In this timely volume, scientists examine examine the physical, structural, and analytical chemistry of fuel combustion. Their contributions also address the issue of combustion efficiency and how air quality can be protected or improved. Supported by numerous illustrations, this volume be appreciated by researchers and students working in various areas of chemistry.

Chemical pretreatment of nuclear wastes refers to the sequence of separations processes used to partition such wastes into a small volume of high-level waste for deep geologic disposal and a larger volume of low-level waste for disposal in a near-surface facility. Pretreatment of nuclear wastes now stored at several U. S. Department of Energy sites ranges from simple solid-liquid separations to more complex chemical steps, such as dissolution of sludges and removal of selected radionuclides, e. g. , 90Sr, 99Tc, 137CS, and TRU (transuranium) elements. The driving force for development of chemical pretreatment processes for nuclear wastes is the economic advantage of waste minimization as reflected in lower costs for near-surface disposal compared to the high cost of disposing of wastes in a deep geologic repository. This latter theme is expertly and authoritatively discussed in the introductory paper by J. and L. Bell. Seven papers in this volume describe several separations processes developed or being developed to pretreat the large volume of nuclear wastes stored at the US DOE Hanford and Savannah River sites. These papers include descriptions of the type and amount of important nuclear wastes stored at the Hanford and Savannah River sites as well as presently envisioned strategies for their treatment and final disposal. A paper by Strachan et al. discusses chemical and radiolytic mechanisms for the formation and release of potentially explosive hydrogen gas in Tank 241-SY-101 at the Hanford site.

Monitoring the environment is absolutely essential if we are to identify hazards to human health, to assess environmental cleanup efforts, and to prevent further degradation of the ecosystem. Biomonitors and biomarkers combined with chemical monitoring offer the only approach to making these assessments. Based on an International Association of Great Lakes Research conference, this book is intended for researchers who want to incorporate new and different technologies in their development of specifically-crafted monitors; students who are learning the field of biomonitoring; and regulatory agencies that want to consider newer technologies to replace inadequate and less powerful test regimes.

Motivation The other day I was waiting at the station for my train. Next to me a young lady was nonchalantly leaning against the wall. Suddenly, she took a cigarette pack out of her handbag, pulled out the last cigarette, put it between her lips, crushed the empty pack, threw it on the ground and hedonistically lit the cigarette. I thought to myself, "What a behavior? ." The nearest trashcan was just five meters away. So I bent down, took the crushed pack and gave it back to her, saying that she had lost it. She looked at me in a rather deranged way, but she said nothing and of waste to the trashcan. brought the piece Often people are not aware of the waste they produce. They get rid of it and that's it. As soon as the charming lady dropped the cigarette pack, the problem was solved for her. The pack was on the ground and it suddenly no longer belonged to her. It is taken for granted that somebody else will do the cleaning up. There is a saying that nature does not produce waste. For long as humans obtained the goods they needed from the ground where they lived, the waste that was produced could be handled by nature. This has drastically changed due to urbanization and waste produced by human activities has become a severe burden.

A survey of the feasibility of aircraft- and satellite-based methods for revealing environmental-geological problems. Throughout, a balanced ratio between explanations on the methodological/technical side and presentations of case studies is maintained. The comparison of case studies from North America and Germany shows how the respective territorial conditions lead to distinct methodological approaches. Equally, the considerable dissimilarities in population density and in distances between waste disposal areas, settlements, and areas of protected groundwater necessitate a "diversified methods" approach.

A survey of recent developments in the field of plutonium disposal by the application of advanced nuclear systems, both critical and subcritical. Current national R&D plans are summarized. The actinide-fuelled critical reactors are associated with control problems, since they tend to have a small delayed neutron fraction coupled with a small Doppler effect and a positive void coefficient. Current thinking is turning to accelerator-driven subcritical systems for the transmutation of actinides. The book's conclusion is that the various systems proposed are technically feasible, even though not yet technically mature. The book presents a unique summary and evaluation of all relevant possibilities for burning surplus plutonium, presented by experts from a variety of different disciplines and interests, including the defence establishment. The obvious issue - the non-proliferation of nuclear weapons - is vital, but the matter represents a complex technological challenge that also requires an assessment in economic terms.

The purpose of these proceedings was to address the technological, economic, insti- tutional and social questions raised by the rapidly evolving u se of biotechnology for the protection. restoration, and sustainability of our environment. The symposium, "Biotech- nology in the Sustainable Environment" emphasized the future-oriented nature of biotech- nology, that is, the potential use of biotechnology in upstream decisions about materials management, in addition to the status and directions of urrent c applications. This sympo- sium incorporated statc-of-the-science. as well as risk and policy issues into the lopics of biotechnology and remediation, waste treatment, environmental evaluation and monitor- ing, and versatility and future directions in biotechnology and sustainability. Achieving a sustainable environment cannot be accomplished by one discipline or one sector of soci- ety. Likewise, long-term environmental sustainability cannot be accomplished by one gov- ernment. Sustainability must be a global effort as is evident from the multinational participation in these proceedings. The importance of biotechnology, sustainability, and the environment is highlighted by the combined support that this discipline receives from industry and the government. In this regard, we acknowledge the foresight of the sponsors and supporters of this sympo- sium: Eastman Chemical Company, E. !. DuPont De Nemours and Company, Inc.

The authors explain the rewarding results from the interdisciplinary collaboration between an environmental study group working on coastal ecosystems and effects of oil spills and applied mathematicians modelling wave motion on sandy beaches. By using the unified Navier-Stokes equations with a Bingham fluid model for spilled oil, multi-phase flow analysis were made. Decomposition of spilled oil by bacteria was simulated as a chemical reaction, and the theoretical and numerical analysis suggested a countermeasure to help reduce stress on coastal ecosystems. The new understanding of how ecosystems both depend upon, and help to determine, the nature of the shoreline demonstrates promising ways to better assist and exploit the regenerative powers inherent in nature.

A review of such natural disasters as floods and landslides, highlighting the possibility of safe and correct land planning and management by means of a global approach to territory. Since the events deriving from slope and fluvial dynamics are commonly triggered by the same factor, occur at the same time and are closely related, this book analyses floods and slope stability phenomena as different aspects of the same dynamic system: the drainage basin.

This manuscript was made possible by the exceptional support provided by INSA (Institut National des Sciences Appliquees) Toulouse, the University of New Mexico and the University of Cincinnati College of Engineering. The authors, as listed in this book, took the time to prepare excellent manuscripts focusing on scientific and technical areas relevant to emerging environmental issues. These manuscripts were rigorously reviewed and refereed by scientists and engineers before inclusion in this book. An introductory chapter was prepared to summarize and integrate technical issues covered and the last chapter was written to present policy perspectives. The editors are most grateful to the contributors, sponsor organizations, and many colleagues who were kind enough to assist us in making this manuscript possible. Background information about the editors, principal authors and other contributor: s to this manuscript follows. Editors Professor Dr. Ravi K. Jain Associate Dean for Research and International Engineering College of Engineering University of Cincinnati Mail Location 0018 Cincinnati OH 45221-0018 U.S.A

Co-utilization or blending of residuals offers a unique opportunity to develop products with particular characteristics that are able to target specific customer needs. The very notion of deliberately blending by-products suggests that the recycling and beneficial reuse industries are taking a quantitative step forward towards developing products rather than simply reusing residuals. At the same time that this step provides unique opportunities, it also presents unique challenges. The science associated with the beneficial use of one product may not apply when that product is mixed with another residual. Blending of materials may alter the chemistry of the components of the mixture. This may offer additional benefits, as in the case of disease suppression in composts, or present unexpected problems, as the use of lime-stabilized biosolids has done in Maryland. This book consists of the proceedings of the Beltsville Symposium. The organizers of the Symposium attempted to structure a meeting that would outline both the potential benefits of co-utilization as well as concerns. The editors have divided the proceedings into sections that describe the practical basis for co-utilization of residuals as well as the potential benefits. Specific considerations are described. Finally, case studies include descriptions of successful operations and data that detail results of research involving co-utilization materials. Blending of materials for specific objectives needs to be the focus of any successful co-utilization effort. The scientific implications of the mix need to be determined before a product can be used properly.

With the end of the Cold War, new opportunities for interaction have opened up between the United States and the countries of the Former Soviet Union. Many of these important initiatives involve the US Department of Energy (DOE) and the Ministry of the Russian Federation for Atomic Energy (MINA TOM). Currently, collaboration is under way which involves reactor safety, the disposition of fissile materials from the weapons program, radioactive waste disposal, and the safety of nuclear warheads. Another fruitful area of interchange resulted from the radiochemical storage tank accident at the site of the Siberian Chemical Compound at Tomsk-7 in 1993. DOE and MINATOM agreed to meet and exchange information about the accident for the purposes of improving safety. A meeting on the Tomsk tank accident was held in Hanford, Washington in 1993, followed by a second meeting in st. Petersburg, Russia in 1994 in which the agenda expanded to include radiochemical processing safety. A third exchange took place in 1995 in Los Alamos, New Mexico, and additional papers were presented on nonreactor nuclear safety. Following a planning session in 1996 in Seattle, Washington, it was decided to hold a fourth technical exchange on the broader subject of nuclear materials safety management. Through a grant from the North Atlantic Treaty Organization (NATO) Disarmament Programme, the meeting took place on March 17- 21, 1997, in Amarillo, Texas as a NATO Advanced Research Workshop (ARW) through grant no. DISRM 961315.

Until the late 1970s, most commercial power plant operators outside the United States adopted a spent fuel management policy of immediate reprocessing and recycling of recovered products. In response to rising reprocessing prices, decreasing values of re covered products, concerns over proliferation risks, and a belief in the favorable eco nomics of direct disposal, many utilities have since opted to store spent fuel on an in terim basis pending the availability of direct disposal facilities or a change in the eco nomic and/or political climate for reprocessing and recycling uranium and plutonium. Spent fuel has traditionally been stored in water-filled pools located in the reactor building or fuel handling buildings, on reactor sites, or as part of large centralized fa cilities (e.g. Sellafield, La Hague, CLAB). Because the economics of pool storage are dependent on the size of the facility, the construction of additional separate pools on reactor sites has only been pursued in a few countries, such as Finland and Bulgaria."

The surplus of plutonium in the world is both an important security issue, and a fact with implications for nuclear energy and environmental policy internationally. The two perspectives are inextricably intertwined in considering options for dealing with the plutonium surplus. It was for this reason that two research programmes at the Royal Institute of International Affairs - respectively on Energy and Environment, and on International Security - jointly approached NATO with a view to organising a work shop on the issue. It was most welcome then to learn that the NATO Science Programe was already supporting plans for a workshop on the issue, initiated by Richard Garwin, and we were pleased to accept the resulting invitation to host that workshop. DrGarwin prepared the initial agenda and established contacts and initial approaches to many of the participants; we were able to develop the agenda further and extend participation in some complementary ways. The result was a most lively and broad-ranging internation al and inter-disciplinary discussion. As the hosts, the RIIA was also given lead responsibility for producing the pro ceedings of the workshop as a publication for NATO. Many of the papers to the work shop are more technical than usually involved in a workshop at the Royal Institute. Yet this is an area in which the policy options are unusually dependent upon a good under standing of the technical issues. which themselves are often a matter of dispute."

Significant amounts of liquid and solid radioactive waste have been generated in Russia during the production of nuclear weapons, and there is an urgent need to find suitable ways to manage these wastes in a way that protects both the current population and future generations. This book contains contributions from pure and applied scientists and other representatives from Europe, North America, and Russia, who are, or have been, actively involved in the field of radioactive waste management and disposal. First-hand experience of specific problems associated with defence-related wastes in the USA and the Russian Federation is presented, and current plans are described for the disposal of solid wastes arising from civilian nuclear power production programmes in other countries, including Belgium, Bulgaria, Canada, Germany and the UK. The book provides a good insight into ongoing research at local and national level within Russia, devoted to the safe disposal of defence-related radioactive waste. It also demonstrates how existing expertise and technology from civilian nuclear waste management programmes can be applied to solving the problems created by nuclear defence programmes. Contributions address methods of immobilisation, site selection methodology, site characterisation techniques and data interpretation, the key elements of safety/performance assessments of planned deep (geological) repositories for radioactive waste, and radionuclide transport modelling. Concerns associated with certain specific nuclear waste disposal concepts and repository sites are also presented.

Purpose ofthe Workshop In the spirit of enhancing developments in science and technology by facilitating international scientific cooperation, the Science Committee of NATO is sponsoring AR W's in several selected priority areas. The objective of this workshop was to discuss what microbial mediated problems have been experienced in the area of nuclear waste management and spent fuel storage. Long term storage of high-level wastes in repositories is just starting in some countries. However, low and medium level wastes have been stored for several decades. In the area of spent fuel interim, storage has been extended at many locations far beyond the intended time. It was a priority of the workshop to examine and discuss what deleterious effects have been observed under these storage conditions or under conditions used in simulated trial tests for predicting material performance under the storage conditions. For example, one chronic problem that was discussed was possibility that microbial influenced corrosion (MIC) could be taking place in the wet storage of spent fuel thereby initiating or accelerating the process of corrosion. Another discussion in the area of waste forms, focused on the presence ofbiofilms which may be breaking down the structure of the waste form and thereby jeopardizing its integrity. The meeting focused on discussing the observations and data collected relating to problems encountered in the storage of these types of wastes, and sharing this information with others that have not monitored their facilities for similar problems.

Leon N. Moses In June 1991, the Transportation Center at Northwestern University sponsored Hazmat Transport '91: A National Conference on the Transportation of Hazardous Materials and Wastes. The faculty associated with the center were aware that there had been many professional, industrial and government conferences and meetings on the subject. However, they believed that the unique capacity of the Transportation Center to bring together leaders from industry and government, as well as leading scholars from economics, law, engineering, psychology and sociology who have done research on the problems associated with the transportation of hazardous materials and wastes (hazmats), could produce a set of integrated insights and understandings that would go well beyond those of previous conferences. The papers that make up this volume were all delivered at Hazmat Transport '91. From a legislative point of view, they tend to deal with issues associated with the Hazardous Materials Transportation Act of 1975 (HMTA), the original act passed to regulate the transportation of hazardous materials, and the Hazardous Materials Transportation Uniform Safety Act of 1990 (HMTVSA). There were talks and papers presented at the conference that focused on other recent legislation and transportation issues with which HMTUSA does not deal. The conference proceedings volume also had discussions and papers on significant managerial and regulatory issues that could not be included in this volume because of constraints on its size. Therefore, this essay is made up of three parts.

Proceedings of the International Workshop, Thermal Solid Waste Utilization in Regular and Industrial Facilities, held in Kazimierz Dolny, Poland, November 28-30, 1999. In recent years, industrial and urban growth has resulted in growing volumes of nondegradable wastes, and this volume focuses on the technologies related to recycling and material reuse which are now being favoured over land disposal. There is an overview on waste utilisation in industrial facilities, particularly cement kilns, from an ecological as well as technological aspect, and some innovative solutions of pyrolitic and plasma reactors, used for hazardous wastes combustion.

Reviews of Environmental Contamination and Toxicology provides detailed review articles concerned with aspects of chemical contaminants, including pesticides, in the total environment with toxicological considerations and consequences.

Reviews of Environmental Contamination and Toxicology attempts to provide concise, critical reviews of timely advances, philosophy and significant areas of accomplished or needed endeavor in the total field of xenobiotics, in any segment of the environment, as well as toxicological implications.

Reviews of Environmental Contamination and Toxicology attempts to provide concise, critical reviews of timely advances, philosophy and significant areas of accomplished or needed endeavor in the total field of xenobiotics, in any segment of the environment, as well as toxicological implications.

Synthetic and semi-synthetic polymeric materials were originally developed for their durability and resistance to all forms of degradation including biodegradation. Such materials are currently widely accepted because of their ease of processability and amenability to provide a large variety of cost effective items that help to enhance the comfort and quality of life in the modern industrial society. However, this widespread utilization of plastics has contributed to a serious plastic waste burden, and the expectation for the 21st century is for an increased demand for polymeric material. This volume focuses on a more rational utilization of resources in the fabrication, consumption and disposal of plastic items, specifically: -Environmentally Degradable Polymeric Materials (EDPs); -Water-soluble/Swellable Biodegradable Polymers; -EDPs from Renewable Resources; -Biopolymers; -Bioresorbable Materials for Biomedical Applications; -Biorelated Polymers; -Standards and Regulations on EDPs.

This book encourages and demonstrates an innovative approach to the design and operation of urban wastewater systems: integrated modelling and control. Consideration of sewer system, wastewater treatment plant and receiving water body as a single system (rather than as three moderately independent units as before) opens up new types of analyses and new control algorithms for urban wastewater systems. After a comprehensive review of the literature of various fields including processes affecting water flow and quality in urban wastewater systems and their description by different types of models, this book also introduces some of the fundamental concepts of the operation of such systems. It discusses conventional as well as innovative control approaches - ranging from control by simple set-points to elaborate hierarchical control concepts taking into account the water flow and the quality of sewer systems, treatment plants and receiving water body. Thus it will enable the researcher as well as the practising engineer to analyse and to implement various types of control for a particular case study site.In order to illustrate the concepts developed, a detailed simulation study, covering the complete urban wastewater system, is presented. The conclusions drawn demonstrate that the application of innovative control concepts can lead to improved performance of wastewater systems. In addition, a comprehensive survey of mathematical optimisation methods is presented. This book can assist the practising engineer and the student to gain knowledge of all aspects of wastewater systems. To the researcher, this book provides a thorough survey of existing simulation and control concepts and inspiration for further work.

The management and disposal of radioactive wastes are key international issues requiring a sound, fundamental scientific basis to insure public and environmental protection. Large quantities of existing nuclear waste must be treated to encapsulate the radioactivity in a form suitable for disposal. The treatment of this waste, due to its extreme diversity, presents tremendous engineering and scientific challenges. Geologic isolation of transuranic waste is the approach currently proposed by all nuclear countries for its final disposal. To be successful in this endeavor, it is necessary to understand the behavior of plutonium and the other actinides in relevant environmental media. Conceptual models for stored high level waste and waste repository systems present many sCientific difficulties due to their complexity and non-ideality. For example, much of the high level nuclear waste in the US is stored as alkaline concentrated electrolyte materials, where the chemistry of the actinides under such conditions is not well understood. This lack of understanding limits the successful separation and treatment of these wastes. Also, countries such as the US and Germany plan to dispose of actinide bearing wastes in geologic salt deposits. In this case, understanding the speciation and transport properties of actinides in brines is critical for confidence in repository performance and risk assessment activities. Many deep groundwaters underlying existing contaminated sites are also high in ionic strength. Until recently, the scientific basis for describing actinide chemistry in such systems was extremely limited."

The ffiM Japan International Symposium Energy and Environment - Global Warming was held in the Keidanren Guesthouse at the foot of Mt. Fuji, from October 21 to 24, 1990. The symposium was conducted in the context of ffiM Japan's longstanding commitment to good corporate citizenship. On this beautiful planet with its inter-dependent waters, lands and atmo sphere, we consider that the problems relating to the global environment are the most serious that the human race will face in the near future. The symposium provided an opportunity for forty scientists and researchers, from a wide variety of international backgrounds, to address matters relating to the global environment in an international forum. Eighteen papers were presented followed by panel and group discussions, on which the concluding remarks and recommendations are based. We chose three types of papers to target different aspects of the condition of the global environment: the natural science component; the socio-economic component; and the energy component which links these two. On the first day the symposium began with a plenary speech by Dr. J. Kondo followed by three keynote speeches, each with a particular focus. The following day, six speakers offered papers relating to the previous day's keynote speeches."