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The book entitled with "Determination of Stability Constants of
Binary and Mixed Complexes" deals with the stability constants of
metal complexes can be very easily calculated by this technique,
therefore the present method is advantageous over other methods (
viz, polarographic, potentiometric, solubility etc) which usually
suffers from a number of vitiating factors (e.g. diffusion, ionic
strength and temperature ). The Electrophoretic technique is almost
free from these vitiating factors and results are fairly reliable.
Its further extension that these studies can be used to reduced the
level of these metal ions in biological system. These studies may
also be used for the resolution of racemic mixture of penicillamine
and other amino acids.
The book entitled with "Solution Ionophoretic Technique in Study of
Metal-Ligand Equilibria" deals with solution ionophoretic
technique, which is used for the determination of the stability
constants of metal complexes is better than other physiochemical
methods but it has some vitiating factors (e.g. diffusion, ionic
strength and temperature). This technique is free from these
vitiating factors and results are fairly reliable. The technique
used in these studies proved to be very useful in studying the
stepwise complextion in solution. The special electrophoretic tube
which has been designed for this work, yields better results after
standardization. This technique provides vivid picturization of
complex formation whose stability constant can be determined
easily. Its further extension in the study of mixed complexation
reactions is obviously a unique advancement in the realm of
coordination chemistry.
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