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The third volume in this series consists of eight chapters. The
first three deal with kinetic aspects of compositional variations
both within individual phases and across crystal boundaries.
Basically, the authors use the kinetic theory and the sparsely
available rate data to explain the formation of various types of
zoning and the exsolution processes in silicates. Loomis rightly
argues that "the kinetic inhibitions to reequilibration that
preserve primary igneous crystals and high- grade metamorphic
assemblages also affect the crystallization and prograde meta-
morphism of these rocks." These "kinetic inhibitions" appear in the
form of zoned crystals, reaction rims and disequilibrium
assemblages. Their proper recognition and quantitative
characterization leads to an understanding of the physico-chem-
ical history of the rock. On a similar theme, I examine possible
relationships between the exsolution processes in Ca-Fe-Mg
pyroxenes and the cation order-disorder on nonequiva- lent
crystallographic sites. A multi-technique study of exsolutions in
crystals employing electron microscopy and X-ray structural
refinements should contrib- ute greatly in understanding the
thermal history of the rock. Many geothermometric studies result in
discordant temperatures when the estimates are done using serveral
coexisting pairs of minerals in a single specimen. Lasaga uses the
kinetic rates of diffusion of various chemical species and explains
the discordance through his "geospeedometric" approach.
Hans Ramberg is working in an area of geology where 60 years are a
short, often negligible period of time. This is not so in the lives
of men. For us it is a time for evaluating past accomplishments and
a time for friends to express their appreciation and admiration.
Some universities have become famous for this ability to foster
eminent scientists in one or several fields. The success of
Cambridge University in physics is a well-known example, but if we
ask ourselves whether the success of Oslo University in earth
sciences is not equally astonishing, then we see that Hans is yet
another example of this process; but it is not the whole story.
There were certainly promising prospects when he started his
studies in geology: V. M. Goldschmidt had just come back from
G6ttingen in Germany and Tom Barth had returned from the
Geophysical Laboratory in Washington, D.C. Two leaders in
geochemistry and petrology at the same time Hans became a student
of Barth, specializing in metamorphic rocks and their problems; but
soon the situation changed. Norway was occupied by the Germans and
the possibili ties for university studies almost vanished. However,
in spite of all difficulties he obtained his Ph.D. in 1946 and
began participating in the geological mapping of Greenland. In 1947
he went to the University of Chicago and stayed there until 1961
when he came to his present position in the University of Uppsala,
Sweden."
Chemical petrology is essentially the physical chemistry of rocks
and associated fluids, although it also borrows heavily from such
other sciences as mineralogy. In terms of fundamentals it is firmly
grounded in chemical thermodynamics and kinetics. In its treatment
of terrestrial environments it grades imperceptably into
sedimentology, geochemistry, and geophysics and in extraterrestrial
environments into cosmochemistry. It is one of the most important
branches of planetology and meteoritics. The unity of approach of
thermodynamics and kinetics to processes in these diverse
environments is stressed in this book by numerous examples which
have been chosen to illuminate different aspects of the subject.
Thus we have discussed in some depth such problems as the genesis
of layered basic complexes, calc-alkaline batholiths, chondri tic
meteorites, and the surface-atmosphere interaction of the planet
Venus because these are important and because they are particularly
good illustrations of the chemical petrology approach. Considerable
attention also has been devoted to volcanic processes. In our
treatment of metamor phism in particular, an attempt has been made
to correlate and integrate the vast number of recent experimental,
theoretical, and field studies. However, we have not attempted a
comprehensive survey of all known rock types or occurrences, nor
did we review all the diverse opinions and conclusions on the
origins of controversial rocks. Instead we have chosen to stress
interpretations we regard as following most directly from the
evidence."
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