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Adsorption, Aggregation and Structure Formation in Systems of Charged Particles - From Colloidal to Supracolloidal Assembly (Hardcover, 2014 ed.)
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Adsorption, Aggregation and Structure Formation in Systems of Charged Particles - From Colloidal to Supracolloidal Assembly (Hardcover, 2014 ed.)
Series: Springer Theses
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Total price: R2,803
Discovery Miles: 28 030
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This thesis presents studies on the interaction of soft materials
like surfactants and proteins with hard silica nanomaterials. Due
to its interdisciplinary nature it combines concepts from the
fields of physical chemistry, nanoscience and materials science,
yielding to fundamental insights into the structure-directing
forces operating at the nano-scale. It is shown that the morphology
of surfactant micellar aggregates adsorbed at the surface of
nanoparticles and inside tubular nanopores can be tuned on demand
by the co-adsorption of a surface modifier. The interaction of
globular proteins with silica nanoparticles is dominated by
electrostatic interactions and can be controlled by pH and ionic
strength, while the bridging of nanoparticles by adsorbed protein
molecules leads to large-scale hybrid aggregates of protein with
the nanoparticles. Concepts emerging from the role of electrostatic
interactions in the hetero-aggregation of nanoparticles with
protein molecules are used for the co-assembly of charged
microbeads into linear clusters and chains of controllable length.
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