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Fluorine is unique in that it is possible to replace hydrogen by
fluorine either singly or multiply, in an organic molecule and, in
so-doing create a potentially infinite extension to organic
chemistry that is entirely synthetic. The excitement of the
chemistry of these systems stems from the unique reactions that
ensue and the "special-effects"that introduction of fluorine
impart. Indeed, these effects are now exploited in a remarkable
array of applications across the whole of the chemical,
pharmaceutical, and plant-protection industries, although this is
not widely appreciated. In this book, we have gathered authors with
immense experience in various aspects of their field and each is a
world-authority on the important topics they have described. Some
topics, like the use of elemental fluorine, and enzymes in
synthesis, are relatively new areas that are rapidly growing. We
dedicate the book to a long standing friend, Professor George Olah,
in the year of his 70th birthday, in recognition of his massive
achievements. Durham, May 1997 Dick Chambers Contents Elemental
Fluorine in Organic Chemistry J. Hutchinson and G. Sandford . . . .
. . . . . . . . . . . . . . . . . . . . 1 Fluorinated
Organometallic Compounds D. J. Burton and L. Lu . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . 45 Enzymatically Controlled
Reactions of Organofluorine Compounds T. Kitazume and T. Yamazaki .
. . . . . . . . . . . . . . . . . . . . . . . . 91 Building Block
Approaches to Aliphatic Organofluorine Compounds J. M. Percy . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131
Electrofluorination of Organic Compounds F. G. Drakesmith . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Author
Index Volumes 151-193 . . . . . . . . . . . . . . . . . . . . . . .
243 Contents of Volume 192 Organofluorine Chemistry: Fluorinated
Alkenes and Reactive Intermediates Volume Editor: R. D. Chambers
Nucleophilic Reactions of Fluorinated Alkenes R. D. Chambers and J.
F. S.
The excitement of the chemistry of organofluorine compounds stems
from the unique reactions that arise and the "special effects" that
introduction of fluorine impart on a molecule. Indeed, these
effects are now exploited in a remarkable array of applications the
whole of the chemical, pharmaceutical, and plant-protection
industries. In this two-volume set, we have gathered authors with
immense experience in various aspects of their fields and each is a
world-authority on the important topics which they have described.
The first volume treats the chemistry of fluorinated alkenes, which
are important "building-blocks" for the synthesis of a range of
fluorinated systems and are used widely in industry. The second
volume is directed to techniques and synthons for obtaining
fluorinated compounds.
Fluorine is unique in that it is possible to replace hydrogen by
fluorine either singly or multiply, in an organic molecule and, in
so-doing create a potentially infinite extension to organic
chemistry that is entirely synthetic. The excitement of the
chemistry of these systems stems from the unique reactions that
ensue and the special-effects that introduction of fluorine impart.
Indeed, these effects are now exploited in a remarkable array of
applications across the whole of the chemical, pharmaceutical, and
plant-protection industries, although this is not widely
appreciated. In this book, we have gathered authors with immense
experience in various aspects of their field and each is a
world-authority on the important topics they have described. Some
topics, like the use of elemental fluorine, and enzymes in
synthesis, are relatively new areas that are rapidly growing. We
dedicate the book to a long standing friend, Professor George Olah,
in the year of his 70th birthday, in recognition of his massive
achievements. Durham, May 1997 Dick Chambers Contents Elemental
Fluorine in Organic Chemistry J. Hutchinson and G. Sandford . . . .
. . . . . . . . . . . . . . . . . . . . 1 Fluorinated
Organometallic Compounds D. J. Burton and L. Lu . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . 45 Enzymatically Controlled
Reactions of Organofluorine Compounds T. Kitazume and T. Yamazaki .
. . . . . . . . . . . . . . . . . . . . . . . . 91 Building Block
Approaches to Aliphatic Organofluorine Compounds J. M. Percy . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131
Electrofluorination of Organic Compounds F. G. Drakesmith . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Author
Index Volumes 151 193 . . . . . . . . . . . . . . . . . . . . . . .
243 Contents of Volume 192 Organofluorine Chemistry: Fluorinated
Alkenes and Reactive Intermediates Volume Editor: R. D. Chambers
Nucleophilic Reactions of Fluorinated Alkenes R. D. Chambers and J.
F.
The excitement of the chemistry of organofluorine compounds stems
from the unique reactions that arise and the "special effects" that
introduction of fluorine impart on a molecule. Indeed, these
effects are now exploited in a remarkable array of applications the
whole of the chemical, pharmaceutical, and plant-protection
industries. In this two-volume set, we have gathered authors with
immense experience in various aspects of their fields and each is a
world-authority on the important topics which they have described.
The first volume treats the chemistry of fluorinated alkenes, which
are important "building-blocks" for the synthesis of a range of
fluorinated systems and are used widely in industry. The second
volume is directed to techniques and synthons for obtaining
fluorinated compounds.
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