New Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation (Hardcover, 1st ed. 2017)

This thesis presents the latest developments in new catalytic C-C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C-H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation. The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C-C bonds to access valuable chemicals. In turn, the second part is devoted to several new C-C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C-H bond as the coupling partner.

General

Imprint:	Springer Verlag, Singapore
Country of origin:	Singapore
Series:	Springer Theses
Release date:	December 2016
First published:	2017
Authors:	Rui Shang
Dimensions:	235 x 155 x 14mm (L x W x T)
Format:	Hardcover
Pages:	216
Edition:	1st ed. 2017
ISBN-13:	978-981-10-3192-2
Categories:	Books > Science & Mathematics > Chemistry > Organic chemistry > Organometallic chemistry Books > Science & Mathematics > Chemistry > Physical chemistry > Catalysis Books > Science & Mathematics > Chemistry > Physical chemistry > Quantum & theoretical chemistry
LSN:	981-10-3192-4
Barcode:	9789811031922

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