There are more than 20 million chemicals in the literature, with new materials being synthesized each week. Most of these molecules are stable, and the 3-dimensional arrangement of the atoms in the molecules, in the various solids may be determined by routine x-ray crystallography. When this is done, it is found that this vast range of molecules, with varying sizes and shapes can be accommodated by only a handful of solid structures. This limited number of architectures for the packing of molecules of all shapes and sizes, to maximize attractive intermolecular forces and minimizing repulsive intermolecular forces, allows us to develop simple models of what holds the molecules together in the solid. In this volume we look at the origin of the molecular architecture of crystals; a topic that is becoming increasingly important and is often termed, crystal engineering. Such studies are a means of predicting crystal structures, and of designing crystals with particular properties by manipulating the structure and interaction of large molecules. That is, creating new crystal architectures with desired physical characteristics in which the molecules pack together in particular architectures; a subject of particular interest to the pharmaceutical industry.

This book presents the first comprehensive, interdisciplinary review of the rapidly developing field of air lasing. In most applications of lasers, such as cutting and engraving, the laser source is brought to the point of service where the laser beam is needed to perform its function. However, in some important applications such as remote atmospheric sensing, placing the laser at a convenient location is not an option. Current sensing schemes rely on the detection of weak backscattering of ground-based, forward-propagating optical probes, and possess limited sensitivity. The concept of air lasing (or atmospheric lasing) relies on the idea that the constituents of the air itself can be used as an active laser medium, creating a backward-propagating, impulsive, laser-like radiation emanating from a remote location in the atmosphere. This book provides important insights into the current state of development of air lasing and its applications.

The purpose of 'Numerical Analysis of Heat and Mass Transfer in Porous Media' is to provide a collection of recent contributions in the field of computational heat and mass transfer in porous media. The main benefit of the book is that it discusses the majority of the topics related to numerical transport phenomenon in engineering (including state-of-the-art and applications) and presents some of the most important theoretical and computational developments in porous media and transport phenomenon domain, providing a self-contained major reference that is appealing to both the scientists, researchers and the engineers. At the same time, these topics encounter of a variety of scientific and engineering disciplines, such as chemical, civil, agricultural, mechanical engineering, etc. The book is divided in several chapters that intend to be a resume of the current state of knowledge for benefit of professional colleagues.

The thesis presents experimental and theoretical results about the surface dynamics and the surface Dirac fermion (DF) spectral function of the strong topological insulators Bi2Te3 and Bi2Se3. The experimental results reveal the presence of a strong Kohn anomaly in the measured surface phonon dispersion of a low-lying optical mode, and the absence of surface Rayleigh acoustic phonons. Fitting the experimental data to theoretical models employing phonon Matsubara functions allowed the extraction of the matrix elements of the coupling Hamiltonian and the modifications to the surface phonon propagator that are encoded in the phonon self-energy. This allowed, for the first time, calculation of phonon mode-specific DF coupling (q) from experimental data, with average coupling significantly higher than typical values for metals, underscoring the strong coupling between optical surface phonons and surface DFs in topological insulators. Finally, to connect to experimental results obtained from photoemission spectroscopies, an electronic (DF) Matsubara function was constructed using the determined electron-phonon matrix elements and the optical phonon dispersion. This allowed calculation of the DF spectral function and density of states, allowing for comparison with photoemission and scanning tunneling spectroscopies. The results set the necessary energy resolution and extraction methodology for calculating from the DF perspective.

Mechanical Properties of Single Molecules and Polymer Aggregates Rudiger Berger, Kurt Binder, Gregor Diezemann, Jurgen Gauss, Mark Helm, Katharina Landfester, Wolfgang Paul (Halle), Peter Virnau. Optical Properties of Individual Molecular Aggregates and Nano Particles Thomas Basche, Hans-Jurgen Butt, Gregor Diezemann, Jurgen Gauss, Klaus Mullen, Harald Paulsen, Carsten Sonnichsen, Rudolf Zentel. Structure Formation of Polymeric Building Blocks I: Self-assembly of Copolymers Kurt Binder, Holger Frey, Andreas Kilbinger (Univ. Fribourg), Ute Kolb, Michael Maskos (IMM Mainz), Wolfgang Paul (Univ. Halle), Hans Wolfgang Spiess. Structure Formation of Polymeric Building Blocks II: Complex Polymer Architectures Kurt Binder, Hans Jurgen Butt, Angelika Kuhnle, Klaus Mullen, Wolfgang Paul (Univ. Halle), Erwin Schmidt, Manfred Schmidt, Hans Wolfgang Spiess, Thomas Vilgis. Structure Formation of Polymeric Building Blocks III: Polymer Complexes in Biological Applications Kurt Kremer, Heiko Luhmann, Christine Peter, Friederike Schmid, Erwin Schmidt, Manfred Schmidt, Eva Sinner (Univ. of Natural Resources, Vienna), Tanja Weil (Univ. Ulm)."

This thesis deals with the processes that create ordered assemblies from disordered nanoparticles. Ordered packings of nanoscale particles can exhibit unusual properties. This work investigates the self-assembly of such particles, a process widely employed for the generation of ordered structures, but not yet well understood. In situ methods are used to observe the assembly of sub-micron polymer lattices and sub-10 nm gold particles into crystalline monolayers and aggregates. On the basis of these results, the book develops new models that describe the competition between different influences, such as thermal agitation and directional forces. It suggests necessary criteria that lead to the emergence of order.

This book provides a detailed overview of the plasma fluidized bed. It is an innovative tool and generally combines plasma process with another efficient reactor, fluidized bed, providing an excellent method for particulate processes over conventional technology. The development and designs of typical types of plasma fluidized beds, mainly thermal plasma fluidized beds and non-thermal plasma fluidized beds are discussed. The influencing factors on the performance of plasma fluidized beds are analyzed in detail. The mechanism, i.e. the discharge characteristics, hydrodynamics, heat transfer and mass transfer are analyzed to offer a further insight of plasma fluidized beds. Applications of plasma fluidized beds for different areas, including metallurgy extraction, green energy process, environmental protection and advanced materials are presented. The book is a valuable reference for scientists, engineers and graduate students in chemical engineering and relative fields.

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Quantum and chaos, key concepts in contemporary science, are incompatible by nature. This volume presents an investigation into quantum transport in mesoscopic or nanoscale systems which are classically chaotic and shows the success and failure of quantal, semiclassical, and random matrix theories in dealing with questions emerging from the mesoscopic cosmos. These traditional theories are critically analysed, and this leads to a new direction. To reconcile quantum with chaos and to restore genuine temporal chaos in quantum systems, a time-discrete variant of quantum dynamics is proposed. Audience: This book will be of interest to graduate students and researchers in physics, chemistry and mathematics, whose work involves fundamental questions of quantum mechanics in chaotic systems.

"Blurb & Contents" This current and comprehensive treatment of the physics of small- amplitude waves in hot magnetized plasmas provides a thorough update of the author's classic Theory of Plasma Waves. New topics include quasi-linear theory, inhomogeneous plasmas, collisions, absolute and convective instability, and mode conversion. Valuable for graduates and advanced undergraduates and an indispensable reference work for researchers in plasmas, controlled fusion, and space science.

This short Introduction into Space Charge E?ects in Semiconductors is designed for teaching the basics to undergraduates and show how space charges are created in semiconductors and what e?ect they have on the el- tric?eldandthe energybanddistributioninsuchmaterials,andconsequently on the current-voltage characteristics in semiconducting devices. Such space charge e?ects were described previously in numerous books, fromtheclassicsofSpenkeandShockleytothemorerecentonesofSeegerand others.Butmanymoredetailedinformationwereonlyavailableintheoriginal literatureandsomeofthemnotatall.Itseemstobeimportanttocollectallin a comprehensive Text that can be presented to students in Physics, Electrical Engineering, and Material Science to create the fundamental knowledge that is now essential for further development of more sophisticated semiconductor devices and solar cells. This book will go through every aspect of space charge e?ects and - scribe them from simple elementaries to the basics of semiconductor devices, systematically and in progressing detail. For simplicity we have chosen this description for a one-dimensional se- conductorthatpermitsasimpledemonstrationoftheresultsgraphicallywi- out requiring sometimes confusing perspective rendering. In order to clarify the principles involved, the book starts with a hy- thetical model, by assuming simple space charge distributions and deriving their e?ects on ?eld and potential distributions, using the Poisson equation. Itemphasizestheimportantsignrelationsoftheinterreactingvariables,space charge, ?eld, and potential (band edges). It then expands into simple semiconductor models that contain an abrupt nn-junction and gives an example of important space chargelimited currents, + as observed in nn -junctions.

A description of general techniques for solving linear partial differential equations by dividing space into regions to which the equations are independently applied and then assembling a global solution from the partial ones. Intended for researchers and graduates involved in calculations of the electronic structure of materials, this will also be of interest to workers in quantum chemistry, electron microscopy, acoustics, optics, and other fields. The book begins with an intuitive approach to scattering theory and then turns to partial waves and a formal development of multiple scattering theory, with applications to the solid state. The authors then present a variational derivation of the formalism and an augmented version of the theory, concluding with a discussion of the relativistic formalism and a discussion of the Poisson equation. Appendices discuss Green's functions, spherical functions, Moller operators and the Lippmann-Schwinger equation, irregular solutions, and singularities in Green's functions.

"Fundamental Tests of Physics with Optically Trapped Microspheres "details experiments on studying the Brownian motion of an optically trapped microsphere with ultrahigh resolution and the cooling of its motion towards the quantum ground state.
Glass microspheres were trapped in water, air, and vacuum with optical tweezers; and a detection system that can monitor the position of a trapped microsphere with Angstrom spatial resolution and microsecond temporal resolution was developed to study the Brownian motion of a trapped microsphere in air over a wide range of pressures. The instantaneous velocity of a Brownian particle, in particular, was studied for the very first time, and the results provide direct verification of the Maxwell-Boltzmann velocity distribution and the energy equipartition theorem for a Brownian particle. For short time scales, the ballistic regime of Brownian motion is observed, in contrast to the usual diffusive regime.
In vacuum, active feedback is used to cool the center-of-mass motion of an optically trapped microsphere from room temperature to a minimum temperature of about 1.5 mK. This is an important step toward studying the quantum behaviors of a macroscopic particle trapped in vacuum.

Volume 9 of the "Handbook of Magnetic Materials" has a dual purpose, as do the preceding volumes in the series. As a textbook it is intended to be of assistance to those who wish to be introduced to a given topic in the field of magnetism without the need to read the vast amount of literature published. As a work of reference it is intended for scientists active in magnetism research. To this dual purpose, Volume 9 of the Handbook is composed of topical review articles written by leading authorities. In each of these articles an extensive description is given in graphical as well as in tabular form, much emphasis being placed on the discussion of the experimental material in the framework of physics, chemistry and material science.

Chapter one presents a general account of the magnetism of heavy-fermion systems. Two novel experimental techniques are described in chapters two and five. Chapter two deals with muon spin rotation and chapter five gives an account of the possibilities offered by photon beam spectroscopy. In both chapters it is shown how these sophisticated experimental methods can be used to obtain experimental information not easily obtainable by conventional experimental methods. Chapter three deals with interstitially modified intermetallic compounds of rare earth and 3d elements. Finally chapter four is concerned with thermodynamic approach to phase transitions and shows how the understanding and description of these magnetic phase transitions can be considerably enriched.

The physics of strongly correlated fermions and bosons in a disordered envi ronment and confined geometries is at the focus of intense experimental and theoretical research efforts. Advances in material technology and in low temper ature techniques during the last few years led to the discoveries of new physical of atomic gases and a possible metal phenomena including Bose condensation insulator transition in two-dimensional high mobility electron structures. Situ ations were the electronic system is so dominated by interactions that the old concepts of a Fermi liquid do not necessarily make a good starting point are now routinely achieved. This is particularly true in the theory of low dimensional systems such as carbon nanotubes, or in two dimensional electron gases in high mobility devices where the electrons can form a variety of new structures. In many of these sys tems disorder is an unavoidable complication and lead to a host of rich physical phenomena. This has pushed the forefront of fundamental research in condensed matter towards the edge where the interplay between many-body correlations and quantum interference enhanced by disorder has become the key to the understand ing of novel phenomena."

Advances in Quantum Methods and Applications in Chemistry, Physics, and Biology includes peer-reviewed contributions based on carefully selected presentations given at the 17th International Workshop on Quantum Systems in Chemistry, Physics, and Biology. New trends and state-of-the-art developments in the quantum theory of atomic and molecular systems, and condensed matter (including biological systems and nanostructures) are described by academics of international distinction.

This volume represents a collection of authoritative reviews by internationally recognized experts in the field of middle infrared (mid-IR) coherent sources and their applications. The compilation describes the fundamental principles and state-of-the-art of practical solid-state sources in the mid-IR regions of the spectrum covering the 2-50 m range. Coherent mid-IR sources also offer important technologies for atmospheric chemistry, free-space communication, imaging, rapid detection of explosives, chemical and biological agents, narcotics, as well as for applications in air- and sea-born security. In comparison to the previous volume on this subject in 2003, which focused mainly on the design and development of mid-IR sources, the emphasis in the present volume is shifted towards applications. The instructive nature of the book makes it an excellent text for practicing engineers, physicists and graduate students.

This book addresses the nonlinear interactions of ultra-high-intensity electromagnetic radiation with matter. It describes fundamentally new regimes of laser pulse propagation, including relativistic and charge-displacement self-channelling and instabilities of electromagnetic radiation in plasmas (Raman scattering by plasmons, harmonic excitation, collective Compton effect). The analysis makes use of fully nonlinear models, analytical techniques and extensive simulations, whereby both qualitative and quantitative interpretations are included. The book provides a comprehensive introduction to laser physics at relativistic intensities that will be valuable to both researchers and graduate students.

This is the second in a series of "International Workshops on Electron Correlations and Materials Properties. " The aim of this series of workshops is to provide a periodic (triennial) and in-depth assessment of advances in the study and understanding of the effects that electron-electron interactions in solids have on the determination of measurable properties of materials. The workshop is structured to include exposure to experimental work, to phenomenology, and to ab initio theory. Since correlation effects are pervasive the workshop aims to concentrate on the identification of promising developing methodology, experimental and theoretical, addressing the most critical frontier issues of electron correlations on the properties of materials. This series of workshops is distinguished from other topical meetings and conferences in that it strongly promotes an interdisciplinary approach to the study of correlations, involving the fields of quantum chemistry, physics, and materials science. The First Workshop was held June 28-July 3, 1998, and a proceedings of the workshop was published by KluwerlPlenum. The Second Workshop was held June 24- 29,2001, and this volume contains the proceedings of that scientific meeting. Through the publications of proceedings, the workshop attempts to disseminate the information gathered during the discussions held at the Workshop to the wider scientific community, and to establish a record of advances in the field.

Nature is the best example of a system functioning on the nanometer scale, wherethematerialsinvolved,energyconsumption,anddatahandlingareop- mized. Opening the doors to the nanoworld, the emergence of the scanning tunneling microscope in 1982 and the atomic force microscope in 1986 led to a shift of paradigmin the understanding and perception of matter at its most fundamentallevel. As aconsequence,newrevolutionaryconceptsstimulateda number of new technologies. The current volume Scanning Probe Methods in Nanoscience and Nanotechnology showsthat these methods arestill making a tremendous impact on many disciplines that range from fundamental physics andchemistry throughinformationtechnology,spintronics,quantumcomp- ing, and molecular electronics, all the way to life sciences. Indeed, over 6,000 AFM-related papers were published in 2008 alone, bringing the total to more than 70,000 since its invention, according to the web of science, and the STM has inspired a total of 20,000 papers. There are also more than 500 patents related to the various forms of scanning probe microscopes. Commerciali- tion of the technology started at the end of the 1980s, and approximately 12,000 commercial systems have been sold so far to customers in areas as diverse as fundamental research,the car industry, and even the fashion ind- try. There are also a signi?cant number of home-built systems in operation. Some60-80companiesareinvolvedinmanufacturingSPMandrelatedinst- ments. Indeed, not even the sky seems to be the limit for AFM technology. TheRosettamissiontocomet67Plaunchedbythe EuropeanSpaceAgencyin 2004 includes an AFM in its MIDAS (Micro-Imaging Dust Analysis System) instrument.

Layered crystals, characterized by a quasi-two-dimensional character of certain physical properties, play an interesting role in surface science. First of all they provide excellent inert substrates for epitaxial deposition and physisorption studies. The surfaces of layered crystals, however, are interesting in their own right because they make a relevant class of low-dimensional phenomena accessible to surface probes. Change density waves, incommensurate structures, phonon anomalies and high Tc superconductivity are well known examples. This book collects a series of review articles written by outstanding specialists on the structural assessment and spectroscopy of layered structures with surface-sensitive probes such as scanning microscopy and helium atom scattering, the theoretical analysis of their electronic and vibrational surface states, and the investigation of physisorbed overlayers.

The conceptofspontaneous symmetry breaking plays a fundamental role in contemporary physics. It is essential for the description of degenerate ground states, massless modes, and topological defects. Examples are abundant in condensed matter physics, atomic and particle physics, as well as in astro physics and cosmology. In fact, spontaneous symmetry breaking can be re garded as a cornerstone ofa whole branch ofphysics which intersects the above mentioned traditionally distinct fields. In the year 2000 the European Science Foundation (ESF) started the Pro gramme "Cosmology in the Laboratory" (COSLAB), with the goal to search for and to develop analogies betweencondensed matterphysics, particle physics, and cosmology. Not surprisingly, spontaneous symmetry breaking is among the most useful notions in that endeavour. It has been decided that in the sec ond year of the Programme a School should be held in order to work out and deliver to a wide audience of students synthetic overviews of achievements and of current research topics of COSLAB. This idea has been supported by the Scientific and Environmental Affairs Division of NATO by including the School in the renowned series of its Advanced Study Institutes. The School, entitled" Patterns of Symmetry Breaking," was held in Cracow during 16-28 September 2002. It gathered 17 lecturers and about 60 students. The present volume contains notes ofmost of the lectures from that School. We hope that of the physics of spon it will convey to the reader the breadth and the beauty taneous symmetry breaking."

Nano-science looks at nano-interfaces and nano-junctions, atomic and molecular manipulation of adsorbates, properties of self assembled films and quantum transport in nano-structures. Understanding of these phenomena at the nano-scale is of great importance for both science and technology. Computations for the Nano-Scale is the first book to present the state of the art of the theory of nano-science and some related experiments. It assembles contributions from leading experts who met for a NATO Workshop in Aspet, France, October 12--16, 1992.

Although exploratory and developmental activity in electron beam testing (EBT) 25 years, it was not had already been in existence in research laboratories for over until the beginning of the 1980s that it was taken up seriously as a technique for integrated circuit (IC) testing. While ICs were being fabricated on design rules of several microns, the mechanical ne edle probe served quite adequately for internal chip probing. This scenario changed with growing device complexity and shrinking geometries, prompting IC manufacturers to take note ofthis new testing technology. It required several more years and considerable investment by electron beam tester manufacturers, however, to co me up with user-friendly automated systems that were acceptable to IC test engineers. These intervening years witnessed intense activity in the development of instrumentation, testing techniques, and system automation, as evidenced by the proliferation of technical papers presented at conferences. With the shift of interest toward applications, the technology may now be considered as having come of age.

Intended for researchers and students in physics, chemistry and materials science, this work aims to provide the necessary background information and sufficient mathematical and physical detail to study research literature in nuclear magnetic resonance studies of liquid crystals. This second edition, updated throughout, incorporates many new references, corrects typographical errors, and includes new mathematical appendices.