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This work has been motivated by the outstanding need to prepare
suitable substrate for growth of III-nitride heteroepitaxial thin
films. The issue of lattice and thermal expansion mismatches
between the substrates and overlayers, which results in a high
threading dislocation density in the films, is seen to be
detrimental to photon and carrier transport in these systems. Thus,
looking for appropriate substrates or modifying substrates
appropriately, has attracted enormous attentions. The work includes
the chemical and structural modifications of silicon, gallium
arsenide and sapphire substrates, to obtain appropriate
characteristics. The work also consists of a significant portion on
the adsorption and desorption characteristic of Ga metal on various
high and low index silicon surfaces. This study not only
complements the search for substrate for GaN growth, but also in
other interesting aspects of initial stages of metal/semiconductor
interface formation, evolution of superstructural 2D- surface
phases and formation of sub-nanodimension metal nanostructures and
delta doped.
The emergence of colloidal semiconductor nanocrystals has generated
great fundamental and technical interest in recent years. The size
dependent emission property for Cadmium Selenide quantum dots
renders it indispensable in the field of nanocrystal-based emitters
used in electronic and bioelectronic devices. Investigation of
these semiconductor quantum dots reveals the evolution of the
electronic structure from an extended solid state to the molecular
limit, an extremely important issue of basic and applied research
in condensed matter physics. The work presented in this book mainly
deals with the synthesis and characterization of chemically
synthesized CdSe nanoparticles. A detailed investigation of the
optical, structural and morphological properties of CdSe QDs and
their correlation with both core and surface has been carried out.
The theoretical aspect of quantum confinement and stability of CdSe
quantum dots with organic and inorganic layers, are correlated to
understand the surface modification aspects. Finally CdSe-polymer
nanocomposites were discussed for their potential application in
biomarkers and photo-electronic devices.
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