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Polymer-Mediated Phase Stability of Colloids (Hardcover, 1st ed. 2019)
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Polymer-Mediated Phase Stability of Colloids (Hardcover, 1st ed. 2019)
Series: Springer Theses
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Colloid-polymer mixtures are subject of intensive research due to
their wide range of applicability, for instance in coatings and
food-stuffs. This thesis constitutes a fundamental investigation
towards a better control over the stability of such suspensions.
Through the chapters, different key parameters governing the
stability of colloid-polymer mixtures are explored. How the colloid
(pigment) shape and the effective polymer-colloid affinity modulate
the stability of the suspension are examples of these key
parameters. Despise the mostly theoretical results presented, the
thesis is written in a format accessible to a broad scientific
audience. Some of the equations of state presented might of direct
use to experimentalists. Furthermore, new theoretical insights
about colloid-polymer mixtures are put forward. These include
four-phase coexistences in effective two-component, quantification
of depletant partitioning at high colloidal concentrations,
multiple re-entrant phase behaviour of the colloidal fluid-solid
coexistence, and a condition where polymers are neither depleted
nor adsorbed from/to the colloidal surface.
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