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Stereoselective Synthesis in Organic Chemistry (Paperback, Softcover reprint of the original 1st ed. 1993)
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Stereoselective Synthesis in Organic Chemistry (Paperback, Softcover reprint of the original 1st ed. 1993)
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This monumental tome by Prof. Atta-ur-Rahman and Dr. Zahir Shah
pres- ents a broad overall perspective of stereo selectivity in the
synthesis of or- ganic molecules. Thus it treats a problem that is
of fundamental importance and will be even more important in the
future as the drug industry is required to supply 1000/0 optically
pure compounds. After an exposition of general principles, the
following subjects are treated: Catalytic Reductions, Heterogeneous
Catalytic Hydrogenations, Stereoselective Non-Catalytic Reductions,
Stereos elective Carbon-Carbon Bond Forming Reactions, Asymmetric
Oxidations, Asymmetric Carbon- Heteroatom Bond Formations, Enzyme
Catalyzed Reactions, Stereo- selective Free Radical Reactions, and
finally Miscellaneous Stereoselective Reactions. For each subject,
a wealth of examples are given. The highly selective reactions are
mentioned along with reactions that are not. This is helpful as it
will teach the practical chemist what to avoid. Much progress has
been made in the last two decades in the design of new, very
stereoselective reactions which can be applied in industry. For
example, and in alphabetical order, we can mention (among other
peers): H.C. Brown (hydroboration), D.C. Evans (carbon-carbon bond
forma- tion), R. Noyori (BINAP reagents for hydrogenation), and
K.B. Sharpless (epoxidation and dihydroxylation of double bonds).
Thus the field has completely changed since the 1950s, when
optically pure compounds were always obtained by difficult
resolutions of racemates and not by stereoselec- tive reactions.
General
Imprint: |
Springer-Verlag New York
|
Country of origin: |
United States |
Release date: |
December 2011 |
First published: |
1993 |
Authors: |
Atta-ur Rahman
• Zahir Shah
|
Dimensions: |
235 x 155 x 27mm (L x W x T) |
Format: |
Paperback
|
Pages: |
522 |
Edition: |
Softcover reprint of the original 1st ed. 1993 |
ISBN-13: |
978-1-4613-8329-1 |
Categories: |
Books >
Science & Mathematics >
Chemistry >
Organic chemistry >
General
|
LSN: |
1-4613-8329-3 |
Barcode: |
9781461383291 |
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