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The Anomeric Effect and Related Stereoelectronic Effects at Oxygen (Paperback, Softcover reprint of the original 1st ed. 1983)
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The Anomeric Effect and Related Stereoelectronic Effects at Oxygen (Paperback, Softcover reprint of the original 1st ed. 1983)
Series: Reactivity and Structure: Concepts in Organic Chemistry, 15
Expected to ship within 10 - 15 working days
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The anomeric effect is a well-defined and much studied example of a
deep- seated and very general effect in organic chemistry. It
involves a fundamental interaction between the lone pair electrons
of oxygen and the antibonding orbitals of adjacent bonds, which can
control not only conformation but also reactivity in suitable
systems. So the heart of this book is a consideration of the
properties of non-bonding pairs of electrons, and the influence of
orbital- orbital interactions on structure and reactivity. I have
been lucky in recent months to be able to discuss various matters
arising in this book with people who know more about them than I
do. Parti- cularly Professors C. Altona, A. Eschenmoser, F.
Hirshfeld, M. Lahav, R.A. McClelland, G.M. Sheldrick and A. Vos,
and, nearer horne, I. Fleming, P.G. Jones, AJ. Stone (who helped
with the rather theoretical Appendix) and I.H. Williams. I am also
most grateful to Professors P. Deslongchamps, ID. Dunitz, D.G.
Gorenstein, W.P. Jencks, G.A. Jeffrey, R.D. Lemieux and S. Wolfe,
for very helpful correspondence, and information in advance of
pUblication. I have covered the literature received in Cambridge up
to early December 1981.
General
Imprint: |
Springer-Verlag
|
Country of origin: |
Germany |
Series: |
Reactivity and Structure: Concepts in Organic Chemistry, 15 |
Release date: |
March 2012 |
First published: |
1983 |
Authors: |
A.J. Kirby
|
Dimensions: |
244 x 170 x 9mm (L x W x T) |
Format: |
Paperback
|
Pages: |
152 |
Edition: |
Softcover reprint of the original 1st ed. 1983 |
ISBN-13: |
978-3-642-68678-8 |
Categories: |
Books >
Science & Mathematics >
Chemistry >
Organic chemistry >
General
|
LSN: |
3-642-68678-8 |
Barcode: |
9783642686788 |
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