Metals in the hydrological cycle represent a very broad subject covering all parts of the geological cycle. The present version of this book, therefore, would not have been possible without the comments and suggestions for improvement on draft ver- sions of the various chapters by a large number of colleagues. We wish to express our gratitude to: P.A. Cawse (AERE, UK), J.N. Galloway (University of Virginia, USA) and S.E. Lindberg (Oak Ridge National Labo- ratory, USA) for reviewing the chapter on atmospheric trace metals. G. Batley (CSIRO, Australia) and B.T. Hart (Chisholm In- stitute of Technology, Australia) for reviewing the chapter on speciation of dissolved metals. E.K. Duursma (Delta Institute, The Netherlands), J.M. Bewers and P.H. Yeats (Bedford Institute of Oceanography, Canada) and D. Eisma (Netherlands Institute for Sea Re- search, the Netherlands) for reviewing the chapter on estuaries. P. Baccini (EAWAG, Switzerland) and W. Davison (Fresh- water Biological Association, UK) for reviewing the chapter on lakes. E.T. Degens (University of Hamburg, W-Germany) for re- viewing the chapter on the oceans, and J.P. Al (Public Works Department, The Netherlands) for reviewing most of the indi- vidual chapters. Without the collaboration of these colleagues this book would not have been possible in its present form.

A NATO Advanced Research Workshop (ARW) was conducted on June 21-23, 1994 in Visegnid, Hungary related to the clean-up of former Soviet military installation sites. This ARW included a technical site visit to the Komarom Base Site which is a former Soviet military installation in Hungary. During this three-day ARW, a strategy and set of recommendations were developed for selecting technologies and evaluating remediation as the economic and approaches for these sites. This strategy incorporated such critical issues financial conditions of the region, temporal considerations with regard to the urgency for which remedial actions are needed for these sites, the prioritization of resource allocations for site clean-up using risk-based considerations, and other crucial issues which will affect the implementation of remedial activities in the region. Approximately 40 invited experts, representing a number of different disciplines as well as both NATO and Cooperation Partner countries from the region, participated in this ARW. The types of former Soviet military installations in Central and Eastern Europe include: aircraft bases, fueling areas, maintenance and repair facilities, training grounds, non ammunition storage areas (for lubricants, chemicals, paints, equipment), ammunition storage areas, medical facilities, production facilities, and municipal facilities. Environmental contamination at these sites poses significant human health and environmental risks. Site contaminants include: solvents (e. g., BTEX), mineral oil hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), chlorinated hydrocarbons, heavy metals, pesticides residues, and polychlorinated biphenyls (PCBs). The primary environmental media adversely affected by these contaminants are soils, ground water and surface water."

The volume contains the main papers presented at the 1994 EUROTOX Congress, Basel, Switzerland, August 21-24, 1994. Toxicology has become a less descriptive science because more importance has been placed on the mechanisms underlying toxic effects. This is reflected in symposia and workshops devoted to species differences in organ toxicity, receptor-mediated toxicity and stereochemical effects of xenobiotics. Recent progress in the fields of immunotoxicology, ecotoxicology, and neurotoxicology is highlighted and documented together with the present discussion on harmonized regulatory guidelines.

International shipping is of great importance for the transport of a great many types of cargo. Substances and products considered dangerous constitute almost 50% of all the payload. It is obvious that stringent regulations are required in order to minimize the risks of accidents. These regulations, which are derived from good practice and which are based on research, have been adopted by a great number of countries. However, emergencies do occur in spite of all precautions. Such emergencies require fast and adequate response in order to confine the consequences for man and his environment to a minimum. Emergency response has political, legal, financial and technical aspects. This makes decision making extremely difficult. The papers carefully prepared and assembled in this book present an up-to-date picture of today's achievements, knowledge and difficulties that are being faced. It was the intention of Oilchem Recovery Denmark and TNO to bring the wide scatter of aspects together in a joined perspective. We also intended to spread the information on latest developments among the many people who are involved in combating calamities and in particular in decision making. Finally, we hope that this conference may help all of us to come to a safer transport of chemicals and a better aquatic environment. We thank all the authors for their magnificent contribution.

For the ninth Gothenburg Symposium time design and operation engineers as well as supervising and funding administrators in chemical water and waste water treatment, have come together to exchange ideas, experiences and personal views on issues of water and waste water management. While the main thrust of past symposia was in the description of the technological know-how of existing chemical unit-operations in water technology this ninth symposium focuses in addition on aspects of overall energy and mass flux analyses, the strive for more and more sustainable solutions (not only in technological turns) and public private partnership in all areas of water management. As the symposium in its effort to address also different geographical areas and therefore different water problems moved to Istanbul in Turkey a special effort was made in developing a platform for industrial water management.

Current research revolves around trends to bring technology into harmony with the natural environment and in order to protect the ecosystem. Bioremediation involves processes which reduce the overall treatment costs by using agricultural residues. Regeneration of the biosorbent further increases the cost effectiveness of the process, thus warranting its future success in solving water quality problems. Special emphasis is paid to chemical modifications resulting in tailored novel biomaterials which improve its sorption efficiency and environmental stability. In this way it can be used commercially as a simple, fast, economical, ecofriendly green technology, for the removal of toxic metals from waste water particularly in rural and remote areas of the country.

The purpose of this book is to give an introduction to the most important aspects of suspended matter in the aquatic environment: its origin and composition, the concentration distribution, transport and deposition, and the most important physical-chemical-bio logical process that affects suspended matter: flocculation. In Chap ter 1 the development of suspended matter observation and study throughout history is given, with the coming of a more modern approach during the 19th century and the first half of the 20th century, and the development of the present science of suspended matter after 1945. The sources of suspended matter in rivers, lakes, estuaries, and the sea are discussed in Chapter 2, which includes the supply of detrital particles as well as the formation of new particles in the water (organic matter, carbonate, opal). The concentration distribution of suspended matter in rivers, lakes, estuaries, tidal is discussed in Chapter 3, to which is areas, lagoons, and in the sea added a discussion on the sampling of suspended matter and on methods to determine its concentration. Particle composition is treated in Chapter 4, to which is added a section (4. 6) on the compositional analysis of suspended particles. Also included is a discussion on particle surface characteristics and the adsorption of elements and compounds onto particles."

This book contains the contributions to an European symposium on "Trace Elements in Environmental History", held from June 24th to 26th at GCittingen, FRG. The confe rence was organised by the Institute of Anthropology of the Georg August-University in GCittingen. At first glance, it might be surprising that the organizers are anthropolo gists. But this is a result of change of paradigm prehistoric anthropology is facing at the time. For decades, population development and population processes in the past have been looked at in terms of morphology, thus describing the diversity of human populations by the outer appearance of the skeletal findings and by the reconstruction of population structures. The new approach concentrates less on how people in the past looked like, but moreover on what they did and how they lived. Thus, research is based on ecosystem-theories, and it aims on the evaluation of ancient ecological features and past man/environment relationships. Research is encouraged since anthropologists are asked a lot of questions by historians and social scientists, who became more and more interested in the history of every day's life. Prehistoric anthropology today focu ses also on manners, habits, ways of life and environmental constituents as they can be traced from skeletal remains, which represent an important historical source. The ecosystemic approach is promising since the experiences of daily life certainly influence human behaviour, life style and mentality, thus directing reproduction and therefore population development.

Defining ecology as a system-theory oriented synthesis of both earth and life sciences, the book aims at a novel co- herent understanding of chemicalimpact on the lower at- mosphere and characteristic types of terrestrial ecosystems. To this end comprehensive flux-analytical and hierarchical modelling approaches were developed and consulted, which in- clude a thorough consideration of the specific physical and geographic boundary conditions of the processes involved. The first part is devoted to fundamentals of environmental chemistry and ecology, while the second deals with the com- plex atmospheric pathways of anthropogenic chemicals. In the last part, the manifold interactions of these compounds or their metabolites with the soil-vegetation complex of eco- systems are described. Chapters on pollutant impact on mate- rials and a review of chemical fate modelling are included. Thus scientists and practitioners facing ecological projects may expect to obtain a deeper insight into landscape ecology from the impact point of view owing to the concise presenta- tion of complex mechanisms and the generalized modelling ap- proach.

various places of the world. Thus, it is hoped that this up-to-date subseries would increase the "awareness" of the world's citizens and encourage governments to devote more attention and resources to address this issue. The series editors thank the international panel of contributors for bringing this timely series into completion. We also wish to acknowledge the very insightful input of the following colleagues: Prof. A.L. Page of the University of California, Prof. T.C. Hutchinson of the University of Toronto, and Dr. Steve Lindberg of the Oak Ridge National Laboratory. We also wish to thank the superb effort and cooperation of the volume editors in handling their respective volumes. The constructive criticisms of chapter reviewers also deserve much appreciation. Finally, we wish to convey our appreciation to my secretary, Ms. Brenda Rosier, and my technician, Ms. Claire Carlson, for their very able assistance in various aspects of this series.

It was intended to return with the International Gothenburg Symposia every other time to the birthplace of these events, Gothenburg in Sweden. But instead the 8th symposium has been invited to be organized and held in Prague, i. e. in the midst of Central and Eastern Europe a region now keen on intensified environmental control. This attests that the symposia have attained such standing in the interna tional world of operators, designers, officers and researchers in water treatment technology that their presence in various parts of the world has been requested. And this ever growing significance, in short the success of this conference series, stems form the fact that the symposia offer a unique platform for the exchange of ideas and experiences on all aspects of water and wastewater treatment between administrators, engineers and scientists. The content of this book, i. e. the schedule of the symposium lectures, results for the most part from a vast response to an international call for papers. Many excellent contributions are included in this volume but at the same time many outstanding ones could not be included for lack of time and space. The total sum of these contributions document again the development in the field, both in terms of new technological (and other) developments as well as public and administrative acceptance and approval of solutions offered."

Wetlands are, by their very nature, ephemeral and transitional, which makes them challenging to characterize. Yet the need for characterizing wetlands continues to grow, particularly as we develop a better understanding of the wealth of ecosystem services that they provide. Wetland Landscape Characterization: Practical Tools, Methods, and Approaches for Landscape Ecology, Second Edition shows how wetland characterization tools, methods, and approaches can be integrated to more effectively address twenty-first-century wetland issues. A Practical Toolbox for Integrated Wetland Landscape Characterization The book explains how to locate, identify, and map the extent of wetlands to learn more about their importance to society and the larger landscape. It examines jurisdictional, regulatory, and practical applications from the scientific, engineering, and lay perspectives. Fully updated, the second edition reflects an emerging infrastructural, ecosystem goods-and-services perspective to better assist readers who may encounter these concepts and challenges as they assess and characterize wetlands. Examples and case studies illustrate a variety of situations and solutions, highlighting the use of current techniques to assess, inventory, and monitor natural resources under changing conditions. These examples offer lessons and ideas for the issues encountered every day by wetland landscape ecology practitioners. The book also refers readers to additional resources to help them solve specific challenges. New in This Edition Updates of practical geospatial methods More project-driven examples A description of the pitfalls of using ecological data at landscape scales, along with solutions Alternative techniques for a variety of practitioners Linkages between field and landscape ecological practices Online resources for practitioners New illustrations This book helps readers develop the concepts, skills, and understanding of how to best achieve project goals in the rapidly changing disciplines of landscape science and wetland ecology and management. A valuable resource, it provides practical tools, methods, and approaches for conceptualizing, designing, and implementing broad-scale wetland projects that take into account critical societal linkages.

Seasonal Snowpacks examines the processes which control the chemistry of seasonal snowcover and provides detailed information on the biogeographical distribution of snow (e.g. urban, alpine snowpacks), snow composition (e.g. micropollutants, stable isotopes) or the physical and biological processes which influence the chemical changes in snow (e.g. wind, microbiological activity). The fluxes of chemicals at the snow-atmosphere and snow-soil interfaces are examined, as are processes which modify composition within the snowcover. It is the first book in which the reader will find a comprehensive overview of the theoretical concepts, latest measurement techniques, process-oriented research methods, and models of studies in snow chemistry. The linkages between snow chemistry, atmospheric chemistry and hydrology will make this book of use to both research workers and students in the physical and biological sciences and to natural resource management personnel.

The fall of the iron curtain revealed widespread environmental and safety short comings in relation to industrial operations, mining and other human activities. It was the purpose of this Advanced Research Workshop, sponsored by NATO, to bring together a group of eminent experts from East and West in order to present and analyse environmental data, assess environmental damage, establish priorities, strategies and methods of remediation and compare these with case studies from the Western World. In this volume a number of important contributions have been gathered, that reflect the presentations and discussions held. Alfons Georges Buekens Vasily Victorovich Dragalov Table of Contents I. General Consideration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Scientific and Technological Policy of Ministry of Sciences of Russian Federation in Application to Water Treatment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Target Federal Program - Revival of the Volga. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 II. River Basins and their Characterization. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 River Basin Management in the Upper and Middle Odra River . . . . . . . . . . . . . . . . . . . 9 Water Quality and Environmental Degradation in the Tom River Basin (Western Siberia): The Need for an Integrated Management Approach . . . . . . 29 Danube Environmental Programme on the Hron River Basin, Slovakia . . . . . 39 Global Regularities in the Occurence of the Environmentally Devastated Urban Areas as a Fundamental Basis for Urbo-Monitoring (Methodology of Sustainable Development of Towns in River Basins) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Principles of Integrated Water Management for the Revival of Old Industrial Areas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 Pollution Potentials of Storm Runoff from Urban and Industrial Areas . . . . . 105 Assessment of Pollution Hazards in the Estarreja Aquifer (Portugal) Remediation Strategies. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ."

The Karl Fischer titration is used in many different ways following its publication in 1935 and further applications are continually being explored. At the present time we are experiencing another phase of expansion, as shown by the development of new titration equipment and new reagents. KF equipment increasingly incorporates microprocessors which enable the course of a titration to be programmed thus sim plifying the titration. Coulometric titrators allow water determinations in the micro gram-range: the KF titration has become a micro-method. The new pyridine-free re agents make its application significantly more pleasant and open up further possibili ties on account of their accuracy. To make the approach to Karl Fischer titrations easier, we have summarized the present knowledge in this monograph and we have complemented it with our own studies and practical experience. As this book should remain "readable," we have tried to keep the fundamentals to a minimum. Historical developments are only mentioned if they seem to be necessary for understanding the KF reaction. The ap plications are described more fully. Specific details which may interest a particular reader can be found in the original publications cited. The referenced literature is in chronological order as the year of publication may also prove informative. Thus, 6902] for example denotes 69 for 1969 being the year of publication and 02 is a non-recurring progressive number. The referenced litera ture includes summaries which we hope will be of help to find the "right" publica tion easily."

This textbook provides a comprehensive review of the problems associated with the supply of drinking water in the developed world. Since the first edition of this book was published, water companies and regulators have been presented with numerous new challenges - global warming has seriously affected water supplies and water quality; advances in chemical and microbial analysis have revealed many new contaminants in water that were previously undetectable; and recent terrorist attacks have demonstrated how vulnerable water supplies are to contamination or disruption. This new edition includes an overview of the current and emerging problems, with potential solutions. It has been completely updated, and includes the WHO Revised Drinking Water Guidelines. An ideal textbook for courses in environmental science, hydrology, environmental health and environmental engineering; it also provides an authoritative reference for practitioners and professionals in the water supply industry.

The Commission of the European Communities presents with this volume the proceedings and the conclusions of the second European Symposium on the analysis of organic micropollutants in water. This symposium has been organized within the framework of the Concerted Action "Analysis of Organic Micropollutants in Water." This research programme is jointly implemented by the European Communities and Norway, Portugal, Spain, Sweden, Switzerland and Yugoslavia within the framework of a COST (Cooperation Scientifique et Technique) agreement. The project, also known as COST Project 64b bis, aims at coordinating all relevant research in this field in the participating countries. An effort is made to improve methods and techniques for the identification and quantitative determination of organic compounds present in all types of water. The symposium permitted to review the results achieved during the past three years of research in the following areas: - Sampling and sample treatment - Gas-chromatography Separation of non-volatile compounds, in particular high performance liquid chromatography (HPLC) - Mass-spectrometry - Data processing - Specific analytical problems, in particular the analysis of organic halogens and phenolic compounds. The volume gives a rather complete overview of the activities in this field in Europe. We are confident that it constitutes a valuable contribution to solving the important problems posed by the huge number of already identified or yet unknown organic pollutants in water. The Commission of the European Communities wishes to express their sincere thanks to the co-organizers, the National Board for Science and Technology, Dublin and An Foras Forbartha, Dublin.

"awareness" of the world's citizens and encourage governments to devote more attention and resources to address this issue. The series editors thank the international panel of contributors for bringing this timely series into completion. We also wish to acknowledge the very insightful input of the following colleagues: Prof. A. L. Page of the University of California, Prof. T . C. Hutchinson of the University of Toronto, and Dr. Steve Lindberg of the Oak Ridge National Laboratory. We also wish to thank the superb effort and cooperation of the volume editors in handling their respective volumes. The constructive criticisms of chapter review ers also deserve much appreciation. Finally, we wish to convey our appreciation to my secretary, Ms. Brenda Rosier, and my technician, Ms. Claire Carlson, for their very able assistance in various aspects of this series. Aiken, South Carolina Domy C. Adriano Coordinating Editor Preface to Acidic Precipitation, Volume 5 (Advances in Environmental Science) Acidification research has been ongoing for several decades. It was not until the 1980s, however, that scientists began to recognize the complex ity of the factors causing the decline in forest growth and deterioration of fish populations in acidified lakes. The general feeling, based on correla tive research, was that long-range transported air pollution was the main cause. Proof, however, was difficult to obtain because of complex interac tions of various stress factors including natural ones."

Co-management is a highly dynamic, evolving, adaptive, and forward looking process. This edited volume covers theoretical background and includes supporting lessons learnt from field experiences. The book has case studies from both North and South America (co-management of fisheries, resilience in near-shore waters of the Great Lakes basin, water level management in Lake Ontario, and case studies from Chile and Brazil), Europe (Tisza river, coastal management and examples of rivers from the Netherlands and from Uzbekistan), Africa (Lake Victoria) and Asia (Pushkar Lake in India).

Most large river basins in the world are transboundary. Experience with such basins emphasizes the urgent need for more efficient transnational water management. This book details recent initiatives undertaken in the Meuse basin (North-West Europe) to develop a transnational adaptation strategy to deal with the impact of climate change. In the 21st century, floods in the Meuse basin are expected to become more intense and more frequent, while summers will be hotter and drier. The transnational adaptation strategy combines scientific research to fill important gaps in knowledge, innovative natural and structural water retention measures, and enhanced (transnational) crisis management. As a scientific basis for this adaptation strategy, common climate and hydrological scenarios have been developed, as well as more uniform methods for transnational flood risk assessment and mapping. The contributions in Transboundary Water Management in a Changing Climate were presented at the final conference of the European project AMICE (Sedan, France, March 2013). They demonstrate that the development of a vision at the level of the river basin, rather than within the national or regional boundaries, faces many practical challenges but offers unique opportunities for adaptation. Covering a wide range of topics, from the latest advances in climate and hydrological research to practical implementation of adaptation measures and communication issues, Transboundary Water Management in a Changing Climate offers a genuine bridge between research and practice, and also reports on similar developments in other river basins.

As the coastal human population increases in the United States, there will likely be increasing environmental and socioeconomic pressures on our coastal and estuarine environments. Monitoring the condition of all our nation's coastal and estuarine ecosystems over the long term is more than any one program can accomplish on its own. Therefore, it is crucial that monitoring programs at all levels (local, state, and federal) cooperate in the collection, sharing, and use of environmental data. This volume is the proceedings of the Coastal Monitoring Through Partnerships symposium that was held in Pensacola, Florida in April of 2001, and was organized by the U.S. Environmental Protection Agency's (EPA's) Environmental Monitoring and Assessment Program (EMAP), and the Council of State Governments (CSG). It contains papers that describe various multi-disciplinary coastal and estuarine environmental monitoring programs, designed and implemented by using regional and national partnerships with federal and state agencies, academia, Native American tribes, and nongovernmental organizations. In addition, it includes papers on modeling and data management; monitoring and assessment of benthic communities; development of biological indicators and interlaboratory sediment comparisons; microbiological modeling and indicators; and monitoring and assessment of phytoplankton and submerged aquatic vegetation. There are many components involved in determining the overall impacts of anthropogenic stressors on coastal and estuarine waters. It will take strong partnerships like those described in this volume to ensure that we have healthy and sustainable coastal and estuarine environments, now and in the future.

As requirements for high quality wastewater effluent increase, quantities of sludge generated also increase. Contaminants removed from wastewater concentrate in the sludge and can represent serious environmental insult and health effects if not properly managed. The cost of sludge handling can be estimated to constitute as much as 50% of the cost of wastewater treatment. If properly managed, however, sludge may be considered a resource of value. Unfortunately, very little attention in the scientific commu nity has been given the sludge dilemma either in research or in practice. Sludge properties are presently characterized in various ways which do not permit rational design and operation of sludge management systems. The need for basic information regarding sludge properties and behavior was the impetus for a NATO Advanced Study Institute. The NATO Advanced Study Institute entitled "Sludge Character istics and Behavior" was held July 17-26, 1979, at the Uni versi ty of Delaware, Newark, DE 19711, USA. The excellent program quality was a result of both outstanding lecturers and participants. Twelve countries were represented at the Institute so that both formal, professional discussions and informal social activities crossed a broad spectrum of cultures. Gratitude is expressed to all contributors to this volume. Special acknowledgement must be given to the Scientific Affairs Division of the North Atlantic Treaty Organization. Without its financial support, this Advanced Study Institute would not have been possible."

The "Fourth European Symposium on Organic Micropollutants in the Aquatic Environment" was held in Vienna (Austria) from 22 to 24 October 1985. The Symposium was organized wi thin the framework of the Concerted Action COST 641* which is included in the Third R&D Programme on the Environment of the Commission of the European Communities. The aim of the Symposium was to review recent scientific and technical progress in the area of organic micropollutants in the aquatic environment and to present relevant research papers related to analytical methodologies, transformation reactions and transport of organic micropollutants in water, and water treatment processes. A special session was devoted to theoretical aspects and future acti vi ties. Furthermore, special poster sessions were organized where original contributions were presented. This book presents the Proceedings of the Symposium including all review papers, presentations of research papers and extended versions of all posters. We believe that these Proceedings provide a good overview of the activities in this field in Europe. We are confident that it will constitute a valuable contribution to the understanding and solution of the problems posed by organic micropollutants in the aquatic environment. The Commission of the European Communi ties whishes to express its grati tude to the co-organizers of the Symposium, Bundesministerium fUr Gesundheit und Umweltschutz, Wien, and Der Osterreichische Wasserwirtschaftsverband.

The microbiology of drinking water remains an important worldwide concern despite modem progress in science and engineering. Countries that are more technologically advanced have experienced a significant reduction in water borne morbidity within the last 100 years: This reduction has been achieved through the application of effective technologies for the treatment, disinfec tion, and distribution of potable water. However, morbidity resulting from the ingestion of contaminated water persists globally, and the available ep idemiological evidence (Waterborne Diseases in the United States, G. F. Craun, ed. , 1986, CRC Press) demonstrates a dramatic increase in the number of waterborne outbreaks and individual cases within the United States since the mid-1960s. In addition, it should also be noted that the incidence of water borne outbreaks of unknown etiology and those caused by "new" pathogens, such as Campylobaeter sp. , is also increasing in the United States. Although it might be debated whether these increases are real or an artifact resulting from more efficient reporting, it is clear that waterborne morbidity cannot be ignored in the industrialized world. More significantly, it represents one of the most important causes of illness within developing countries. Approxi mately one-half the world's population experiences diseases that are the direct consequence of drinking polluted water. Such illnesses are the primary cause of infant mortality in many Third World countries.