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General The making and breaking of carbon-metal bonds is
fundamental to all the p- cesses of organometallic chemistry and
moreover plays a significant role in - mogeneous as well as
heterogeneous catalysis. This rather blunt statement - phasises the
extent to which a proper understanding of the structure, energetics
and reactivity of C-M bonds is at the core of the discipline. In
order to accept it, a proper definition of the terms involved is
required. Quite simply we define the metal-carbon bond in its
broadest sense to embrace carbon linked to transiti- metals,
lanthanides and actinides, and main group metals. We do not dist-
guish between formally covalent single or multiple bonding on the
one hand and q-bonding on the other. In the studies to be described
in the following chapters, the emphasis will be on transition metal
complexes and insofar as the fun- mentals come under scrutiny,
simple metal alkyls or related species (metal al- nyl, alkynyl,
aryl, or allyl) will play an emphatic part. The central role of
metal alkyls and their congeners and especially the role of their
metal carbon linkage in homogeneous catalysis may be appreciated by
considering some key reaction steps leading to their formation or
breakdown. There follows a few prominent examples of transition
metal mediated stoichiometric or catalytic processes: - In
homogeneous hydrogenation of double bonds, the stepwise reaction of
an q2-coordinated alkene with dihydrogen gives first an alkyl metal
hydride, and then the decoordinated alkane by elimination.
General The making and breaking of carbon-metal bonds is
fundamental to all the p- cesses of organometallic chemistry and
moreover plays a significant role in - mogeneous as well as
heterogeneous catalysis. This rather blunt statement - phasises the
extent to which a proper understanding of the structure, energetics
and reactivity of C-M bonds is at the core of the discipline. In
order to accept it, a proper definition of the terms involved is
required. Quite simply we define the metal-carbon bond in its
broadest sense to embrace carbon linked to transiti- metals,
lanthanides and actinides, and main group metals. We do not dist-
guish between formally covalent single or multiple bonding on the
one hand and q-bonding on the other. In the studies to be described
in the following chapters, the emphasis will be on transition metal
complexes and insofar as the fun- mentals come under scrutiny,
simple metal alkyls or related species (metal al- nyl, alkynyl,
aryl, or allyl) will play an emphatic part. The central role of
metal alkyls and their congeners and especially the role of their
metal carbon linkage in homogeneous catalysis may be appreciated by
considering some key reaction steps leading to their formation or
breakdown. There follows a few prominent examples of transition
metal mediated stoichiometric or catalytic processes: - In
homogeneous hydrogenation of double bonds, the stepwise reaction of
an q2-coordinated alkene with dihydrogen gives first an alkyl metal
hydride, and then the decoordinated alkane by elimination.
This volume contains manuscripts based upon talks presented at the
International Symposium on Signal Transduction in Photoreceptor
Cells which was held at the Forschungszentrum Jiilich August 8-11,
1990. * The meeting was dedicated to the memory of Hermann Kuhn who
made major contributions to our understand ing of transduction
pathways in visual cells. Presentations at the meeting were
organized around the following topics: (1) Rhodopsin Structure and
Function, (2) Transducin and Phosphodiesterase, (3) Arrestin and
Kinase, (4) The cGMP-gated 2 channel, (5) Role of Ca + in
Photoreceptors, and (6) Transduction in Inverte brates. In a
Plenary Lecture, D. Oesterhelt (Martinsried, FRG) described the sen
sory transduction system of the halobacteria. These primitive
organisms employ several retinal-containing pigments for sensory
and ion-translocation purposes. Their study is intrinsically
interesting as well as serving as potential models for the
understanding of more complex systems. Study of the structure and
function of rhodopsin has been greatly aided by use of the methods
of molecular biology. T. Sakmar (Cambridge, MA, USA) described his
use of site specific mutagenesis to make systematic substitutions
of charged residues in the transmembrane helices of rhodopsin,
leading to iden tification of the particular glutamic acid residue
that serves as a counterion for the protonated Schiff base.
Vertebrate rhodopsin has also been cloned and ex pressed in the
baculovirus system, (W. DeGrip, Nijmegen, The Netherlands) which
should facilitate production of sufficient quantities of mutant
rhodopsin to allow biophysical studies."
More and more possible applications of organometallic compounds in
organic synthesis have been uncovered and a growing number of
scientists are attracted to this area of research. This book
presents an state-of-the-art account of the successful application
of main- and transition metal mediated syntheses. It will stimulate
new ideas and initiate further research in all areas of this
fascinating chemistry.
Das Buch enthAlt eine Auswahl der besten BeitrAge des
Internationalen Kongresses fA1/4r "Klinische Psychotherapie a "
Psychotherapie in der Psychiatrie" im Oktober 1995 in Graz. Die
BeitrAge setzen sich mit grundlegend konzeptionellen
Fragestellungen klinischer Psychotherapie, mit konkreten
Beschreibungen einzelner Anwendungsgebiete verschiedener
therapeutischer Schulen sowie mit der Darstellung der Ergebnisse
klinischer Studien auseinander. Das Buch bietet den interessierten
A"rzten und Psychotherapeuten einen aktuellen Aoeberblick A1/4ber
das sich rasch entwickelnde Gebiet der Psychotherapie in der
Psychiatrie.
In a fast-moving world, the necessity of making decisions, and
preferably good ones, has become even more difficult. One reason is
the variety and number of choices perhaps available which often are
not presented or understood. Alternatives are often unclear and
complex paths to them confusing and misleading. Thus the process of
decision making itself requires analysis on an ongoing basis.
Decision making is often made based on cultural factors whereas the
best alternative might be quite different. The subject touches
ethics aspects as well as psychological considerations. This book
presents important research on the psychology of decision making
related to economics, business and finance.
Das europäische Neolithikum zeichnet sich durch eine Vielzahl von
Umgangsweisen mit menschlichen Körpern von Toten aus. Der
archäologische Diskurs zu Mensch, Körper und Tod stützte sich
für das Neolithikum traditionell jedoch auf Körperbestattungen.
Dies ist unter anderem auf die in der westlichen Welt
vorherrschende Idealvorstellung von Totenruhe und der Deponierung
eines Körpers an einem, oft separat dafür vorgesehenen Ort
zurückzuführen. In der letzten Zeit gerieten jedoch Deponierungen
fragmentierter und mitunter auch manipulierter menschlicher
Ãœberreste in den Fokus des Interesses, nicht zuletzt durch die
Zunahme neuer archäologischer Funde, die sich mit traditionellen
Begriffen und Konzepten nicht ohne weiteres erklären lassen. Eine
wachsende Zahl solcher Funde fordert die Archäologie heraus, sich
mit diesen Themen aus neuen Perspektiven zu beschäftigen. Der
vorliegende Band integriert theoretische Reflexionen zur Bedeutung
des menschlichen Körpers und zur Wahrnehmung des Übergangs vom
Leben zum Tod, wie sie anhand von Bestattungen und Deponierungen
menschlicher Überreste und archäologischer Funde untersucht
werden können. Ein besonderer Schwerpunkt liegt dabei auf dem
neolithischen Mitteleuropa. Mit Hilfe verschiedener
interdisziplinärer und theoretischer Ansätze wird anhand von
Fallstudien deutlich, dass etablierte Praktiken und performative
Akte des Umgangs mit dem menschlichen Körper hochkomplex sind und
daher auch gemeinsam aus unterschiedlichen Blickwinkeln betrachtet
werden sollten. Der aus einer Tagungssektion in Würzburg 2019
hervorgegangene Sammelband vereint dabei Beiträge zu verschiedenen
Gebieten und neolithischen Subperioden, wie der Linearbandkeramik,
der Trichterbecherkultur und dem subalpinen Spätneolithikum,
darunter prominente Fundkomplexe. Eingerahmt werden diese von
Aufsätzen, die sich kritisch mit der archäologischen Erforschung
des Umgangs von Tod und mit Toten auseinandersetzen und einem
zusammenfassenden Überblick zu den Beiträgen des Sammelbandes
geben. English Abstract The European Neolithic is characterized by
a variety of practices for dealing with human remains. In Central
European Neolithic studies, the archaeological discourse on humans,
bodies and death has traditionally dealt with finds of inhumations.
This is not least due to dominant Western conceptions of death
involving the deposition of the intact body at one, often
delimited, place. Recently, focus has been drawn to the depositions
of fragmented and even manipulated human remains, not least through
an increasing amount of new archaeological evidence, which
challenges traditional archaeological terms, concepts and research
practices. The present volume integrates theoretical perspectives
on the meaning of the human body and the perception of the
transformation from life to death in as much as they can be studied
from archaeological finds such as burials and depositions of human
remains, with a special focus on Neolithic Central Europe. The
collection of papers, the result of a session at a conference in
Würzburg 2019, brings together articles with theoretical
approaches, as well as contributions which deal with different
areas and Neolithic sub-periods, such as the Linear Pottery
culture, the Funnel Beaker Culture and the sub-alpine Late
Neolithic, and includes prominent find complexes. These are framed
by essays that critically examine archaeological research on the
handling of death and the dead, and a summary overview of the
contributions to the volume.
Das europäische Neolithikum zeichnet sich durch eine Vielzahl von
Umgangsweisen mit menschlichen Körpern von Toten aus. Der
archäologische Diskurs zu Mensch, Körper und Tod stützte sich
für das Neolithikum traditionell jedoch auf Körperbestattungen.
Dies ist unter anderem auf die in der westlichen Welt
vorherrschende Idealvorstellung von Totenruhe und der Deponierung
eines Körpers an einem, oft separat dafür vorgesehenen Ort
zurückzuführen. In der letzten Zeit gerieten jedoch Deponierungen
fragmentierter und mitunter auch manipulierter menschlicher
Ãœberreste in den Fokus des Interesses, nicht zuletzt durch die
Zunahme neuer archäologischer Funde, die sich mit traditionellen
Begriffen und Konzepten nicht ohne weiteres erklären lassen. Eine
wachsende Zahl solcher Funde fordert die Archäologie heraus, sich
mit diesen Themen aus neuen Perspektiven zu beschäftigen. Der
vorliegende Band integriert theoretische Reflexionen zur Bedeutung
des menschlichen Körpers und zur Wahrnehmung des Übergangs vom
Leben zum Tod, wie sie anhand von Bestattungen und Deponierungen
menschlicher Überreste und archäologischer Funde untersucht
werden können. Ein besonderer Schwerpunkt liegt dabei auf dem
neolithischen Mitteleuropa. Mit Hilfe verschiedener
interdisziplinärer und theoretischer Ansätze wird anhand von
Fallstudien deutlich, dass etablierte Praktiken und performative
Akte des Umgangs mit dem menschlichen Körper hochkomplex sind und
daher auch gemeinsam aus unterschiedlichen Blickwinkeln betrachtet
werden sollten. Der aus einer Tagungssektion in Würzburg 2019
hervorgegangene Sammelband vereint dabei Beiträge zu verschiedenen
Gebieten und neolithischen Subperioden, wie der Linearbandkeramik,
der Trichterbecherkultur und dem subalpinen Spätneolithikum,
darunter prominente Fundkomplexe. Eingerahmt werden diese von
Aufsätzen, die sich kritisch mit der archäologischen Erforschung
des Umgangs von Tod und mit Toten auseinandersetzen und einem
zusammenfassenden Überblick zu den Beiträgen des Sammelbandes
geben. English Abstract The European Neolithic is characterized by
a variety of practices for dealing with human remains. In Central
European Neolithic studies, the archaeological discourse on humans,
bodies and death has traditionally dealt with finds of inhumations.
This is not least due to dominant Western conceptions of death
involving the deposition of the intact body at one, often
delimited, place. Recently, focus has been drawn to the depositions
of fragmented and even manipulated human remains, not least through
an increasing amount of new archaeological evidence, which
challenges traditional archaeological terms, concepts and research
practices. The present volume integrates theoretical perspectives
on the meaning of the human body and the perception of the
transformation from life to death in as much as they can be studied
from archaeological finds such as burials and depositions of human
remains, with a special focus on Neolithic Central Europe. The
collection of papers, the result of a session at a conference in
Würzburg 2019, brings together articles with theoretical
approaches, as well as contributions which deal with different
areas and Neolithic sub-periods, such as the Linear Pottery
culture, the Funnel Beaker Culture and the sub-alpine Late
Neolithic, and includes prominent find complexes. These are framed
by essays that critically examine archaeological research on the
handling of death and the dead, and a summary overview of the
contributions to the volume
The primary way of generating knowledge in archaeology is through
its collections and archives of objects of past cultures and
societies - as was and still is stated quite often. But archaeology
has been struggling with the sheer masses of objects since, which
steadily grow because of excavations. The following seventeen
articles were contributions to a conference in Berlin in 2013,
which was organized by the German Association for Theories in
Archaeology. This edited volume focuses on two general topics. The
essays in the first part of the volume treat the virulent problem
of objects stockpiling in collections. The history as well as the
psychology of collecting are addressed. There is a focus on the
development which began with a passionate, subjective "delight in
collecting" but which moved towards a regulated, institutionalized
"burden of collecting". However, alternatives which lead to a
self-conscious practice of de-collecting, are discussed as well.
The contributions in the second part of the volume deal with the
established empirical-antiquarian research in the light of the
material turn and also show the complexity of the relationship
between humans and objects. Last but not least, this volume
discusses current attempts at the understanding of objects in other
disciplines from an archaeological perspective.
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