archives of objects of past cultures and societies - as was and still is stated quite often. But archaeology has been struggling with the sheer masses of objects since, which steadily grow because of excavations. The following seventeen articles were contributions to a conference in Berlin in 2013, which was organized by the German Association for Theories in Archaeology. This edited volume focuses on two general topics. The essays in the first part of the volume treat the virulent problem of objects stockpiling in collections. The history as well as the psychology of collecting are addressed. There is a focus on the development which began with a passionate, subjective "delight in collecting" but which moved towards a regulated, institutionalized "burden of collecting". However, alternatives which lead to a self-conscious practice of de-collecting, are discussed as well. The contributions in the second part of the volume deal with the established empirical-antiquarian research in the light of the material turn and also show the complexity of the relationship between humans and objects. Last but not least, this volume discusses current attempts at the understanding of objects in other disciplines from an archaeological perspective.

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