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This thesis presents the latest developments in new catalytic C-C
bond formation methods using easily accessible carboxylate salts
through catalytic decarboxylation with good atom economy, and
employing the sustainable element iron as the catalyst to directly
activate C-H bonds with high step efficiency. In this regard, it
explores a mechanistic understanding of the newly discovered
decarboxylative couplings and the catalytic reactivity of the iron
catalyst with the help of density functional theory calculation.
The thesis is divided into two parts, the first of which focuses on
the development of a series of previously unexplored, inexpensive
carboxylate salts as useful building blocks for the formation of
various C-C bonds to access valuable chemicals. In turn, the second
part is devoted to several new C-C bond formation methodologies
using the most ubiquitous transition metal, iron, as a catalyst,
and using the ubiquitous C-H bond as the coupling partner.
This thesis presents the latest developments in new catalytic C-C
bond formation methods using easily accessible carboxylate salts
through catalytic decarboxylation with good atom economy, and
employing the sustainable element iron as the catalyst to directly
activate C-H bonds with high step efficiency. In this regard, it
explores a mechanistic understanding of the newly discovered
decarboxylative couplings and the catalytic reactivity of the iron
catalyst with the help of density functional theory calculation.
The thesis is divided into two parts, the first of which focuses on
the development of a series of previously unexplored, inexpensive
carboxylate salts as useful building blocks for the formation of
various C-C bonds to access valuable chemicals. In turn, the second
part is devoted to several new C-C bond formation methodologies
using the most ubiquitous transition metal, iron, as a catalyst,
and using the ubiquitous C-H bond as the coupling partner.
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