This book brings together current thought on several aspects of the use of pesticides in and around homes, schools and workplaces. The book addresses several parts of the process, from the discovery and development of new active ingredients, their formulation, use, longevity, environmental fate and human exposure.

Describes more than 800 currently available agricultural chemical products covering a wide variety of uses. Only the most recent information has been included. Products range from pesticides, herbicides, insecticides, and fungicides to plant growth regulators, animal repellents, nematicides, soil penetrants, seed treatments, composting aids, micronutrients, and specialty fertilizers.

This book attempts to define practical solutions to pesticide users' disposal problems. A major agreement must be reached on what can be done, legally and technically, to deal with the difficulties of proper pesticide-related waste disposal, and who should share in the cost of a clean environment.

The book covers a critical compilation of analytical methods used for the monitoring of pesticides and their degradation products in water. It contains up-to-date material and is the direct result of the authors' experience in the field of pesticide analysis. The book is structured in six chapters, starting from general aspects of pesticides like usage, physicochemical parameters and occurrence in the environment. A second chapter is devoted to sampling from water matrices, stability methods of pesticides in water and quality assurance issues. The general chromatographic methods for pesticides are reported, including the newly developed electrophoresis methods and GC-MS and LC-MS confirmatory analytical methods. Sample preparation methodologies, including off-line and on-line techniques are described in the next two chapters, with a comprehensive list of examples of pesticides and many metabolites, including the use of different GC-methods and LC-methods. The final chapter is devoted to the development of biological techniques, immunoassays and biosensors, for the trace determination of pesticides in water samples.

The book answers one of the key problems in pesticide analysis: the diversity of chemical functional groups, with varying polarity and physicochemical properties. Pesticides and their metabolites have received particular attention during the last few years in environmental trace-organic analysis. For instance, in the case of groundwater, the use of pesticides has become a cause for concern. Under the right conditions, pesticides, such as fertilizer nitrogen, can move through the soil into groundwater, a phenomenon once thought improbable. The movement of agrochemicals in surface water flow can be, in some instances, a major problem, specially in the case of water soluble pesticides that are generally transported to estuarine and coastal waters. Estuarine waters feature gradients of both pollutant concentrations and physicochemical characteristics such as salinity, turbidity and pH, and all these parameters must be carefully considered when developing methods of analysis for trace organics in estuarine waters.

One of the key parameters in analytical determination is the environmental sampling. Different protocols and devices are needed for sampling sea-water samples - usually using large sample volumes of more than 50 litres either with LLE or SPE, with the problems encountered due to dissolved and particulate matter - which is different from drinking water and well water sampling. The representativeness of the sampling is also of concern.

The sample preparation of organic compounds from water matrices has been recognized to be a bottleneck and it has been traditionally neglected in the literature. We should comment following R.W. Frie's ideas - that the most sophisticated hardware is useless if the chemistry in the protocol does not work. During the last few years new adsorbents have appeared - carbon type, polymeric sorbents with high capacity and immunosorbents - which can more efficiently trap the more polar compounds.

The development of advanced automation methods based, usually on solid phase extraction techniques - PROSPEKT, OSP-2 and ASPEC XL - are examples of commercially available equipment that are of growing importance. These systems are generally coupled to LC and GC techniques.

Sampling and sample handling can not be regarded as separate techniques in the analytical process and both should be integrated into the whole analytical determination. For this reason, validation and confirmation methods, such as mass spectrometry, either GC-MS and/or LC-MS, are needed. These serve to check the quality assurance of the developed method. The discussion between multiscreening versus specific methods of analysis and the influence of the matrix (ground-, surface- and estuarine-water), is also a point of concern due to the diversity of chemical classes within the compounds of study.

Finally the use of rapid methods of analysis, which refer basically to biological techniques, biosensors and immunoassays are also of growing interest for the determination of pesticides in environmental matrices. The rapid development of these techniques, being more sensitive and that can work at different pH and drastic environmental conditions, like very different pH and salinity values, makes that these methods are very useful and complementary to conventional GC and/or LC techniques for the determination of pesticides.

This volume pulls together a wealth of up-to-date information on the toxicology of this diverse and ubiquitous class of insecticides. Leading experts review the reactivity of organophosphorus compounds with cholinesterase, as well as their metabolism and biological effects on humans and other nontarget organisms. The book not only covers the anticholinesterase actions of organophosphates, but also other, presumably independent, effects, such as teratogenicity, delayed neuropathy, immunotoxicity, and behavioral toxicity.
Key Features
* Offers crucial overviews of chemical and biochemical reactivity and biological responsiveness of mainly nontarget organisms
* Reviews new developments in assessment of metabolism and disposition of organophosphorus compounds
* Examines organophosphorus compound-induced toxicity mediated by mechanisms other than
inhibition of acetylcholinesterase
* Covers new research on differences in toxicity induced by the variety of organophosphorus
* Analyzes current controversies on the relevance of certain biochemical parameters in actual organophosphate toxicity "in vivo"

This new volume brings together scientists from a variety of disciplines to present, summarize, review, and update information related to bioherbicides. Among the topics covered are pathogens with potential as bioherbicides, phylloplane-pathogen interactions, aspects of soil microorganisms, formulation and commercialization of microbes as bioherbicides, genetic aspects of pathogens for weed control, and chemistry and biochemistry of microbial-plant interactions. A valuable source of information for researchers involved in both biological weed control and herbicide development.

Describes approximately 350 fungicides, biocides and preservatives which are currently available for industrial and agricultural usage. The book will be of value to industrial and agricultural, technical and managerial personnel involved in the specification and use of these products. It has been produced from information received from numerous industrial companies and other organizations.

Pesticide Profiles: Toxicity, Environmental Impact, and Fate is like three books in one-it is a profile containing specific information about 137 pesticides, a primer of environmental toxicology, and an extensive trade name index. Profiles of each pesticide contain regulatory information, toxicity assessments, environmental fate data, physical properties, and acceptable exposure limit values. What these values and data mean in terms of human toxicity is clearly interpreted as well. The book also describes the meaning of carcinogenicity and how it is assessed in non-technical terms the non-expert can understand. Readers with a technical background are provided with the data to make their own judgments.
In addition to information about specific pesticides, there are sections on general classes of pesticides, such as organophosphates. This information allows readers to make inferences about any pesticide in a class, even if a profile is not provided. Pesticide Profiles: Toxicity, Environmental Impact, and Fate goes beyond the usual listings of toxicity values or environmental half-lives to offer a broad understanding to readers of various backgrounds and interests.

This work highlights the physical chemistry of surfactant solutions, detailing a fundamental method of selecting surfactants for agrochemical formulations and delineating how surfactants enhance the biological efficacy of agrochemicals. The unique properties of surfactants that have a major influence on the performance of an agrochemical are summarized.;The book is intended for physical, surface and colloid chemists; biochemists; microbiologists; agronomists; research and development personnel in the pesticide and fertilizer industries; and upper-level undergraduate and graduate students taking chemistry and chemical engineering courses.;College and university bookstores may order five or more copies at a special price which is available on request from Marcel Dekker Inc.

Basic Guide to Pesticides covers the physical properties of about 700 pesticides and their contaminants and related health hazards. It is important in dealing with environmental problems in general and individual cases.

This book presents detailed information on the imidazolinone herbicides, provided in chapters contributed by scientists and product development managers who work for American Cyanamid, categorized in sections covering chemistry, biology, metabolism and residues, environmental fate and product performance. Each chapter has its own bibliography, and appendices give (a) details of the chemical and physical properties, formulations and trade names of imazapyr, imazamethabenz-methyl, imazethapyr and imazaquin, and (b) the scientific and common names of species used in the text. There is a general bibliography of references for each of the above imidazolinone herbicides and a useful subject index. The individual chapters are abstracted separately.

With increasing population and industrialization, our negative impact on our environment is no longer limited to coastal and surface waters or to urban air; it is necessary to examine the movement of chemical pollutants over vastly greater areas. Oceans, deep groundwater aquifers, and even the stratosphere are significantly affected. The mechanisms by which pollutants reach these areas, how they migrate and are transformed through physical and biochemical processes, and their ultimate effects are the topics at the forefront of environmental science. This volume addresses the fate of chemical pollutants in our air, water, and soil. The result of a historic collaboration between eminent Russian and American scientists, Fate of Pesticides and Chemicals in the Environment contains new predictive models of transport and transformation from many of the leading scientists in this area of research. Numerous informative chapters analyze the biotransformation of organic chemicals and pesticides, atmospheric deposition of toxic pollutants in the Great Lakes and elsewhere, the transport of volatile organic compounds and pesticide residues through surface soil, and many other important problems in the field. The sources and pathways of pollutants into all areas of the environment are thoroughly explored; the role of free radicals in chemical transformations, surface and bottom sediment redox reactions in water, the contribution of microbial degradation, and considerations for in situ biorestoration are just a few of the complex issues addressed. The book also contains comprehensive information on pesticide labeling laws and groundwater protection which will be of interest to all soil and waterchemists and environmental engineers.

This book presents the current approaches for insect pest control as a "green" alternative to classical and more toxaic agrochemicals. An overview of the recent advances in insecticide chemistry is also included, which will be of interest to a vast group of researchers - agrochemists, biochemists, chemists and toxicologists. The combination of both chemical and toxicological aspects of insecticides is unique and the book includes contributions from synthetic chemists, entomologists, environmentalists and toxicologists giving it wide appeal. Throughout the book, the different approaches that involve "greener chemicals" are emphasized. The book is divided into 9 chapters, each considering the state of art of each family of insecticides, together with future expectations. Each chapter gives a description of useful biorational insecticides, highlighting environmentally-friendly processes and then the mode of action is fully-described, emphasizing selectivity towards targeted species. Finally, for every family of compounds, their environmental effects (toxicity, bioaccumulation and metabolism) is considered, comparing them to classical insecticides, including human and environmental risk assessments. In addition the formulation, dispersal and persistence in the environment are covered as key aspects in developing greener agrochemicals. The book also includes a general introduction to entomology, with special emphasis on those insects that act as vectors in the spread of diseases. Insects that may be potential pests against humans and livestock are included, focusing on their life cycles, and physiology, as a logical comprehension of mode of action of insecticides. In addition there is a chapter on classical insecticides (covering both, approaches prior to the chemical era, and classical chemical insecticides, organochlorinated, organophosphorus, and carbamates) for comparison with current trends in pest control. The negative environmental effects that such insecticides have caused in nature, such as poisonings, bioaccumulation or toxic effects are highlighted. It is hoped that the use of more specific agrochemicals and approaches may avoid, or at least considerably reduce such severe and irreversible effects in nature. The insecticides covered are considered from numerous points of views: chemistry, toxicological profile, risk assessment, legal status, environmental behaviour and selectivity. The most important families of currently used insecticides are covered and critical discussions about future perspectives are included with frequent comparisons to classical insecticides. The following topics are covered in the book, as greener alternatives to classical insecticides: " Pyrethrins and pyrethroids " Neonicotinoids " Spynosins " Insect growth regulators " Botanical insecticides " Microbial insecticides " Integrated Pest Management Programs (IPM)

This handbook provides a systematic description of the principles, procedures, and technology of the modern analytical techniques used in the detection, extraction, clean up, and determination of pesticide residues present in the environment. This book provides the historical background of pesticides and emerging trends in pesticide regulation. The text discusses various techniques for analysis, including supercritical fluid extraction, disposable electrochemical biosensors, matrix solid-phase dispersion, volatmetric methods, and liquid chromatography. The authors also address the scope and limitation of NEEM products in plant protection as well as the analysis of medicinal plants.

Worldwide, there are a vast array of agricultural pesticides and chemicals used to eliminate pests and to protect health, food, and fiber. The safe handling, usage, and disposal of these chemicals and pesticides is of vital importance. The Agrochemical and Pesticides Safety Handbook serves as a field resource on the hazards of these pesticides and chemicals.
Providing information on more than 500 pesticides and 100 agricultural chemicals, this informative handbook guides the reader in selecting proper respiratory protection, chemical protective clothing, and storage methods. The text also instructs users on proper response procedures for fires, spills, and other incidents involving these chemicals.

This book presents a collection of known information on the insecticidal properties of constituents of higher plants, microorganisms, animals, and marine flora and fauna in order to assist researchers in selecting leads for further development.

Pesticide Formulation and Adjuvant Technology brings together experts from industry, academia, regulatory offices, and the legal profession to provide a complete and international reference on agrichemical formulations and modern adjuvant technology.
Global specialists discuss key topics, from scientific and technical issues to regulatory and legal aspects, including:

Emphasizing the need for more integrated pest management programmes, this work presents the development and state-of-the-art technology of genetically-engineered microbes, viruses, bacterial toxins and plants. Throughout, both environmental and regulatory concerns are addressed.

This quick-reference guide contains over 400 Fourier-transform infrared (FTIR) spectra of commonly used pesticides and related metabolites. Systematically arranged for easy referral, the book: supplies relevant chemical, physical and structural data, in addition to the spectra; compares the improved quality of spectra performed on Fourier transform instruments, in terms of signal-to-noise ratio and optical resolution, to those recorded on dispersive spectrometers; and promotes Good Laborotory Practices (GLP) and Good Manufacturing Practices (GMP) by applying infrared spectroscopy to identify control of standards prior to performing qualitative and quantitative analyses.

Reference to the design of new insecticides nontoxic to the environment and the public emphasizing optimal food production with greater safety. Some 30 international experts examine topics including new types of active molecules among natural products and animal toxins; insect metabolic and organ sy

Genital prolapse, or pelvic organ prolapse, occurs when the structures of the pelvis protrude into the outside vaginal canal. "Genital Prolapse and Urinary Incontinence" is the first book of its kind dedicated specifically to genital prolapse and is filled with every different type of prolapse, including the bladder, uterus, rectum, and the mucosal fold containing the intestine. Covering all aspects of this defect while emphasizing the managed care of genital prolapse, this text also explores both surgical and non-surgical treatments, which include methods for the diagnosis and treatment of all abnormalities.

This source examines:

This guide brings together the varied and multiple skills and activities required of pest control practitioners, including biology, chemistry, architecture, engineering, sales, logistics, legal and accounting, presented with a primary emphasis on pest organisms at its core. This book provides information and tips on all of these aspects and: explores the business of controlling pests (including trends in the industry, pest control tools, and sustainable pest control); covers biological information on each pest in addition to information on control and management, monitoring and follow-up; focusses particularly on globally significant pests with internationally-applicable use and guidance; and provides practical and hands-on experience, drawing on original case studies This is a key resource for pest control practitioners, as well as in-house staff of companies or buildings involved in household or urban pest control. It is also a valuable reference for researchers, and sanitation and building managers.

Throughout Asia, Australia and the Pacific, and increasingly in Africa, the primary horticultural insect pests are fruit flies belonging to the genera Bactrocera, Zeugodacus and Dacus (Diptera: Tephritidae: Dacini). The Dacini is a hugely diverse clade of nearly 900 species endemic to the rainforests of Asia, Australia and the western Pacific, and the savannas and woodlands of Africa. All these species lay their eggs into fleshy fruits and vegetables, where the maggots feed, therefore destroying the fruit. In addition to being crop pests, dacines are also invasive pests of major quarantine importance and their presence in production areas can significantly impact market access opportunities. This broad text provides a rapid introduction to this economically and ecologically important group, which includes species such as the Oriental fruit fly (B. dorsalis), Melon fly (Z. cucurbitae), Queensland fruit fly (B. tryoni) and the Olive fly (B. oleae). Broken into three primary sections, it first explores the evolutionary history, systematic relationships, taxonomy and species-level diagnosis of the Dacini flies. The following biology section covers their life history, population demography, behaviour and ecology, and natural enemies. The final section of the book covers the management of these flies, with chapters on pre-harvest, post-harvest and regulatory controls. Each chapter concludes with a list of key monographs, papers or book chapters for further reading. This book will be of interest to field entomologists, extension officers, quarantine officers and market access negotiators, as well as students of applied entomology and pest management.

Increasing resistance to established fungicides has stimulated the search for novel fungicides with new modes of action. Environmental concerns now also demand that these have low environmental impact and toxicity. Fungicidal Activity discusses new approaches to fungicide development including biological control and genetic engineering, and takes a global view of the future of fungicidal development. Fungicidal Activity is a volume in the Wiley Series in Agrochemicals and Plant Protection. This series brings together current scientific and regulatory knowledge and perspectives on all aspects of the use of chemicals and biotechnology in agriculture.

The chemistry of heterocycles is an important branch of organic chemistry. This is due to the fact that a large number of natural products,
e. g. hormones, antibiotics, vitamins, etc. are composed of heterocyclic structures. Often, these compounds show beneficial properties and are
therefore applied as pharmaceuticals to treat diseases or as insecticides, herbicides or fungicides in crop protection. This volume presents important agrochemicals. Each of the 21 chapters covers in a concise manner one class of heterocycles, clearly structured as follows:
* Structural formulas of most important examples (market products)
*Short background of history or discovery
* Typical syntheses of important examples
* Mode of action
* Characteristic biological activity
* Structure-activity relationship
* Additional chemistry information (e.g. further transformations, alternative syntheses, metabolic pathways, etc.)
* References
A valuable one-stop reference source for researchers in academia and industry as well as for graduate students with career aspirations in the
agrochemical chemistry.