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Elements Cr (24) to Br (35) (Paperback, Softcover reprint of the original 1st ed. 1972)
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Elements Cr (24) to Br (35) (Paperback, Softcover reprint of the original 1st ed. 1972)
Series: Handbook of Geochemistry, 2 / 3
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The literature on the geochemistry of gallium is very extensive and
several problems arise in an attempt to summarise the available
information in a short account. Only a small proportion of the many
determinations of gallium in rocks and minerals has been made by
the most precise and accurate procedures, and ana lyses by emission
spectrographic methods constitute a dominant part of the data given
here. In Table 31-1 are summarised the results of determinations of
gallium in two standard rocks by various procedures. These results
show that the generally less precise spectrographic procedures
give, on average, values of adequate accuracy. In view of this and
also the quite low dispersion of gallium in common rocks and
minerals, the average results of the less precise analyses often
constitute abundance data of reasonable quality. Individual
determinations or whole series of determina tions by these methods
are sometimes inaccurate, however, and it remains difficult to
assess questions such as the extent to which differences in
concentrations recorded for various areas represent genuine
regional variations as distinct from systematic analytical errors.
Furthermore, the low dispersion of gallium leads to an interest in
relatively small variations in processes such as magmatic
differentiation, and these variations tend to be obscured in many
investigations through the use of imprecise methods."
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