Electrical Properties of Polymers describes the electric phenomena responsible for determining the chemical and supramolecular structure of polymers and polymeric materials. The authors explore the properties of quasi-static dipoles, reviewing Brownian motion, Debye theory, Langevin and Smoluchowski equations, and the Onsager model. This reference displays Maxwell and entropy equations, along with several others, that depict the thermodynamics of dielectric relaxation. Featuring end-of-chapter problems and useful appendices, the book reviews molecular dynamics simulations of dynamic dielectric properties and inspects mean-square dipole moments of gases, liquids, polymers, and fixed conformations.

Showcasing vital engineering applications to transient and dynamic pertubations of macromolecular materials, structural recovery's role in mechanical responses in the glassy state, and viscoelastic parameters that condition the non-Newtonian behaviour of polymers, this work presents a systematic account of the responses of macromolecular materials to mechanical force fields. It focuses on the most important features of the linear stress-strain relationships for ideal solids and liquids.