The work deals with an electro-optical study of chiral nematic
liquid crystals, S-(+)-4-(2- methybutyl)phenyl 4-decyloxybenzoate
(CE6) and Cholesteryl Nonanoate (CN), a cholesteric polymer, C4745,
and a 90%CE6-10% C4745 mixture through the use of optical activity
and light scattering techniques. An expression for the optical
activity in chiral nematic liquid crystals has been derived for
zero field. This derivation represents an extension of the present
theory of optical activity in chiral nematics.Dynamic light
scattering studies were performed on various concentrations of CE6-
CE6R. From these results, phase diagrams were constructed for the
CE6-CE6R mixtures. The ransition to the blue phases becomes more
continuous with increasing chirality. The light scattering data can
be fitted to a single exponential over a wide temperature range.
The scattered intensity increases with increasing chirality and
with increasing electric field. The isotropic transition becomes
more discontinuous as the electric field increases. The electric
field destroys the contribution from the m = 2 modes while
enhancing the contributions from the m = 0 mode.
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