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On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes (Paperback, Softcover reprint of the original 1st ed. 2017)
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On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes (Paperback, Softcover reprint of the original 1st ed. 2017)
Series: Springer Theses
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This outstanding thesis describes a detailed investigation into the
use of low-oxidation-state group 14 complexes in catalysis,
developed at the cutting edge of inorganic and organometallic
chemistry. It includes the preparation of a number of landmark
compounds, some of which challenge our current understanding of
metal-metal bonding and low-oxidation-state main group chemistry.
Among the many highlights of this thesis, the standout result is
the development of the first well-defined, low- oxidation-state
main group hydride systems as highly efficient catalysts in the
hydroboration of carbonyl substrates, including carbon dioxide,
which are as efficient as those observed in more traditional,
transition-metal catalyses. These results essentially define a new
subdiscipline of chemistry.
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