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This book reviews the fundamental aspects of quinoxaline chemistry:
synthesis, reactions, mechanisms, structure, properties, and uses.
The first four chapters present a survey of the developments in
quinoxaline chemistry since the publication of the monograph on
"Condensed Pyrazines" by Cheeseman and Cookson in 1979. These
chapters give comprehensive coverage of all the methods of the
synthesis of quinoxalines and the important quinoxaline-containing
ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and
imidazo[1,5-a]quinoxalines. Chapter five describes many new methods
for the construction of quinoxaline macrocycles, which are
important in applications such as optical devices and materials.
The final chapter reviews all previously known rearrangements of
heterocyclic systems that lead to benzimidazole derivatives.
Mamedov critically analyses these transformations to reveal a novel
acid-catalyzed rearrangement of quinoxalinones giving
2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the
presence of nucleophilic reactants (MAMEDOV Heterocycle
Rearrangement). This book is of interest to researchers in the
fields of heterocyclic and synthetic organic chemistry.
This book reviews the fundamental aspects of quinoxaline chemistry:
synthesis, reactions, mechanisms, structure, properties, and uses.
The first four chapters present a survey of the developments in
quinoxaline chemistry since the publication of the monograph on
"Condensed Pyrazines" by Cheeseman and Cookson in 1979. These
chapters give comprehensive coverage of all the methods of the
synthesis of quinoxalines and the important quinoxaline-containing
ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and
imidazo[1,5-a]quinoxalines. Chapter five describes many new methods
for the construction of quinoxaline macrocycles, which are
important in applications such as optical devices and materials.
The final chapter reviews all previously known rearrangements of
heterocyclic systems that lead to benzimidazole derivatives.
Mamedov critically analyses these transformations to reveal a novel
acid-catalyzed rearrangement of quinoxalinones giving
2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the
presence of nucleophilic reactants (MAMEDOV Heterocycle
Rearrangement). This book is of interest to researchers in the
fields of heterocyclic and synthetic organic chemistry.
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