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On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes (Hardcover, 1st ed. 2017): Terrance John Hadlington On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes (Hardcover, 1st ed. 2017)
Terrance John Hadlington
R3,572 Discovery Miles 35 720 Ships in 12 - 19 working days

This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.

On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes (Paperback, Softcover reprint of the original 1st ed.... On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes (Paperback, Softcover reprint of the original 1st ed. 2017)
Terrance John Hadlington
R2,873 Discovery Miles 28 730 Ships in 10 - 15 working days

This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.

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